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Liquid-phase exfoliation, the use of a sheared liquid to delaminate graphite into few-layer graphene, is a promising technique for the large-scale production of graphene. But the micro and nanoscale fluid-structure processes controlling the…

软凝聚态物质 · 物理学 2020-04-22 Simon Gravelle , Catherine Kamal , Lorenzo Botto

Graphene flakes were produced by nanosecond plasma discharge at atmospheric pressure between an electrode and the surface of distilled water, in which were placed graphite flakes. The discharge ionizes the gas and forms free radicals on the…

In the present work, the use of a commercial ionic liquid as a convenient solvent medium for graphite exfoliation in mild and easy conditions without any chemical modification is presented. To confirm the presence of few layer graphene, its…

Bulk quantities of graphene nanosheets and nanodots have been selectively fabricated by mechanical grinding exfoliation of natural graphite in a small quantity of ionic liquids. The resulting graphene sheets and dots are solvent free with…

Graphene stands as a promising material with vast potential across energy storage, electronics, etc. Here, we present a novel mechanical approach utilizing ultrasonic high-energy intercalation exfoliation to extract monolayer graphene from…

材料科学 · 物理学 2025-01-15 Kaitong Sun , Si Wu , Junchao Xia , Yinghao Zhu , Guanping Xu , Hai-Feng Li

Graphene is at the centre of nanotechnology research. In order to fully exploit its outstanding properties, a mass production method is necessary. Two main routes are possible: large-scale growth or large-scale exfoliation. Here, we…

Synthesis of graphene with reduced use of chemical reagents is essential for manufacturing scale-up and to control its structure and properties. In this paper, we report on a novel chemical-free mechanism of graphene exfoliation from…

Surfactants are often used to stabilise two-dimensional (2D) materials in environmentally friendly solvents such as water. Aqueous-surfactant solutions prevent agglomeration of nanosheets through steric and electrostatic repulsion,…

材料科学 · 物理学 2021-11-05 Diego Tomohisa Pérez-Álvarez , Philip Davies , Jason Stafford

Molecular dynamics (MD) simulations were performed to study the formation process of nanopores in a suspended graphene sheet irradiated by using energetic ions though a mask. By controlling the ion parameters including mass, energy and…

介观与纳米尺度物理 · 物理学 2016-03-10 Weisen Li , Li Liang , Shijun Zhao , Shuo zhang , Jianming Xue

High surface area graphene sheets were obtained by electrochemical exfoliation of graphite in an acid media under constant potential conditions. Filtration and centrifugation processes played an important role in order to obtain stable…

材料科学 · 物理学 2016-06-22 M. Hurtado-Morales , M. Ortiz , C. Acuna , H. C. Nerl , V. Nicolosi , Y. Hernandez

Liquid phase exfoliation (LPE) is the most promising method for the low-cost, scalable production of two-dimensional nanosheets from their bulk counterparts. Extensive exfoliation occurs in most solvents due to the huge amount of energy…

材料科学 · 物理学 2023-10-27 Urvesh Patil , Nuala M. Caffrey

Manganese oxide nanosheets were synthesized using liquid phase exfoliation that achieved suspensions in isopropanol with concentrations of up to 0.45 mg/ml. A study of solubility parameters showed that the exfoliation was optimum in DMF…

We investigated the effect of surfactants and their concentration (Csur) on the final graphene concentration (CG) via the liquid-phase exfoliation method. Six typical surfactants including ionic and non-ionic ones were explored and the…

材料科学 · 物理学 2016-06-14 Shuai Wang , Min Yi , Shuaishuai Liang , Zhigang Shen , Xiaojing Zhang , Shulin Ma

Porous graphene has high mechanical strength and atomic layer thickness, which make it a promising material for material separation and biomolecule sensing. Electrostatic interactions between charges in aqueous solution are a kind of strong…

化学物理 · 物理学 2016-08-02 Yinghua Qiu , Kun Li , Weiyu Chen , Wei Si , Qiyan Tan , Yunfei Chen

This work describes the behaviour of water molecules in 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid under nanoconfinement between graphene sheets. By means of molecular dynamics simulations, an adsorption of water molecules…

In liquid-phase exfoliation for the production of 2D nanomaterials fluid forces are used to gently overcome adhesive interlayer forces, leading to single- or few-layer 2D nanomaterials. Predicting accurately the critical fluid shear rate…

软凝聚态物质 · 物理学 2019-12-19 Lorenzo Botto

Graphene-based membranes have been investigated as promising candidates for water filtration and gas separation applications. Experimental evidences have shown that graphene oxide can be impermeable to liquids, vapors and gases, while…

Bulk applications of graphene in fields such as advanced composites, conductive ink, and energy storage require cheap and scalable graphene. Fortunately, in the last decade, liquid-phase exfoliation of graphite to give pristine graphene has…

材料科学 · 物理学 2016-08-22 Min Yi , Zhigang Shen

Owing to wide variety of applications of graphene, high-quality and economical way of synthesizing graphene is highly desirable. In this study, we report a cost effective and simple approach to production of high-quality graphene. Here the…

材料科学 · 物理学 2013-10-29 Prashant Tripathi , Ch. Ravi Prakash Patel , M. A. Shaz , O. N. Srivastava

The extreme sensitivity of 2D materials to defects and nanostructure requires precise imaging techniques to verify presence of desirable and absence of undesirable features in the atomic geometry. Helium-ion beams have emerged as a…

材料科学 · 物理学 2022-05-19 Alina Kononov , Alexandra Olmstead , Andrew D. Baczewski , Andre Schleife
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