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Mixed iodine-bromine perovskites used in solar cells undergo below a critical temperature an intrinsic demixing into phases with different iodine-bromine compositions. In addition, under illumination they show nucleation of an iodine-rich…

材料科学 · 物理学 2022-11-09 Zehua Chen , Geert Brocks , Shuxia Tao , Peter A. Bobbert

Perovskite semiconductors have demonstrated outstanding external luminescence quantum yields, enabling high power conversion efficiencies (PCE). However, the precise conditions to advance to an efficiency regime above monocrystalline…

The coherence of collective modes, such as phonons, and their modulation of the electronic states are long sought in complex systems, which is a cross-cutting issue in photovoltaics and quantum electronics. In photovoltaic cells and lasers…

材料科学 · 物理学 2020-03-23 Z. Liu , C. Vaswani , L. Luo , D. Cheng , X. Yang , X. Zhao , Y. Yao , Z. Song , R. Brenes , R. Kim , J. Jean , V. Bulovic , Y. Yan , K. -M. Ho , J. Wang

Methylammonium lead iodide (MAPI) is a benchmark hybrid organic perovskite material, which is used for the low-cost, printed solar cells with over 20 percent power conversion efficiency. Yet, the nature of light-matter interaction in MAPI…

Inverted perovskite solar cells (PSCs) using a Cu:NiOx hole transporting layer (HTL) often exhibit stability issues and in some cases J/V hysteresis. In this work, we developed a \b{eta}-alanine surface treatment process on Cu:NiOx HTL that…

Single-crystalline ferroelectric (FE) perovskites show a large electrocaloric effect at electric field-induced phase transitions, promising for solid-state cooling technologies. However, paraelectric-FE transition temperatures are often too…

材料科学 · 物理学 2024-10-03 Lan-Tien Hsu , Frank Wendler , Anna Grünebohm

Recent advances of highly efficient solar cells based on organic-inorganic halide perovskites have triggered intense research efforts to establish the fundamental properties of these materials. In this work, we utilized diamond anvil cell…

材料科学 · 物理学 2015-09-15 Kai Wang , Ran Liu , Yuancun Qiao , Jinxing Cui , Bo Song , Bingbing Liu , Bo Zou

Halide segregation in metal halide perovskites limits their bandgap tunability and hinders their adoption in tandem solar cells and light emitting diodes. Here, we reveal the thermodynamic driving force behind halide segregation in mixed…

材料科学 · 物理学 2026-03-10 Abrar Fahim Navid , Zeeshan Ahmad

Organometallic lead halide perovskites are highly efficient materials for solar cells and other optoelectronic applications due to their high quantum efficiency and exceptional semiconducting properties. A peculiarity of these perovskites…

Historically, the design of hybrid solar photovoltaic thermal (PVT) systems has focused on cooling crystalline silicon (c-Si)-based photovoltaic (PV) devices to avoid temperature-related losses. This approach neglects the associated…

材料科学 · 物理学 2012-08-09 M. J. M Pathak , K. Girotra , S. J. Harrison , J. M. Pearce

Mixed-halide perovskites (MHPs) offer good band gap tunability by stoichiometry changes, which is an essential property for the creation of multijunction solar cells. However, under illumination, halide ions in MHP segregate and create I-…

Organic-inorganic halide perovskite materials have emerged as attractive alternatives to conventional solar cell building blocks. Their high light absorption coefficients and long diffusion lengths suggest high power conversion efficiencies…

Organic-inorganic hybrid perovskites (OIHPs) exhibiting exceptional photovoltaic and optoelectronic properties are of fundamental and practical interest, owing to their tunability and low manufacturing cost. For practical applications,…

Halide perovskites show unusual thermalisation kinetics for above bandgap photo-excitation. We explain this as a consequence of excess energy being deposited into discrete large polaron states. The cross-over between low-fluence and…

材料科学 · 物理学 2017-12-07 Jarvist Moore Frost , Lucy D. Whalley , Aron Walsh

The oxide heterostructure [(YFeO$_3$)$_5$(LaFeO$_3$)$_5$]$_{40}$, which is magnetically ordered and piezoelectric at room temperature, has been constructed from two weak ferromagnetic AFeO$_3$ perovskites with different A cations using…

Efficient semi-transparent solar cells can trigger the adoption of building integrated photovoltaics. Halide perovskites are particularly suitable in this respect owing to their tunable bandgap. Main drawbacks in the development of…

Two-dimensional (2D) halide perovskites (HPs) are promising materials for various optoelectronic applications, yet a comprehensive understanding of their dynamics is still elusive. Here, we offer insight into the dynamics of prototypical 2D…

材料科学 · 物理学 2024-08-15 Erik Fransson , Julia Wiktor , Paul Erhart

Charge transport layers (CTLs) are key components of diffusion controlled perovskite solar cells, however, they can induce additional non-radiative recombination pathways which limit the open circuit voltage (V_OC) of the cell. In order to…

A model is derived for the frequency- and time-domain opto-electronic response of perovskite solar cells (PSCs) that emphasizes the role of charge carrier exchange, .i.e. extraction and injection, from (to) the perovskite through the…

材料科学 · 物理学 2023-11-10 Sandheep Ravishankar , Zhifa Liu , Yueming Wang , Thomas Kirchartz , Uwe Rau

We investigate the origin of the hysteresis observed in the transfer characteristics of back-gated field-effect transistors with an exfoliated MoS2 channel. We find that the hysteresis is strongly enhanced by increasing either gate voltage,…

介观与纳米尺度物理 · 物理学 2017-10-24 Antonio Di Bartolomeo , Luca Genovese , Filippo Giubileo , Laura Iemmo , Giuseppe Luongo , Tobias Foller , Marika Schleberger