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We show that the stacking of flat aromatic molecules on a curved surface results in topological defects. We consider, as an example, spherical vesicles, self-assembled from molecules with 5- and 6-thiophene cores. We predict that the…

软凝聚态物质 · 物理学 2011-02-18 O. V. Manyuhina , A. Fasolino , M. I. Katsnelson

Recent experimental observations have suggested that topological defects can facilitate the creation of sharp features in developing embryos. Whereas these observations echo established knowledge about the interplay between geometry and…

软凝聚态物质 · 物理学 2023-07-25 Ludwig A. Hoffmann , Livio Nicola Carenza , Luca Giomi

We propose a general formalism to characterize orientational frustration of smectic liquid crystals in confinement by interpreting the emerging networks of grain boundaries as objects with a topological charge. In a formal idealization,…

In an elegant paper, D. Nelson suggested a method to produce tetravalent colloids based on a tetrahedral configuration created on the surface of a spherical particle. It emerges from a two-dimensional nematic liquid crystal placed on a…

软凝聚态物质 · 物理学 2009-11-10 M. Huber , H. Stark

We study both experimentally and theoretically the self-assembly of binary block copolymers in dilute solution, where self-assembly is triggered by changing the solvent from the common good solvent THF to the selective solvent water, and…

软凝聚态物质 · 物理学 2011-06-28 P. Schuetz , M. J. Greenall , J. Bent , S. Furzeland , D. Atkins , M. F. Butler , T. C. B. McLeish , D. M. A. Buzza

Epithelial monolayers are a central building block of complex organisms. Topological defects have emerged as important elements for single cell behavior in flat epithelia. Here we theoretically study such defects in a three-dimensional…

生物物理 · 物理学 2025-02-19 Oliver M. Drozdowski , Ulrich S. Schwarz

The transition from a nematic to an isotropic state in a self-closing spherical liquid crystal shell with tangential alignment is a stimulating phenomenon to investigate, as the topology dictates that the shell exhibits local isotropic…

软凝聚态物质 · 物理学 2024-02-02 Yucen Han , Jan Lagerwall , Apala Majumdar

We analyse liquid-crystalline ordering in vertically vibrated monolayers of cylinders confined in a circular cavity. Short cylinders form tetratic arrangements with C$_4$ symmetry. This symmetry, which is incompatible with the geometry of…

We investigate the morphology of a toroidal fluid membrane vesicle confined inside a spherical container. The equilibrium shapes are assembled in a geometrical phase diagram as a function of scaled area and reduced volume of the membrane.…

生物物理 · 物理学 2015-10-21 Lila Bouzar , Ferhat Menas , Martin Michael Müller

We systematically explore the self-assembly of semi-flexible polymers in deformable spherical confinement across a wide regime of chain stiffness, contour lengths and packing fractions by means of coarse-grained molecular dynamics…

软凝聚态物质 · 物理学 2021-07-12 Maxime M. C. Tortora , Daniel Jost

Amphiphilic block copolymer solutions form various micellar structures including micelles and vesicles. We applied the density functional theory for block copolymers which we have proposed to amphiphilic block copolymer systems. The 3…

软凝聚态物质 · 物理学 2007-05-23 Takashi Uneyama , Masao Doi

This paper reviews the research work on the liquid crystalline (LC) polymer vesicles (polymersomes), where the thermotropic nematic and smectic phases are displayed in the lyotropic bilayer polymer membrane. LC polymersomes possess the…

软凝聚态物质 · 物理学 2015-03-05 Lin Jia , Min-Hui Li

We consider the shear flow of well-aligned one-component smectic phases, such as thermotropic smectics and lamellar diblock copolymers, below the critical region. We show that, as a result of thermal fluctuations of the layers, parallel…

凝聚态物理 · 物理学 2016-08-31 Mark Goulian , Scott T. Milner

Using particle-resolved molecular-dynamics simulations, we compute the phase diagram for soft repulsive spherocylinders confined on the surface of a sphere. While crystal (K), smectic (Sm), and isotropic (I) phases exhibit a stability…

软凝聚态物质 · 物理学 2025-11-03 Jaydeep Mandal , Hartmut Löwen , Prabal K. Maiti

We present a scheme to explicitly construct and classify general topological states jointly protected by an onsite symmetry group and a spatial symmetry group. We show that all these symmetry protected topological states can be…

介观与纳米尺度物理 · 物理学 2020-01-03 Zhida Song , Sheng-Jie Huang , Yang Qi , Chen Fang , Michael Hermele

We carry out Monte Carlo simulations on fluid membranes with orientational order and multiple edges in the presence and absence of external forces. The membrane resists bending and has an edge tension, the orientational order couples with…

软凝聚态物质 · 物理学 2023-11-01 Lijie Ding , Robert A. Pelcovits , Thomas R. Powers

The smectic C (smC) phase represents a unique class of liquid crystal phases characterised by the layered arrangement of molecules with tilted orientations with respect to layer normals. Building upon the real-valued tensorial smectic A…

软凝聚态物质 · 物理学 2024-08-09 Jingmin Xia , Yucen Han

We use classical molecular dynamics combined with the recently developed metadynamics method [A. Laio and M. Parrinello, Procs. Natl. Acad. Sci. USA 99, 20 (2002)] to study the process of bulk melting in hexagonal ice. Our simulations show…

统计力学 · 物理学 2007-05-23 Davide Donadio , Paolo Raiteri , Michele Parrinello

Determining the equilibrium configuration and shape of curved two-dimensional films with (generalized) liquid crystalline (LC) order is a difficult infinite dimensional problem of direct relevance to the study of generalized polymersomes,…

软凝聚态物质 · 物理学 2017-05-09 Mark J. Bowick , Oksana V. Manyuhina , Francesco Serafin

A stack of tensionless membranes with nonlinear curvature energy and vertical harmonic interaction is studied. At low temperatures, the system forms a lamellar phase. At a critical temperature, the stack disorders vertically in a…

凝聚态物理 · 物理学 2009-10-31 M. E. S. Borelli , H. Kleinert , Adriaan M. J. Schakel