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Oxygen (O2) adsorbed on metal oxides is important in catalytic oxidation reactions, chemical sensing, and photocatalysis. Strong adsorption requires transfer of negative charge from oxygen vacancies (VOs) or dopants, for example. With…

The clean production of hydrogen as a zero-emission fuel can be done using photocatalysis, with TiO2 being one of the most promising photocatalysts. However, the activity of TiO2 anatase and rutile phases is still limited. In this study, an…

材料科学 · 物理学 2025-08-19 Jacqueline Hidalgo-Jimenez , Taner Akbay , Tatsumi Ishihara , Kaveh Edalati

By using first-principles approach, the interaction of CO${_2}$ with (001) surfaces of six cubic ABO${_3}$ perovskites (A = Ba, Sr and B = Ti, Zr, Hf) is studied in detail. We show that CO${_2}$ adsorption results in the formation of highly…

材料科学 · 物理学 2018-06-27 Kostiantyn V. Sopiha , Oleksandr I. Malyi , Clas Persson , Ping Wu

We present a study on the crystallization process of undoped and Ta doped TiO2 amorphous thin films. In particular, the effect of ultra-fast annealing treatments in environments characterized by different oxygen concentrations is…

In the present work we report significant enhancement of the photoelectrochemical properties of self-organized TiO2 nanotubes by a combined de-coring of classic nanotubes followed by an appropiate TiCl4-treatment. We show that, except for…

We present nonlinear optical absorption properties of pulsed laser deposited thin films of topological insulator (TI), Bi2Se3 on quartz substrate, using open aperture Z - scan technique. The saturable intensity of as-deposited thin films…

强关联电子 · 物理学 2016-12-12 Radha Krishna Gopal , Deepak K. S. Ambast , Sourabh Singh , Jit Sarkar , Bipul Pal , Chiranjib Mitra

The evolution of titanyl-phthalocyanine (TiOPc) thin films on Ag(111) has been investigated using IRAS, SPA-LEED and STM. In the (sub)monolayer regime various phases are observed that can be assigned to a 2D gas, a commensurate and a…

The structural and electronic recovery pathways of a photoexcited ultrathin VO2 film at nanosecond time scales have been studied using time-resolved x-ray diffraction and transient optical absorption techniques. The recovery pathways from…

In the present work we use TiO2 nanotube arrays, carrying a Pt coating that is optimally dewetted, as a photocatalyst to generate H2. In order to achieve a maximum H2-generation efficiency, on the one hand an ideal thermal dewetting of the…

In this work, we design a TiO2 nanomembrane (TiNM) that can be used as a nanofilter platform for a selective enrichment of specific proteins. After use the photocatalytic properties of TiO2 allow to decompose unwanted remnant on the…

材料科学 · 物理学 2016-10-21 Jingwen Xu , Lingling Yang , Yuyao Han , Yongmei Wang , Xuemei Zhou , Zhida Gao , Yan-Yan Song , Patrik Schmuki

Understanding the mechanism of the heterojunction is an important step towards controllable and tunable interfaces for photocatalytic and photovoltaic based devices. To this aim, we propose a thorough study of a double heterostructure…

计算物理 · 物理学 2019-04-04 Slimane Haffad

We report a femtosecond mid-infrared study of the broadband low-energy response of individually separated (6,5) and (7,5) single-walled carbon nanotubes. Strong photoinduced absorption is observed around 200 meV, whose transition energy,…

介观与纳米尺度物理 · 物理学 2010-07-16 Jigang Wang , Matt W. Graham , Yingzhong Ma , Graham R. Fleming , Robert A. Kaindl

Titanium dioxide (TiO$_2$) plays a central role in the study of artificial photosynthesis, owing to its ability to perform photocatalytic water splitting. Despite over four decades of intense research efforts in this area, there is still…

材料科学 · 物理学 2016-07-28 Christopher E. Patrick , Feliciano Giustino

We show that the third order optical nonlinearity of 15-atom gold clusters is significantly enhanced when in contact with indium tin oxide (ITO) conducting film. Open and close aperture z-scan experiments together with non-degenerate…

介观与纳米尺度物理 · 物理学 2013-04-02 Sunil Kumar , E. S. Shibu , T. Pradeep , A. K. Sood

TiO2 nanotube arrays grown by anodization were coated with thin layers of polydopamine as visible light sensitizer. The PDA-coated TiO2 scaffolds were used as photocatalyst for selective oxidation of benzyl alcohol under monochromatic…

材料科学 · 物理学 2016-10-18 Jyotsna Tripathy , Gabriel Loget , Marco Altomare , Patrik Schmuki

Theory of optical absorption of linearly and circularly polarized light in surface and edge states in topological insulators is developed for a nonlinear in light intensity regime. The absorbance for surface states and the absorption width…

介观与纳米尺度物理 · 物理学 2022-03-30 N. V. Leppenen , L. E. Golub

Resonant optical excitation of apical oxygen vibrational modes in the normal state of underdoped YBa2Cu3O6+x induces a transient state with optical properties similar to those of the equilibrium superconducting state. Amongst these, a…

We have investigated the growth of BaTiO3 thin films deposited on pure and 1% Nb-doped SrTiO3(001) single crystals using atomic oxygen assisted molecular beam epitaxy (AO-MBE) and dedicated Ba and Ti Knudsen cells. Thicknesses up to 30 nm…

材料科学 · 物理学 2015-06-12 A. Barbier , C. Mocuta , D. Stanescu , P. Jegou , N. Jedrecy , H. Magnan

We investigated the growth of titanium oxide two-dimensional (2D) nanostructures on Au(111), produced by Ti evaporation and post-deposition oxidation. Scanning tunneling microscopy and spectroscopy (STM and STS) and low-energy electron…

材料科学 · 物理学 2016-12-21 F. Tumino , P. Carrozzo , L. Mascaretti , C. S. Casari , M. Passoni , S. Tosoni , C. E. Bottani , A. Li Bassi

We revisited ab initio evaluations of the energy barriers along the possible diffusion paths of the defects in rutile TiO$_2$. By using a method carefully considering the cancellation of the self-interaction, Ti interstitials hopping along…

材料科学 · 物理学 2019-12-11 Tom Ichibha , Anouar Benali , Kenta Hongo , Ryo Maezono