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Absolute photoionisation cross sections for the Cl$^+$ ion in its ground and the metastable states; $3s^2 3p^4\; ^3P_{2,1,0}$, and $3s^2 3p^4\; ^1D_2,\; ^1S_0$, were measured recently at the Advanced Light Source ALS) at Lawrence Berkeley…

原子物理 · 物理学 2016-10-12 Brendan M McLaughlin

Processes that break molecular bonds are typically observed with molecules occupying a mixture of quantum states and successfully described with quasiclassical models, while a few studies have explored the distinctly quantum mechanical…

原子物理 · 物理学 2018-10-10 S. S. Kondov , C. -H. Lee , M. McDonald , B. H. McGuyer , I. Majewska , R. Moszynski , T. Zelevinsky

Studies on the interactions between an alkali atom and an alkaline earth ion at low energy are important in the field of cold chemistry. In this paper we, extensively, study the structure, interactions, and dynamics of (MgCs)$^+$ molecular…

原子物理 · 物理学 2022-10-05 Mohamed Farjallah , Dibyendu Sardar , Bimalendu Deb , Hamid Berriche

We suggest a way to disentangle self- from cross-correlation contributions in the dielectric spectra of glycerol. Recently it was demonstrated for monohydroxy alcohols that a detailed comparison of the dynamic susceptibilities of photon…

Photoelectron photoion coincidence spectroscopy has been used to measure the threshold photoelectron spectrum of 1-ethynylpyrene and to obtain the breakdown graph describing the dissociation of the 1-ethynylpyrene cation. The threshold…

星系天体物理 · 物理学 2021-12-13 Gaël Rouillé , Mathias Steglich , Patrick Hemberger , Cornelia Jäger , Thomas Henning

We report the observation of above-threshold dissociation of a multielectron molecular system, Na$_2^+$. The process is due to continuum-continuum transitions in a field-dressed molecular continuum. Three well resolved fragmentation…

化学物理 · 物理学 2008-08-24 Qun Zhang , John W. Hepburn , Moshe Shapiro

Photodissociation of a molecule produces a spatial distribution of photofragments determined by the molecular structure and the characteristics of the dissociating light. Performing this basic chemical reaction at ultracold temperatures…

原子物理 · 物理学 2018-01-24 M. McDonald , I. Majewska , C. -H. Lee , S. S. Kondov , B. H. McGuyer , R. Moszynski , T. Zelevinsky

The absolute photodetachment cross-section characterizes the photostability of atomic and molecular anions against photodestruction by neutralization. The measurement of this quantity has been reported only for atomic and simple molecular…

原子与分子团簇 · 物理学 2025-09-23 Salvi Mohandas , Uma Namangalam , Abheek Roy , Hemanth Dinesan , S. Sunil Kumar

Within the Dirac- and Lorentz-bubble potential models an electronic structure of the doubly-charged negative ion has been studied by a variational method. It is shown that even in the first approximation of this method when a trial wave…

原子物理 · 物理学 2016-01-18 A. Z. Msezane , A. S. Baltenkov

We characterize the anisotropic differential ac-Stark shift for the Dy $626$ nm intercombination transition, induced in a far-detuned $1070$ nm optical dipole trap, and observe the existence of a "magic polarization" for which the…

The optical emission spectrum of acetylene excited by monoenergetic electrons was studied in the range of 190 nm to 660 nm. The dissociative excitation and dissociative ionization associated with excitation of the ions initiated by electron…

原子物理 · 物理学 2022-12-12 Juraj Országh , Marián Danko , Peter Čechvala , Štefan Matejčík

Carbonyl complexes of $d^6$ metals with an alpha-diimine ligand exhibit both emission and ligand-selective photodissociation from MLCT states. Studying this photodissociative mechanism is challenging for experimental approaches due to an…

化学物理 · 物理学 2025-01-14 Bartosz Ciborowski , Morgane Vacher

Photodissociation cross sections for the SH$^+$ radical are computed from all rovibrational (RV) levels of the ground electronic state X$~^3\Sigma^-$ for wavelengths from threshold to 500~\AA. The five electronic transitions, $2~ ^3\Sigma^-…

地球与行星天体物理 · 物理学 2016-05-04 E. C. McMillan , G. Shen , J. F. McCann , B. M. McLaughlin , P. C. Stancil

The photodissociation of the HD+ molecular ion in intense short- pulsed linearly polarized laser fields is studied using a time- dependent wave-packet approach where molecular rotation is fully included. We show that applying a coherent…

chem-ph · 物理学 2019-04-04 Eric Charron , Annick Giusti-Suzor , Frederick Mies

The cross section of dipole-magnetic photodisintegration of the negative hydrogen ion has been calculated within the framework of an effective-range theory. The dipole-magnetic cross section of photodetachment within the very narrow range…

原子物理 · 物理学 2015-06-17 Arkadiy S. Baltenkov

The absolute single photoionization cross-section was measured for Cl-like K$^{2+}$ over the photon energy range from 44.2 - 69.7 eV at a constant energy resolution of 0.045 eV. The experiments were performed by merging an ion beam with a…

Photodetachment cross-section $\sigma_{ph}(p_e)$ of the negatively charged hydrogen ion H$^{-}$ is determined with the use of highly accurate variational wave functions constructed for this ion. Photodetachment cross-sections of the H$^{-}$…

太阳与恒星天体物理 · 物理学 2015-11-26 Alexei M. Frolov

The system of CH$_3$I adsorbed on submonolayer, monolayer and multilayer thin films of D$_2$O on Cu(110) has been studied by measuring the time-of-flight (TOF) distributions of the desorbing CH$_3$ fragments after photodissociation using…

化学物理 · 物理学 2021-01-18 E. R. Miller , G. D. Muirhead , E. T. Jensen

The dissociation of excited electron-hole pairs is a microscopic process that is fundamental to the performance of photovoltaic systems. For this process to be successful, the oppositely charged electron and hole must overcome an…

介观与纳米尺度物理 · 物理学 2017-08-14 Liang Shi , Chee Kong Lee , Adam P. Willard

The fragmentation of 1-propanol resulting from dissociative electron attachment has been explored across an energy range of 3.5 to 16 eV. Four distinct ion species are identified: $\text{H}^{-}$, $\text{O}^{-}$, $\text{OH}^{-}$, and…

原子与分子团簇 · 物理学 2026-02-06 Soumya Ghosh , Dipayan Chakraborty , Anirban Paul , Dhananjay Nandi