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We investigate the impact of various levels of approximation in density functional theory calculations for the structural and binding properties of the prototypical halide perovskite MAPbI$_3$. Specifically, we test how the inclusion of…

材料科学 · 物理学 2019-03-04 Hubert Beck , Christian Gehrmann , David A. Egger

Mixed-halide perovskites offer a route to enhance phase stability and modify optoelectronic properties. Here, we use large-scale molecular dynamics simulations with a reactive force field to investigate defects in…

材料科学 · 物理学 2026-05-12 Konrad Wilke , Mike Pols , Titus S. van Erp , Geert Brocks , Shuxia Tao

The Rashba effect is one of the most striking manifestations of spin-orbit coupling in solids, and provides a cornerstone for the burgeoning field of semiconductor spintronics. It is typically assumed to manifest as a momentum-dependent…

Recently, replacing or mixing organic molecules in the hybrid halide perovskites with the inorganic Cs or Rb cations has been reported to increase the material stability with the comparable solar cell performance. In this work, we…

材料科学 · 物理学 2018-09-19 Un-Gi Jong , Chol-Jun Yu , Yun-Sim Kim , Yun-Hyok Kye , Chol-Ho Kim

Organic-inorganic halide CH$_3$NH$_3$PbI$_3$ solar cells have attracted enormous attention in recent years due to their remarkable power conversion efficiency. When inversion symmetry is broken, these materials should exhibit interesting…

介观与纳米尺度物理 · 物理学 2016-05-10 Junwen Li , Paul M. Haney

Strong Rashba effects at surfaces and interfaces have attracted great attention for basic scientific exploration and practical applications. Here, the first-principles investigation shows that giant and tunable Rashba effects can be…

材料科学 · 物理学 2025-07-11 Ning Wu , Xue-Jing Zhang , Bang-Gui Liu

Lead halide perovskites are causing a change of paradigm in photovoltaics. Among other peculiarities, these perovskites exhibit an atypical temperature dependence of the fundamental optical gap: It decreases in energy with decreasing…

The manipulation of the Rashba spin-splitting is crucial for the development of nanospintronic technology. Here, it is proposed that the Rashba spin-splitting can be turned on and off by reversing electric-field direction. By the…

材料科学 · 物理学 2022-09-30 San-Dong Guo , Jing-Xin Zhu , Hao-Tian Guo , Bing Wang , Guang-Zhao Wang , Yee-Sin Ang

Halide perovskite (HP) semiconductors exhibit unique strong coupling between the electronic and structural dynamics. The high-temperature cubic phase of HPs is known to be entropically stabilized, with imaginary frequencies in the…

Metal halide perovskites (MHPs) exhibit pronounced spin-orbit coupling (SOC) as a result of their heavy metal constituents, leading to distinctive electronic properties such as Rashba type band splitting which make them promising candidates…

材料科学 · 物理学 2025-12-09 Sushovan Sarkar , Koushik Gayen , Ashish Soni , Suman Kalyan Pal

Extensive efforts have been undertaken on the photoelectric physics of hybrid organolead halide perovskites to unveil the reason for the attractive photovoltaic performance. Yet, the resulting evidences are far from being fully conclusive.…

Mixing iodide and bromide in halide perovskite semiconductors is an effective strategy to tune their bandgap, therefore mixed-halide perovskites hold great promise for color-tunable LEDs and tandem solar cells. However, the bandgap of…

Despite the tremendous interest in halide perovskites in solar cells, the reason that the all-inorganic perovskite CsPbI$_3$ is unstable at room temperature remains mysterious. Here single-crystal X-ray diffraction and powder pair…

材料科学 · 物理学 2020-07-08 Daniel B. Straus , Shu Guo , Milinda Abeykoon , Robert J. Cava

Strong spin-orbit coupling in noncentrosymmetric materials and interfaces results in remarkable physical phenomena, such as nontrivial spin textures, which may exhibit Rashba, Dresselhaus, and other intricated configurations. This provides…

介观与纳米尺度物理 · 物理学 2021-11-15 Thorsten Aull , Igor V. Maznichenko , Sergey Ostanin , Ersoy Şaşıoğlu , Ingrid Mertig

Time- and Angle-Resolved Photoelectron Spectroscopy (tr-ARPES) is employed to monitor photoexcited electrons in the two-dimensional hybrid perovskite (BA)$_2$(MA)$_2$Pb$_3$I$_{10}$. Photoelectron intensity maps are in good agreement with…

The hybrid halide perovskite CH$_{3}$NH$_{3}$PbI$_{3}$ has enabled solar cells to reach an efficiency of about 18\%, demonstrating a pace for improvements with no precedents in the solar energy arena. Despite such explosive progress, the…

材料科学 · 物理学 2015-05-20 Carlo Motta , Fedwa El Mellouhi , Sabre Kais , Nouar Tabet , Fahhad Alharbi , Stefano Sanvito

We investigate thermoelectric properties of a ferromagnet-superconductor hybrid structure with Rashba spin-orbit interaction and delta function potential barrier at the interfacial layer. The exponential rise of thermal conductance with…

介观与纳米尺度物理 · 物理学 2017-09-07 Paramita Dutta , Arijit Saha , A. M. Jayannavar

Rashba spin-orbit coupling significantly modifies the electronic band structure in two-dimensional (2D) van der Waals (vdW) heterobilayers, which may enhance their thermoelectric (TE) properties. In this study, we use first-principles…

材料科学 · 物理学 2025-04-24 Vuong Van Thanh , Nguyen Tuan Hung

We demonstrate theoretically that non-chiral perovskite layers can exhibit circular dichroism (CD) in the absence of a magnetic field and without chiral activation by chiral molecules. The effect is shown to be due to splitting of helical…

介观与纳米尺度物理 · 物理学 2024-12-03 Peter C. Sercel , Zeev Valy Vardeny , Alexander L. Efros

We intercalate a van der Waals heterostructure of graphene and hexagonal Boron Nitride with Au, by encapsulation, and show that Au at the interface is two dimensional. A charge transfer upon current annealing indicates redistribution of Au…

介观与纳米尺度物理 · 物理学 2016-08-24 E. C. T. O'Farrell , J. Y. Tan , Y. Yeo , G. K. W. Koon , K. Watanabe , T. Taniguchi , B. Özyilmaz