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The phase transition behaviour of PbTiO3 and BaTiO3 under (111) epitaxial strain is investigated using density-functional theory calculations. From tensile strains of +0.015 to compressive strains of -0.015, PbTiO3 undergoes phase…

材料科学 · 物理学 2009-11-13 Riku Oja , Karen Johnston , Johannes Frantti , Risto M. Nieminen

Reversible topotactic transitions between oxygen-vacancy-ordered structures in transition metal oxides provide a promising strategy for active manipulation of material properties. While transformations between various oxygen-deficient…

材料科学 · 物理学 2020-05-06 Sampo Inkinen , Lide Yao , Sebastiaan van Dijken

The sensitivity of materials properties, particularly those of perovskite oxides, to epitaxial strain has been exploited to great advantage to create materials with new or enhanced properties. Although it has certainly been recognized that…

材料科学 · 物理学 2020-09-09 Ethan T. Ritz , Nicole A. Benedek

Phase change materials (PCMs) that exhibit volatile resistive switching are promising for emulating neuronal oscillators. Charge transfer insulators, such as ReNiO3 (where Re represents rare earth metals like Pr, Nd, Sm, Eu...), form a…

材料科学 · 物理学 2024-10-31 Prashanth S , Binoy Krishna De , Shubham Kumar Parate , Kartick Biswas , Pavan Nukala

A novel approach for finding new transparent conductors involves taking advantage of electronic correlations in metallic transition metal oxides, such as SrVO$_3$, to enhance the electronic effective mass and suppress the plasma frequency…

材料科学 · 物理学 2019-08-28 Arpita Paul , Turan Birol

The correlation between ex situ electronic conductivity, oxygen vacancy content, flat-band potential (Efb), and the oxygen evolution reaction (OER) activity for a wide range of perovskite compositions are investigated experimentally and…

We use density functional theory plus dynamical mean-field theory (DFT+DMFT) to study multiple control parameters for tuning the metal-insulator transition (MIT) in CaVO$_3$ thin films. We focus on separating the effects resulting from…

强关联电子 · 物理学 2018-02-14 Sophie Beck , Gabriele Sclauzero , Uday Chopra , Claude Ederer

We study the effect of substrate induced strain on the structural, transport, optical and electronic properties of Sr$_2$CoNbO$_6$ double perovskite thin films. The reciprocal space mapping, $\phi$-scan and high-resolution…

With recent advances in strain engineering and its widespread applications, it is becoming increasingly important to understand the effect of biaxial strain on the most common structural phase of perovskites -- the orthorhombic $Pnma$…

材料科学 · 物理学 2023-11-23 Amartyajyoti Saha , Turan Birol

We report on a systematic study of strain effects on the transport properties and the ferromagnetic transition temperature $T_{c}$ of high-quality La$_{0.9}$Sr$_{0.1}$MnO$_{3}$ thin films epitaxially grown on (100) SrTiO$_{3}$ substrates.…

材料科学 · 物理学 2009-11-07 X. J. Chen , S. Soltan , H. Zhang , H. -U. Habermeier

Effect of biaxial tensile strains on optical functions and band edge transitions of ultra thin epitaxial films was studied using as an example a 13 nm thick SrTiO3 films deposited on KTaO3(100) single-crystal substrates. Optical functions…

材料科学 · 物理学 2015-05-14 A. Dejneka , M. Tyunina , J. Narkilahti , J. Levoska , D. Chvostova , L. Jastrabik , V. A. Trepakov

We report a strong thickness dependence of the complex frequency-dependent optical dielectric function in epitaxial CaMnO3(001) thin films on SrTiO3(001), LaAlO3(001), and SrLaAlO4(001) substrates. A doubling of the peak value of the…

Since the discovery of two-dimensional (2D) electron gas in LaAlO3/SrTiO3 interface, 2D carrier gases in perovskite oxides have attracted great attention because they can host many important phenomena and may produce novel functional…

材料科学 · 物理学 2019-06-05 Xue-Jing Zhang , Bang-Gui Liu

Double-perovskite oxides have attracted recent attention due to their attractive functionalities and application potential. In this paper, we demonstrate the effect of dual controls, i.e., the deposition pressure of oxygen (P$_O2$) and…

强关联电子 · 物理学 2023-04-27 Z. T. Zhang , H. Yan , Z. Huang , X. Chi , C. J. Li , Z. S. Lim , S. W. Zeng , K. Han , G. J. Omar , K. X. Jin , A. Ariando

The discovery of superconductivity in bilayer nickel-oxides has revived an intense effort to understand the potential of high-temperature superconductivity in these materials and their relation to cuprate superconductors. In this work, we…

强关联电子 · 物理学 2026-03-31 Deepak Kumar , Jared Z. Dans , Keenan E. Avers , Ryan Paxson , Ichiro Takeuchi , Johnpierre Paglione

Using spectroscopic ellipsometry, we studied the optical conductivity of LaCoO$_3$ with various degrees of strain. The optical response of the compressively strained \lco\ film is qualitatively similar to the one of the unstrained LaCoO$_3$…

强关联电子 · 物理学 2025-03-13 F. Abadizaman , M. Kiaba , A. Dubroka

La-based perovskites are a versatile class of materials that are of interest for solid oxide fuel cells and electrocatalytic water splitting. During fabrication of composition spread materials libraries of La-Co-based oxide systems for the…

Atomically precise superlattices involving transition metal oxides provide a unique opportunity to engineer correlated electron physics using strain (modulated by choice of substate) and quantum confinement (controlled by layer thickness).…

强关联电子 · 物理学 2016-06-15 Hyowon Park , Andrew J. Millis , Chris A. Marianetti

Manganite perovskites host emerging physical properties of strongly-correlated electrons with charge, spin, and lattice degrees of freedom. Using epitaxial lift-off technique, we report enhancement of saturation magnetization and…

强关联电子 · 物理学 2023-11-27 Ryuji Atsumi , Junichi Shiogai , Takumi Yamazaki , Takeshi Seki , Kohei Ueda , Jobu Matsuno

We report the effect of epitaxial strain on the magnitude and retention of the ferroelectric field effect in high quality PbZr$_{0.3}$Ti$_{0.7}$O$_3$ (PZT)/3.8-4.3 nm Sm$_{0.5}$Nd$_{0.5}$NiO$_3$ (SNNO) heterostructures grown on (001)…

强关联电子 · 物理学 2015-10-28 L. Zhang , X. G. Chen , H. J. Gardner , M. A. Koten , J. E. Shield , X. Hong