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We report photoassociation spectroscopy of ultracold $^{86}$Sr atoms near the intercombination line and provide theoretical models to describe the obtained bound state energies. We show that using only the molecular states correlating with…

The electrostatic interaction between an excited atom and a diatomic ground state molecule in an arbitrary rovibrational level at large mutual separations is investigated with a general second-order perturbation theory, in the perspective…

量子物理 · 物理学 2017-04-11 M. Lepers , R. Vexiau , N. Bouloufa , O. Dulieu , V. Kokoouline

The binding energies of the five bound rotational levels $J=0-4$ in the highest vibrational level $v=14$ in the X$^1\Sigma_g^+$ ground electronic state of H$_2$ were measured in a three-step ultraviolet-laser experiment. Two-photon…

原子物理 · 物理学 2025-02-05 K. -F. Lai , W. Ubachs , M. Beyer

An experimental study of the long range behavior of the ground state X^1\Sigma^+_g of Sr_2 is performed by high resolution spectroscopy of asymptotic vibrational levels and the use of available photoassociation data. Ground state levels as…

化学物理 · 物理学 2010-04-19 A. Stein , H. Knöckel , E. Tiemann

We perform a theoretical analysis to interpret the spectra of purely long-range helium dimers produced by photoassociation (PA) in an ultra-cold gas of metastable helium atoms. The experimental spectrum obtained with the PA laser tuned…

量子物理 · 物理学 2009-11-10 J. Leonard , A. P. Mosk , M. Walhout , P. Van Der Straten , M. Leduc , C. Cohen-Tannoudji

We present experimental observations of seven vibrational levels $v'=20-26$ of the $1^{3}\Sigma_{g}^{+}$ excited state of Li$_2$ molecules by the photoassociation (PA) of a degenerate Fermi gas of $^6$Li atoms. For each vibrational level,…

Precise potentials for the ground state X1Sigma+g and the minimum region of the excited state 2_1Sigma+u of Sr2 are derived by high resolution Fourier-transform spectroscopy of fluorescence progressions from single frequency laser…

化学物理 · 物理学 2009-01-09 A. Stein , H. Knöckel , E. Tiemann

We establish a theoretical model to analyze the photoassociative (PA) spectroscopy of $(3)^3\Sigma^+$ state of $^{85}$Rb$^{133}$Cs molecule. The term energy, spin-spin coupling constants and hyperfine interaction constant of nine…

原子物理 · 物理学 2022-05-25 Zi-wei Wang , Zi-ang Li , Xu-hui Bai , Ting Gong , Zhong-hua Ji , Yan-ting Zhao , Gao-ren Wang

With ultracold $^{88}$Sr in a 1D magic wavelength optical lattice, we performed narrow line photoassociation spectroscopy near the $^1$S$_0 - ^3$P$_1$ intercombination transition. Nine least-bound vibrational molecular levels associated…

原子物理 · 物理学 2009-11-11 T. Zelevinsky , M. M. Boyd , A. D. Ludlow , T. Ido , J. Ye , R. Ciurylo , P. Naidon , P. S. Julienne

We describe bound states, resonances and elastic scattering of light ions using a $\delta$-shell potential. Focusing on low-energy data such as energies of bound states and resonances, charge radii, asymptotic normalization coefficients,…

核理论 · 物理学 2019-11-11 Benjamin K. Luna , T. Papenbrock

The vibrational branching ratios of SrOH for radiative decay to the ground electronic state, $X^{2}\Sigma^{+}$, from the first two electronically excited states, $A^{2}\Pi$ and $B^{2}\Sigma^{+}$, are determined experimentally at the…

原子物理 · 物理学 2022-08-17 Zack Lasner , Annika Lunstad , Chaoqun Zhang , Lan Cheng , John M. Doyle

This work presents the bound-state spectra of Morse oscillator, which remains one of the oldest important model potentials for molecules. Accurate ro-vibrational energies are obtained by means of a generalized pseudospectral method that…

量子物理 · 物理学 2013-07-19 Amlan K. Roy

We analyze the formation of Rb_2 molecules with short photoassociation pulses applied to a cold Rb-85 sample. A pump laser pulse couples a continuum level of the ground electronic state X ^1\Sigma_{g}^+ with bound levels in the 0_{u}^+…

原子物理 · 物理学 2007-06-22 Jordi Mur-Petit , Eliane Luc-Koenig , Françoise Masnou-Seeuws

We report on the anomalously high line strength of a single rotational level in the ultracold photoassociation of two 85Rb atoms to form 85Rb2. The v' = 111, J' = 5 level belongs to the Hund's case (c) 2 (0g+) state, which correlates to the…

原子物理 · 物理学 2013-02-27 R. Carollo , M. A. Bellos , D. Rahmlow , J. Banerjee , E. E. Eyler , P. L. Gould , W. C. Stwalley

We observe long-range $^{85}$Rb and $^{87}$Rb (24$D$+5$S_{1/2}$) Rydberg molecules for eight different spin couplings, with binding energies up to 440~MHz and sub-percent relative uncertainty. Isotopic effects of the molecular binding…

原子物理 · 物理学 2020-01-15 Jamie L. MacLennan , Yun-Jhih Chen , Georg Raithel

The bound states of the fermionic ^3He(2 ^3S_1)+ ^3He(2 ^3P_j)system, where j=0,1,2, are investigated using the recently available ab initio short-range ${}^{1,3,5}\Sigma^{+}_{g,u}$ and ${}^{1,3,5}\Pi_{g,u}$ potentials computed by Deguilhem…

原子与分子团簇 · 物理学 2017-09-13 Daniel G. Cocks , Gillian Peach , Ian B. Whittingham

We report on the observation of blue-detuned photoassociation in Rb2, in which vibrational levels are energetically above the corresponding excited atomic asymptote. 85Rb atoms in a MOT were photoassociated at short internuclear distances…

We perform a study on extended adiabatic potential energy curves of nearly 38 states of 1,3$\Sigma^+$, 1,3$\Pi$ and 1,3$\Delta$ symmetries for the (SrNa)$^+$ ion, though only the ground and first two excited states are used for the study of…

We report the high resolution photoassociation (PA) spectroscopy of a $^{87}Rb$ Bose-Einstein condensate (BEC) to excited molecular states near the dissociation limit of $5P_{1/2} +5S_{1/2}$ by optical Bragg scattering. Since the detection…

Cold quantum gases, when acted upon by electromagnetic fields, can give rise to samples where isolated atoms coexist with dimers or trimers, which raises the question of the interactions between these various constituents. Here we perform…

量子气体 · 物理学 2022-11-10 C. Maury , B. Bakkali-Hassani , G. Chauveau , F. Rabec , S. Nascimbene , J. Dalibard , J. Beugnon