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Magnetic resonance imaging at microtesla fields is a promising imaging method that combines the pre-polarization technique and broadband signal reception by SQUID sensors to enable in vivo MRI at microtesla-range magnetic fields. Despite…

医学物理 · 物理学 2010-10-18 V. S. Zotev , T. Owens , A. N. Matlashov , I. M. Savukov , J. J. Gomez , M. A. Espy

Dynamic nuclear polarization (DNP) is an NMR sensitivity enhancement technique that mediates polarization transfer from unpaired electrons to NMR-active nuclei. Despite its success in elucidating important structural information on…

Dynamic nuclear polarization (DNP) is an important method to enhance the limited sensitivity of nuclear magnetic resonance (NMR). Using the existing mechanisms such as Overhauser DNP (ODNP) is still difficult to achieve significant…

化学物理 · 物理学 2025-03-31 Maria Grazia Concilio , Yiwen Wang , Linjun Wang , Xueqian Kong

Dynamic nuclear polarisation (DNP) refers to a class of techniques used to increase the signal in nuclear magnetic resonance measurements by transferring spin polarisation from ensembles of highly polarised electrons to target nuclear…

量子物理 · 物理学 2020-12-24 L. T. Hall , D. A. Broadway , A. Stacey , D. A. Simpson , J-P. Tetienne , L. C. L. Hollenberg

Dynamic nuclear polarization (DNP) enhances nuclear magnetic resonance (NMR) signals by transferring electron spin polarization to nuclei. As DNP requires microwave magnetic fields B1 strong enough to saturate electron spins, microwave…

Dynamic Nuclear Polarization (DNP) has enabled enormous gains in magnetic resonance signals and led to vastly accelerated NMR/MRI imaging and spectroscopy. Unlike conventional cw-techniques, DNP methods that exploit the full electron…

应用物理 · 物理学 2018-11-27 A. Ajoy , R. Nazaryan , K. Liu , X. Lv , B. Safvati , G. Wang , E. Druga , J. A. Reimer , D. Suter , C. Ramanathan , C. A. Meriles , A. Pines

Magnetic resonance imaging in ultra-low fields is often limited by mediocre signal-to-noise ratio hindering a higher resolution. Overhauser dynamic nuclear polarisation (O-DNP) using nitroxide radicals has been an efficient solution for…

Dynamic nuclear polarization (DNP) has revolutionized the field of NMR spectroscopy, expanding its reach and capabilities to investigate diverse materials, biomolecules, and complex dynamic processes. Bringing high-efficiency DNP to the…

介观与纳米尺度物理 · 物理学 2024-02-27 Sahand Tabatabaei , Pritam Priyadarsi , Namanish Singh , Pardis Sahafi , Daniel Tay , Andrew Jordan , Raffi Budakian

J-driven Dynamic Nuclear Polarization (JDNP) was recently proposed for enhancing the sensitivity of solution-state nuclear magnetic resonance (NMR), while bypassing the limitations faced by conventional (Overhauser) DNP at magnetic fields…

化学物理 · 物理学 2023-01-03 Maria Grazia Concilio , Lucio Frydman

Dynamic Nuclear Polarization (DNP) is a powerful suite of techniques that deliver multifold signal enhancements in NMR and MRI. The generated athermal spin states can also be exploited for quantum sensing and as probes for many-body…

Dynamic nuclear polarization is widely used to enhance the sensitivity of nuclear magnetic resonance. It is presently the method of choice for enhancing the sensitivity of high-field solid state NMR experiments performed under cryogenic…

化学物理 · 物理学 2022-02-02 Maria Grazia Concilio , Ilya Kuprov , Lucio Frydman

Dynamic nuclear polarization (DNP) is a promising strategy for generating a significantly increased non-thermal spin polarization in nuclear magnetic resonance (NMR) applications thereby circumventing the need for strong magnetic fields.…

量子物理 · 物理学 2015-07-15 Alexander Karabanov , Daniel Wisniewski , Igor Lesanovsky , Walter Köckenberger

Dynamic nuclear polarization (DNP) is used in nuclear magnetic resonance (NMR) to transfer polarization from electron spins to nuclear spins. The resulting nuclear polarization enhancement can, in theory, be two or three orders of magnitude…

量子物理 · 物理学 2015-10-14 Sarah Sheldon , David G. Cory

One of solution-state Nuclear Magnetic Resonance (NMR)'s main weaknesses, is its relative insensitivity. J-driven Dynamic Nuclear Polarization (JDNP) was recently proposed for enhancing the sensitivity of solution-state NMR, by bypassing…

化学物理 · 物理学 2023-08-07 Maria Grazia Concilio , Lucio Frydman

Dynamic nuclear polarization (DNP) is a method of enhancing NMR signals via the transfer of polarization from electron spins to nuclear spins using on-resonance microwave (MW) irradiation. In most cases, monochromatic continuous-wave (MCW)…

化学物理 · 物理学 2022-11-17 Daphna Shimon , Kelly A. Cantwell , Linta Joseph , Chandrasekhar Ramanathan

We introduce a novel NMR approach that extends the capabilities of indirect dynamic nuclear polarization (DNP) under magic-angle spinning to probe the local environment of half-integer spin quadrupolar nuclei. Compared to…

Dynamic Nuclear Polarization (DNP) presently stands as the preferred strategy to enhance the sensitivity of nuclear magnetic resonance measurements, but its application relies on the use of high-frequency microwave to manipulate electron…

介观与纳米尺度物理 · 物理学 2022-02-02 Carlos A. Meriles , Pablo R. Zangara

Dynamic Nuclear Polarization (DNP) is to date the most effective technique to increase the nuclear polarization up to a factor $100,000$ opening disruptive perspectives for medical applications. In DNP, the nuclear spins are driven to an -…

强关联电子 · 物理学 2015-08-26 Andrea De Luca , Alberto Rosso

Nuclear magnetic resonance (NMR) spectroscopy is a widely used tool for chemical analysis and molecular structure identification. Because it typically relies on the weak magnetic fields produced by a small thermal nuclear spin polarization,…

We propose a new, more efficient, and potentially cost effective, solid-state nuclear spin hyperpolarization method combining the Cross Effect mechanism and electron spin optical hyperpolarization in rotating solids. We first demonstrate…

量子物理 · 物理学 2022-01-25 Frederic Mentink-Vigier , Vinayak Rane , Thierry Dubroca , Krishnendu Kundu
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