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Nanoparticles with hydrophobic capping ligands and amphiphilic phospholipids are both found to self-assemble into monolayer films when deposited on the air water interface. By separately measuring the anisotropic stress response of these…

Bio-conjugated nanomaterials play a promising role in the development of novel supramolecular structures, molecular machines, and biosensing devices. In this study, lipid-conjugated gold nanoparticles were synthesized and allowed to form a…

材料科学 · 物理学 2012-07-24 Subhasish Chatterjee , Markrete Krikorian , Harry D. Gafney , Bonnie Gersten

Hypothesis: Introducing charged terminal groups to polymers that graft nanoparticles enables Coulombic control over their assembly by tuning the pH and salinity of aqueous suspensions. Experiments: Gold nanoparticles (AuNPs) are grafted…

We report the results of molecular dynamics simulations of the properties of a pseudo-atom model of dodecane thiol ligated 5-nm diameter gold nanoparticles (AuNP) in vacuum as a function of ligand coverage and particle separation in three…

化学物理 · 物理学 2019-02-20 Christopher Liepold , Alex Smith , Binhua Lin , Juan de Pablo , Stuart A. Rice

Chemically-reduced graphene-oxide-supported gold nanoparticles are considered here as catalytic materials for the reduction of oxygen in alkaline medium. Gold nanoparticles are prepared by the chemical reduction method, in which the…

Monolayer-protected gold nanoparticles (Au NPs) are promising biomedical tools with applications to diagnosis and therapy, thanks to their biocompatibility and versatility. Here we show how the NP surface functionalization can drive the…

生物大分子 · 定量生物学 2019-06-20 Sebastian Salassi , Ester Canepa , Riccardo Ferrando , Giulia Rossi

The ion-lipid interface in Langmuir monolayers of Dipalmitoylphosphatidylcholine (DPPC) on pure water and 10 mM solutions of Na+ and K+ at different [K+]/[Na+] (a), atom/atom ratios, were studied initially by Surface Pressure (p) versus…

Atomically thin materials exhibit electronic and optical properties distinct from their three-dimensional counterparts. For metals, particularly gold, monolayer studies remain largely unexplored due to fabrication and characterisation…

The investigation of the Localized Surface Plasmon Resonance for plasmonic nanoparticles has opened new perspectives for optical nanosensors. Today, an issue in plasmonics is the development of large scale and low cost devices. We focus…

介观与纳米尺度物理 · 物理学 2013-04-23 S. Lamarre , A. Sarrazin , J. Proust , H. Yockell-Lelièvre , J. Plain , A. M. Ritcey , T. Maurer

In recent years, nanostructures with hexagonal polytypes of gold have been synthesised, opening new possibilities in nanoscience and technology. As bulk gold crystallizes in the \textit{fcc} phase, surface effects can play an important role…

Real time electron microscopy observation on morphological changes in gold nano structures deposited on Si (100) surfaces as a function of annealing temperatures has been reported. Two types of interfaces with the substrate silicon were…

介观与纳米尺度物理 · 物理学 2017-11-27 Ashutosh Rath , J. K. Dash , R. R. Juluri , A Rosenauer , P V Satyam

In the present work, the formation of silver and copper nanostructures on highly oriented pyrolytic graphite (HOPG) modified with self-assembled gold nanoparticles (Au NPs) is demonstrated. Surface patterning with nanometer resolution was…

介观与纳米尺度物理 · 物理学 2017-10-05 A. Taleb , V. Ivanova

In this work, we combine electron microscopy measurements of the surface compositions in Cu-Au nanoparticles and atomistic simulations to investigate the effect of gold segregation. While this mechanism has been extensively investigated…

The dependence of the structure of a phospholipid layer (DSPC and SOPC) adsorbed on a hydrosol substrate on the concentration of NaOH in a solution of 5-nm silica particles has been studied by X-ray reflectrometry with the use of…

软凝聚态物质 · 物理学 2015-12-07 Aleksey M. Tikhonov , Viktor E. Asadchikov , Yuri O. Volkov

We present results of an x-ray study of structural properties of semicrystalline polymer films using nanofocused x-ray beam. We applied the x-ray cross-correlation analysis (XCCA) to scattering data from blends of poly(3-hexylthiophene)…

Nanoporous gold (np-Au) has found use in applications ranging from catalysis to biosensing where pore morphology plays a critical role in performance. While morphology evolution of bulk np-Au has been widely studied, knowledge about its…

材料科学 · 物理学 2024-02-20 Sadi Shahriar , Kavya Somayajula , Conner Winkeljohn , Jeremy Mason , Erkin Seker

A mesoscale model with molecular resolutions is presented for the dipalmitoyl-phosphatidylcholine (DPPC) and 1-palmitoyl-2-oleyl-sn-glycero-3-phosphocholine (POPC) monolayer simulations at the air-water interface using many-body dissipative…

生物物理 · 物理学 2025-08-06 Yongzheng Zhu , Xuan Bai , Guoqing Hu

This study presents the results of atomistic structural characterisation of 3.7 nm diameter gold nanoparticles (NP) coated with polymer polyethylene glycol (PEG)-based ligands of different lengths (containing $2-14$ monomers) and solvated…

原子与分子团簇 · 物理学 2023-09-07 Matthew D. Dickers , Alexey V. Verkhovtsev , Nigel J. Mason , Andrey V. Solov'yov

Gold nanoparticles (AuNPs) play an important role in fundamental research and development due to their versatile applications and biocompatibility. This study addresses the aging of three AuNP suspensions after the addition of various…

软凝聚态物质 · 物理学 2025-02-04 Philipp Ritzert , Alexandra Striegel , Regine von Klitzing

The development of simple, versatile strategies for the synthesis of gold nanoparticles (AuNPs) on semiconducting transition metal dichalcogenides (TMDC) layers is of increasing scientific and technological interest in photocatalysis,…

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