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In photovoltaic diodes recombination of photogenerated electrons and holes is a major loss process. Biological light harvesting complexes (LHCs) prevent recombination via the use of cascade structures, which lead to spatial separation of…

The determination of transport mechanisms in organic light-emitting diodes (OLEDs) is crucial for optimizing device performance. Magnetic field measurements enable the differentiation of spin state interconversion mechanisms, but data…

The kinetics of the charge carrier recombination in dye molecule-doped multilayer organic light-emitting diodes (OLEDs) was quantified by transient electroluminescence (EL). Three sets of dye molecules, such as derivatives of naphthalimide…

材料科学 · 物理学 2014-11-13 Shengwei Shi , Feng Gao , Zhengyi Sun , Yiqiang Zhan , Mats Fahlman , Dongge Ma

Angle-independent, narrowband emission is required for many optoelectronic devices, ranging from high-definition displays to sensors. However, emerging materials for electroluminescent devices, such as organics and perovskites, show…

光学 · 物理学 2023-03-17 Andreas Mischok , Sabina Hillebrandt , Seonil Kwon , Malte C. Gather

Quantum-dot light-emitting diodes (QD-LEDs) promise a new generation of efficient, low-cost, large-area, and flexible electroluminescent devices. However, the inferior performance of green and blue QD-LEDs is hindering the commercialization…

Carbene-metal-amide type photoemitters based on CF$_3$-substituted carbazolate ligands show sky-blue to deep-blue photoluminescence from charge-transfer excited states. They are suitable for incorporation into organic light-emitting diodes…

Organic light emitting diodes (OLEDs) based on thermally activated delayed fluorescence (TADF) utilize molecular systems with a small energy splitting between singlet and triplet states. This can either be realized in intramolecular charge…

This work reports our effort on understanding the efficiency roll-off in blue phosphorescent organic light-emitting diodes (OLEDs), based on a blue phosphorescence from bis(3,5-difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl)- iridium…

材料科学 · 物理学 2014-10-27 Wenyu Ji , Furong Zhu

Closed-shell light-emitting diodes (LEDs) suffer from the internal quantum efficiency (IQE) limitation imposed by optically inactive triplet excitons. Here we show an undiscovered emission mechanism of lead-halide-perovskites (LHPs)…

材料科学 · 物理学 2020-12-21 Chang Woo Myung , Kwang S. Kim

Engineering the position of the lowest triplet state (T1) relative to the first excited singlet state (S1) is of great importance in improving the efficiencies of organic light emitting diodes and organic photovoltaic cells. We have carried…

化学物理 · 物理学 2014-06-11 Suryoday Prodhan , Zoltan G. Soos , S. Ramasesha

Spin-spin interactions in organic light-emitting diodes (OLEDs) based on thermally activated delayed fluorescence (TADF) are pivotal because radiative recombination is largely determined by triplet-to-singlet conversion, also called reverse…

Organic light emitting diodes (OLEDs) based on thermally activated delayed fluorescence (TADF) can be highly efficient because of the conversion of non-radiative triplet to radiative singlet states by reverse intersystem crossing (RISC).…

Control of the band-edge offsets at heterojunctions between organic semiconductors allows efficient operation of either photovoltaic or light-emitting diodes. We investigate systems where the exciton is marginally stable against charge…

软凝聚态物质 · 物理学 2013-09-27 Arne C. Morteani , Paiboon Sreearunothai , Laura M. Herz , Richard H. Friend , Carlos Silva

Excitons are composite bosons that can feature spin singlet and triplet states. In usual semiconductors, without an additional spin-flip mechanism, triplet excitons are extremely inefficient optical emitters. Large spin-orbit coupling in…

Asymmetrical horizontal interdot coupling was demonstrated to exist in a system of a single plane of self-assembled CdTe/ZnTe quantum dots. Photoluminescence excitation (PLE), second order photon correlation and optical orientation were…

其他凝聚态物理 · 物理学 2009-06-12 T. Kazimierczuk , J. Suffczynski , P. Wojnar , A. Golnik , J. A. Gaj , P. Kossacki

This paper presents a possible explanation for the enhanced singlet exciton yield in light emitting polymers. We propose a theory of electron-hole recombination via inter-molecular inter-conversion from inter-molecular weakly bound polaron…

化学物理 · 物理学 2009-11-10 William Barford

Organic light-emitting diodes (OLEDs) are the leading self-emitting pixel technology in current and future small and large area displays. Once integrated with a certain layer architecture into the backplane layout, their emission colour and…

应用物理 · 物理学 2019-06-07 Felix Fries , Markus Fröbel , Pen Yiao Ang , Simone Lenk , Sebastian Reineke

The maximum efficiency in organic light-emitting diodes (OLEDs) depends on the ratio, $r=k_S/k_T$, where $k_S$ ($k_T$) is the singlet (triplet) exciton formation rate. Several recent experiments found that r increases with increasing…

软凝聚态物质 · 物理学 2009-11-10 Markus Wohlgenannt

At low temperatures and high magnetic fields, electron and hole spins in an organic light-emitting diode (OLED) become polarized so that recombination preferentially forms molecular triplet excited-state species. For low device currents,…

介观与纳米尺度物理 · 物理学 2021-04-28 Tobias Scharff , Wolfram Ratzke , Jonas Zipfel , Philippe Klemm , Sebastian Bange , John M. Lupton

Considerable progress has been made in organic light-emitting diodes (OLEDs) to achieve high external quantum efficiency (EQE), among which the dipole orientation of OLED emitters has a remarkable effect. In most cases, EQE of the OLED…