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We report first-principles density-functional study of electron-phonon interactions and thermoelectric transport properties of full-Heusler compounds Sr$_{2}$BiAu and Sr$_{2}$SbAu. Our results show that ultrahigh intrinsic bulk…

材料科学 · 物理学 2020-08-26 Junsoo Park , Yi Xia , Alex Ganose , Anubhav Jain , Vidvuds Ozolins

We theoretically unveil the unconventional possibility to achieve extremely high thermoelectric power factors in lightly doped narrow gap semiconductors with asymmetric conduction/valence bands operated in the bipolar transport regime.…

材料科学 · 物理学 2020-08-05 Patrizio Graziosi , Neophytos Neophytou

As-Based Zintl compounds Ba1-xKxCd2As2 crystallized in the CaAl2Si2-type structure (space group P3-m1) were prepared using solid-state reactions followed by hot-pressing. We have successfully substituted K for Ba up to x = 0.08, producing…

材料科学 · 物理学 2018-11-28 H. Kunioka , K. Kihou , H. Nishiate , a A. Yamamoto , H. Usui , K. Kuroki , C. H. Lee

Low band gap thermoelectric materials suffer from bipolar effects at high temperatures, with increased electronic thermal conductivity and reduced Seebeck coefficient, leading to reduced power factor and low ZT figure of merit. In this work…

材料科学 · 物理学 2022-03-14 Patrizio Graziosi , Zhen Li , Neophytos Neophytou

The electronic, phonon and thermoelectric transport properties of (PbTe)2 layer are systematically investigated by using first-principles pseudopotential method and Boltzmann transport equation. Our calculations demonstrate that there is a…

材料科学 · 物理学 2020-03-04 Caiyu Sheng , Dengdong Fan , Huijun Liu

Tungsten diselenide (WSe2) emerges as a promising thermoelectric (TE) candidate due to its high thermopower (S), cost-effectiveness, and environmentally friendly characteristics. However, pristine WSe2 exhibits limited electrical…

The thermoelectric properties of distorted bismuth (110) layer are investigated using first-principles calculations combined with the Boltzmann transport equation for both electrons and phonons. To accurately predict the electronic and…

介观与纳米尺度物理 · 物理学 2016-06-07 L. Cheng , H. J. Liu , J. Zhang , J. Wei , J. H. Liang , P. H. Jiang , D. D. Fan , L. Sun , J. Shi

By using a first-principles approach, monolayer PbI$_2$ is found to have great potential in thermoelectric applications. The linear Boltzmann transport equation is applied to obtain the perturbation to the electron distribution by different…

材料科学 · 物理学 2021-05-24 Bo Peng , Haodong Mei , Hao Zhang , Hezhu Shao , Ke Xu , Gang Ni , Qingyuan Jin , Costas M. Soukoulis , Heyuan Zhu

Half-Heusler compounds usually exhibit relatively higher lattice thermal conductivity that is undesirable for thermoelectric applications. Here we demonstrate by first-principles calculations and Boltzmann transport theory that the BiBaK…

材料科学 · 物理学 2020-08-26 S. H. Han , Z. Z. Zhou , C. Y. Sheng , J. H. Liu , L. Wang , H. M. Yuan , H. J. Liu

Thermoelectric (TE) materials seamlessly convert thermal into electrical energy and vice versa, making them promising for applications such as power generation or cooling. Although historically the TE effect was first discovered in metals,…

Improving the figure of merit $zT$ of thermoelectric materials requires simultaneously a high power factor and low thermal conductivity. An effective approach for increasing the power factor is to align the band extremum and achieve high…

材料科学 · 物理学 2019-03-06 Jiangang He , Yi Xia , S. Shahab Naghavi , Vidvuds Ozoliņš , Chris Wolverton

Band convergence is an effective strategy to improve the thermoelectric performance of complex bandstructure thermoelectric materials. Half-Heuslers are good candidates for band convergence studies because they have multiple bands near the…

材料科学 · 物理学 2020-11-10 Chathurangi Kumarasinghe , Neophytos Neophytou

A half-Heusler material FeNb$_{0.8}$Ti$_{0.2}$Sb has been identified as a promising thermoelectric material due to its excellent thermoelectric performance at high temperatures. The origins of the efficient thermoelectric performance are…

材料科学 · 物理学 2018-08-01 Hong-Jie Pang , Chen-Guang Fu , Hao Yu , Liu-Cheng Chen , Tie-Jun Zhu , Xiao-Jia Chen

High Seebeck coefficient by creating large density of state (DOS) around the Fermi level through either electronic structure modification or manipulating nanostructures, is commonly considered as a route to advanced thermoelectrics.…

材料科学 · 物理学 2011-11-24 Yanzhong Pei , Aaron D. LaLonde , Heng Wang , G. Jeffrey Snyder

In this first-principles study, we investigated the thermoelectric properties of the full-Heusler compound CsK$_2$Sb at different compressive strains. This material exhibits a valence band structure with significant effective mass…

材料科学 · 物理学 2025-05-14 Øven A. Grimenes , G. Jeffrey Snyder , Ole M. Løvvik , Kristian Berland

Thermoelectric materials create an electric potential when subject to a temperature gradient and vice versa hence they can be used to harvest waste heat into electricity and in thermal management applications. However, finding highly…

材料科学 · 物理学 2022-05-10 Enamul Haque , Claudio Cazorla , M. Anwar Hossain

Thermoelectrics are promising to address energy issues but their exploitation is still hampered by low efficiencies. So far, much improvement has been achieved by reducing the thermal conductivity but less by maximizing the power factor.…

High thermoelectric properties are associated with the phonon-glass electron-crystal paradigm. Conventional wisdom suggests that the optimal bandgap of semiconductor to achieve the largest power factor should be between 6 and 10 kbT. To…

The design of uranium-based thermoelectric materials presents a novel and intriguing strategy for directly converting nuclear heat into electrical power. Using high-level first-principles approach combined with accurate solution of…

材料科学 · 物理学 2019-12-30 Z. Z. Zhou , D. D. Fan , H. J. Liu , J. Liu

The thermoelectric power S and the thermal conductivity k of stoichiometric and vacancy-doped CaB6 have been measured between 5 and 300 K. The thermopower of both materials is surprisingly large at room temperature. Across the whole covered…

强关联电子 · 物理学 2007-05-23 K. Gianno' , A. V. Sologubenko , H. R. Ott , A. D. Bianchi , Z. Fisk
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