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The existence of heterogeneity in the dynamics of supercooled liquids is believed to be one of the hallmarks of the glass transition. Intense research has been carried out in the past to understand the origin of this heterogeneity in…

软凝聚态物质 · 物理学 2020-07-01 Indrajit Tah , Smarajit Karmakar

The viscosity of glass-forming liquids increases by many orders of magnitude if their temperature is lowered by a mere factor of 2-3 [1,2]. Recent studies suggest that this widespread phenomenon is accompanied by spatially heterogeneous…

无序系统与神经网络 · 物理学 2015-05-28 Walter Kob , Sandalo Roldan-Vargas , Ludovic Berthier

We examine the phenomenon of dynamical heterogeneity in computer simulations of an equilibrium, glass-forming liquid. We describe several approaches to quantify the spatial correlation of single-particle motion, and show that spatial…

软凝聚态物质 · 物理学 2009-09-25 Sharon C. Glotzer , Claudio Donati

We compare dynamical heterogeneities in equilibrated supercooled liquids and in the nonequilibrium glassy state within the framework of the random first order transition theory. Fluctuating mobility generation and transport in the glass are…

统计力学 · 物理学 2014-01-21 Apiwat Wisitsorasak , Peter G. Wolynes

Supercooled liquids display dynamics that are inherently heterogeneous in space. This essentially means that at temperatures below the melting point, particle dynamics in certain regions of the liquid can be orders of magnitude faster than…

软凝聚态物质 · 物理学 2021-01-04 Dipanwita Ghoshal , Ashwin Joy

Dynamic and structural heterogeneities play an important role in glass transition phenomena and in the formation of amorphous structures. Since structure and dynamics are mutually related, it is expected that there exists some relation…

Dynamic heterogeneity as one of the most important properties in supercooled liquids has been found for several decades. However, its structural origin remains open for many systems. Here, we propose a new structural parameter to…

无序系统与神经网络 · 物理学 2015-10-16 S. P. Pan , S. D. Feng , J. W. Qiao , W. M. Wang , J. Y. Qin

While deeply supercooled liquids exhibit divergent viscosity and increasingly heterogeneous dynamics as the temperature drops, their structure shows only seemingly marginal changes. Understanding the nature of relaxation processes in this…

材料科学 · 物理学 2022-11-03 Matthias Lerbinger , Armand Barbot , Damien Vandembroucq , Sylvain Patinet

As liquids approach the glass transition temperature, dynamical heterogeneity emerges as a crucial universal feature of their behavior. Dynamic facilitation, where local motion triggers further motion nearby, plays a major role in this…

As approaching the glass transition, particle motion in liquids becomes highly heterogeneous and regions with virtually no mobility coexist with liquid-like domains. This complex dynamics is believed to be responsible for different…

软凝聚态物质 · 物理学 2018-03-28 F. Puosi , N. Jakse , A. Pasturel

In this paper the phenomenon of dynamic heterogeneity in supercooled liquid systems is considered in terms of the recently proposed gauge theory of glass transition. The physical interpretation of the dynamic scaling is considered. It is…

统计力学 · 物理学 2015-06-23 Mikhail Vasin

Despite the use of glasses for thousands of years, the nature of the glass transition is still mysterious. On approaching the glass transition, the growth of dynamic heterogeneity has long been thought to play a key role in explaining the…

软凝聚态物质 · 物理学 2018-03-23 Lijin Wang , Ning Xu , W. H. Wang , Pengfei Guan

We combine the swap Monte Carlo algorithm to long multi-CPU molecular dynamics simulations to analyse the equilibrium relaxation dynamics of model supercooled liquids over a time window covering ten orders of magnitude for temperatures down…

软凝聚态物质 · 物理学 2022-12-16 Camille Scalliet , Benjamin Guiselin , Ludovic Berthier

We report an extensive and systematic investigation of the multi-point and multi-time correlation functions to reveal the spatio-temporal structures of dynamic heterogeneities in glass-forming liquids. Molecular dynamics simulations are…

软凝聚态物质 · 物理学 2013-01-04 Kang Kim , Shinji Saito

A few years ago it was showed that some systems that have very similar local structure, as quantified by the pair correlation function, exhibit vastly different slowing down upon supercooling [L. Berthier and G. Tarjus, Phys. Rev. Lett.…

软凝聚态物质 · 物理学 2015-06-17 Elijah Flenner , Hannah Staley , Grzegorz Szamel

We investigate the characteristic length scales associated with the glass transition phenomenon. By studying an atomic glass-forming liquid in negatively curved space, for which the local order is well identified and the amount of…

统计力学 · 物理学 2010-02-10 François Sausset , Gilles Tarjus

When a liquid is cooled below its melting temperature, if crystallization is avoided, it forms a glass. This phenomenon, called glass transition, is characterized by a marked increase of viscosity, about 14 orders of magnitude, in a narrow…

无序系统与神经网络 · 物理学 2008-08-23 Simone Capaccioli , Giancarlo Ruocco , Francesco Zamponi

We discuss a novel approach, the point-to-set correlation functions, that allows to determine relevant static and dynamic length scales in glass-forming liquids. We find that static length scales increase monotonically when the temperature…

无序系统与神经网络 · 物理学 2013-07-04 Walter Kob , Sandalo Roldan-Vargas , Ludovic Berthier

The most puzzling aspect of the glass transition observed in laboratory is an apparent decoupling of dynamics from structure. In this paper we recount the implication of various theories of glass transition for the static correlation length…

无序系统与神经网络 · 物理学 2017-02-08 S. Davatolhagh

We discuss the spatiotemporal behavior of local density and its relation to dynamical heterogeneity in a highly supercooled liquid by using molecular dynamics simulations of a binary mixture with different particle sizes in two dimensions.…

软凝聚态物质 · 物理学 2015-03-20 Hayato Shiba , Takeshi Kawasaki
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