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Raman scattering data were collected on graphite monochromator. Spectra were interpreted in terms of the space group $P6_3mc$, a subgroup of space group $P6_3/mmc$. The latter has commonly been used for the interpretation of Raman…

材料科学 · 物理学 2007-05-23 Y. Fujioka , J. Frantti , E. Yasuda , Y. Tanabe , M. Kakihana

Raman spectroscopy of graphene is reviewed from a theoretical perspective. After an introduction of the building blocks (electronic band structure, phonon dispersion, electron-phonon interaction, electron-light coupling), Raman intensities…

介观与纳米尺度物理 · 物理学 2017-03-23 Sven Reichardt , Ludger Wirtz

Results of room temperature Raman scattering studies of ultrathin graphitic films supported on Si (111)/SiO2 substrates are reported. The results are significantly different from those known for graphite. Spectra were collected using 514 nm…

介观与纳米尺度物理 · 物理学 2015-06-25 Awnish Gupta , Gugang Chen , P. Joshi , S. Tadigadapa , P. C. Eklund

This paper reports the experimental determination of the phase-breaking length L of conduction electrons in graphene using Raman spectroscopy. Based on the double-resonance model, we extract L from the spatial dependence of the D band…

材料科学 · 物理学 2008-02-27 Luiz Gustavo Cancado , Ryan Beams , Lukas Novotny

Under homogeneous uniaxial strains, the Raman 2D band of graphene involving two-phonon double-resonance scattering processes splits into two peaks and they altogether redshift strongly depending on the direction and magnitude of the strain.…

介观与纳米尺度物理 · 物理学 2015-03-19 Duhee Yoon , Young-Woo Son , Hyeonsik Cheong

The properties of polycrystalline materials are often dominated by the size of their grains and by the atomic structure of their grain boundaries. These effects should be especially pronounced in 2D materials, where even a line defect can…

Raman imaging on the edges of single layer micromechanical cleavage graphene (MCG) was carried out. The intensity of disorder-induced Raman feature (D band at ~1350 cm-1) was found to be correlated to the edge chirality: it is stronger at…

材料科学 · 物理学 2009-11-13 YuMeng You , ZhenHua Ni , Ting Yu , ZeXiang Shen

We present a systematic study of the Raman spectra of optical phonons in graphene monolayers under tunable uniaxial tensile stress. Both the G and 2D bands exhibit significant red shifts. The G band splits into two distinct sub-bands (G+,…

材料科学 · 物理学 2008-12-15 Mingyuan Huang , Hugen Yan , Changyao Chen , Daohua Song , Tony F. Heinz , James Hone

We present a detailed calculation of intensities of two-phonon and four-phonon Raman peaks in graphene. Writing the low-energy hamiltonian of the interaction of electrons with the crystal vibrations and the electromagnetic field from pure…

材料科学 · 物理学 2009-11-13 D. M. Basko

Graphene has many unique properties that make it an ideal material for fundamental studies as well as for potential applications. Here we review the recent results on the Raman spectroscopy and imaging of graphene. Raman spectroscopy and…

材料科学 · 物理学 2008-10-17 Zhen hua Ni , Ying ying Wang , Ting Yu , Ze xiang Shen

Graphene edges are of particular interest, since their chirality determines the electronic properties. Here we present a detailed Raman investigation of graphene flakes with well defined edges oriented at different crystallographic…

材料科学 · 物理学 2009-04-10 C. Casiraghi , A. Hartschuh , H. Qian , S. Piscanec , C. Georgi , K. S. Novoselov , D. M. Basko , A. C. Ferrari

Graphene can at present be grown at large quantities only by the chemical vapor deposition method, which produces polycrystalline samples. Here, we describe a method for constructing realistic polycrystalline graphene samples for atomistic…

材料科学 · 物理学 2012-05-28 Jani Kotakoski , Jannik C. Meyer

The paper presents a cooperative consideration of Raman spectra of $^2$ amorphous carbons as well as the nature and type of their amorphicity. The latter was attributed to the amorphization of a new type named as enforced fragmentation. The…

材料科学 · 物理学 2020-07-16 E. F. Sheka , Ye. A. Golubev , N. A. Popova

Low-frequency Raman scattering spectra are presented for gold nanocrystals with diameters 3.5 and 13 nm. The frequencies of the Raman peaks but also their number are shown to vary with the nanocrystal size. These results are analyzed using…

介观与纳米尺度物理 · 物理学 2012-02-09 Lucien Saviot , Nicolas Combe , Adnen Mlayah

The polarization dependences of the G, D, and 2D (G$'$) bands in Raman spectra at graphene bulk and edge are examined theoretically. The 2D and D bands have different selection rules at bulk and edge. At bulk, the 2D band intensity is…

介观与纳米尺度物理 · 物理学 2010-11-15 K. Sasaki , K. Wakabayashi , T. Enoki

Accurate and simple local strain assessment in graphene is one of the crucial tasks in device characterization. Raman spectroscopy is often used for that purpose through monitoring of the G and 2D modes. However, the shifts of those two…

材料科学 · 物理学 2018-04-27 Elena del Corro , Ladislav Kavan , Martin Kalbac , Otakar Frank

The effect of grain boundaries and wrinkles on the electrical properties of polycrystalline graphene is pronounced. Here we investigate the stitching between grains of polycrystalline graphene, specifically, overlapping of layers at the…

材料科学 · 物理学 2014-06-09 Rahul Rao , Neal Pierce , Avetik R. Harutyunyan

Raman spectroscopy is one of the widely used methods in the analysis of various samples including carbon-based materials. This study aimed to identify the number of layers and defects in graphene using micro-Raman spectroscopy. More…

光学 · 物理学 2024-03-21 Somayeh Gholipour , Maryam Bahreini , Mohamad Reza Jafarfard

The frequency dependence of the Raman coupling coefficient $C(\omega)$ is calculated numerically for square and cubic percolation clusters. No general scaling law in terms of the macroscopic parameters such as the fractal dimension $D$ or…

凝聚态物理 · 物理学 2007-05-23 P. Benassi , O. Pilla , G. Viliani , G. Ruocco , G. Signorelli , V. Mazzacurati , M. Montagna

We investigated Raman spectra of single-layer and multi-layer graphene under ultraviolet laser excitation at the wavelength of 325 nm. It was found that while the G peak of graphene remains pronounced in UV Raman spectra, the 2D band…

材料科学 · 物理学 2015-05-13 Irene Calizo , Igor Bejenari , Muhammad Rahman , Guanxiong Liu , Alexander A. Balandin
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