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Through infrared spectroscopy, we systematically study the pressure effect on electronic structures of few-layer black phosphorus (BP) with layer number ranging from 2 to 13. We reveal that the pressure-induced shift of optical transitions…

Recent experimental measurements of light absorption in few-layer black phosphorus (BP) reveal a series of high and sharp peaks, interspersed by pairs of lower and broader features. Here, we propose a theoretical model for these excitonic…

介观与纳米尺度物理 · 物理学 2021-05-12 A. Chaves , G. O. Sousa , K. Khaliji , D. R. da Costa , G. A. Farias , Tony Low

Two-dimensional (2D) layered transition metal dichalcogenides (TMDs) have recently attracted tremendous interest as potential valleytronic and nano-electronic materials, in addition to being well-known as excellent lubricants in the bulk.…

Black Phosphorus (BP) is unique among layered materials owing to its homonuclear lattice and strong structural anisotropy. While recent investigations on few layers BP have extensively explored the in-plane (a,c) anisotropy, much less…

We investigate the electro-optic properties of black phosphorus (BP) thin films for optical modulation in the mid-infrared frequencies. Our calculation indicates that an applied out-of-plane electric field may lead to red-, blue-, or…

介观与纳米尺度物理 · 物理学 2016-04-20 Charles Lin , Roberto Grassi , Tony Low , Amr S. Helmy

We investigate the impact of the encapsulation with hexagonal boron nitride (h-BN) on the Raman spectrum of few layer black phosphorus. The encapsulation results in a significant reduction of the line width of the Raman modes of black…

介观与纳米尺度物理 · 物理学 2017-11-23 J. M. Urban , M. Baranowski , A. Surrente , D. Wlodarczyk , A. Suchocki , G. Long , Y. Wang , L. Klopotowski , N. Wang , D. K. Maude , P. Plochocka

Black phosphorus is a very promising material for telecommunication due to its direct bandgap and strong resonant absorption in near-infrared wavelength range. However, ultrafast nonlinear photonic applications relying on the ultrafast…

Black phosphorus (BP) has recently emerged as an alternative 2D semiconductor owing to its fascinating electronic properties such as tunable bandgap and high charge carrier mobility. The structural investigation of few-layer BP, such as…

介观与纳米尺度物理 · 物理学 2017-02-01 Yangjin Lee , Jun-Yeong Yoon , Declan Scullion , Jeongsu Jang , Elton J G Santos , Hu Young Jeong , Kwanpyo Kim

Recently, black phosphorus (BP) has joined the two dimensional material family as a promising candidate for photonic applications, due to its moderate bandgap, high carrier mobility, and compatibility with a diverse range of substrates.…

Black phosphorus (BP) is an emerging two-dimensional semiconducting material with great potential for nanoelectronic and nanophotonic applications, especially owing to its unique anisotropic electrical and optical properties. Many…

Owing to its outstanding electronic properties, black phosphorus (BP) is considered as a promising material for next-generation optoelectronic devices. In this work, devices based on BP/MXene (Zrn+1CnT2, T = O, F, OH, n = 1, 2) van der…

材料科学 · 物理学 2018-02-13 Hao Yuan , Zhenyu Li

Layer-layer coupling plays a critical role in defining the physical properties of few-layer graphene (FLG). With respect to vibrations, the interlayer coupling is predicted to create a set of N-1 finite frequency, out-of-plane interlayer…

介观与纳米尺度物理 · 物理学 2013-04-04 Chun Hung Lui , Tony F. Heinz

The possibility of hybridizing collective electronic motion with mid-infrared (mid-IR) light to form surface polaritons has made van der Waals layered materials a versatile platform for extreme light confinement and tailored nanophotonics.…

Atomically thin black phosphorus (BP) is a promising two-dimensional material for fabricating electronic and optoelectronic nano-devices with high mobility and tunable bandgap structures. However, the charge-carrier mobility in few-layer…

Thin flakes of black phosphorus (BP) are a two-dimensional (2D) semiconductor whose energy gap is predicted being sensitive to the number of layers and external perturbations. Very recently, it was found that a simple method of potassium…

材料科学 · 物理学 2015-12-15 Seung Su Baik , Keun Su Kim , Yeonjin Yi , Hyoung Joon Choi

Black phosphorus (BP), an emerging two-dimensional (2D) material with intriguing optical properties, forms a promising building block in optics and photonics devices. In this work, we propose a simple structure composed of BP sandwiched by…

光学 · 物理学 2019-09-18 Tingting Liu , Xiaoyun Jiang , Chaobiao Zhou , Shuyuan Xiao

Black phosphorus is an infrared layered material. Its bandgap complements other widely studied two-dimensional materials: zero-gap graphene and visible/near-infrared gap transition metal dichalcogenides. Though highly desirable, a…

介观与纳米尺度物理 · 物理学 2017-02-07 Guowei Zhang , Shenyang Huang , Andrey Chaves , Chaoyu Song , V. Ongun Özçelik , Tony Low , Hugen Yan

Few-layer graphene is a layered carbon material with covalent bonding in the layers and weak van der Waals interactions between the layers. The interlayer energy is more than two orders of magnitude smaller than the intralayer one, which…

介观与纳米尺度物理 · 物理学 2014-12-24 Valentin N. Popov , Christian Van Alsenoy

We report a study of the structural phase transitions induced by pressure in bulk black phosphorus by using both synchrotron x-ray diffraction for pressures up to 12.2 GPa and Raman spectroscopy up to 18.2 GPa. Very recently black…

材料科学 · 物理学 2018-11-21 B. Joseph , S. Caramazza , F. Capitani , T. Clarté , F. Ripanti , P. Lotti , A. Lausi , D. Di Castro , P. Postorino , P. Dore

High-performance infrared photodetection underpins various applications spanning surveillance, environmental monitoring, optical communications and biomedical imaging. However, conventional bulk detectors remain limited by poor spectral…