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Steepest-entropy-ascent quantum thermodynamics, or SEAQT, is a unified approach of quantum mechanics and thermodynamics that avoids many of the inconsistencies that can arise between the two theories. Given a set of energy levels, i.e.,…

材料科学 · 物理学 2019-07-26 Ryo Yamada , Michael R. von Spakovsky , William T. Reynolds

This work outlines the foundations for being able to do a first-principle study of the adsorption process using the steepest-entropy-ascent quantum thermodynamic (SEAQT) framework, a framework able to predict the unique non-equilibrium path…

Steepest-entropy-ascent quantum thermodynamics (SEAQT) is an intriguing approach that describes equilibrium and dynamic processes in a self-consistent way. The applicability is limited to mainly gas phases because of a complex…

材料科学 · 物理学 2018-08-01 Ryo Yamada , Michael R. von Spakovsky , William T. Reynolds,

This paper presents a nonequilibrium, first-principles, thermodynamic-ensemble based model for the relaxation process of interacting non-equilibrium systems. This model is formulated using steepest-entropy-ascent quantum thermodynamics…

统计力学 · 物理学 2018-10-10 Guanchen Li , Michael R. von Spakovsky

Quantum systems driven by time-dependent Hamiltonians are considered here within the framework of steepest-entropy-ascent quantum thermodynamics (SEAQT) and used to study the thermodynamic characteristics of such systems. In doing so, a…

统计力学 · 物理学 2017-08-23 ILki Kim , Michael R. von Spakovsky

A Potts model and the Replica Exchange Wang-Landau algorithm are used to construct an energy landscape for a crystalline solid containing surfaces and grain boundaries. The energy landscape is applied to an equation of motion from the…

材料科学 · 物理学 2023-03-22 Jared McDonald , Michael R. von Spakovsky , William T. Reynolds

The steepest-entropy-ascent quantum thermodynamic (SEAQT) framework was used to calculate the stability of a collection of point defects in 2D PtSe$_2$ and predict the kinetics with which defects rearrange during thermal annealing. The…

材料科学 · 物理学 2022-12-19 Aimen Younis , Fazel Baniasadi , Michael R. von Spakovsky , William T. Reynolds

A formal development of the hypoequilibrium (HE) state concept within the Steepest-Entropy-Ascent Quantum Thermodynamics (SEAQT) framework is presented, emphasizing its rigorous mathematical formulation. Using a general decomposition of the…

量子物理 · 物理学 2026-05-27 Gian Paolo Beretta , Rohit Kishan Ray , Michael R. von Spakovsky

By suitable reformulations, we cast the mathematical frameworks of several well-known different approaches to the description of non-equilibrium dynamics into a unified formulation, which extends to such frameworks the concept of Steepest…

统计力学 · 物理学 2014-10-14 Gian Paolo Beretta

We consider the steepest entropy ascent (SEA) ansatz to describe the non-linear thermodynamic evolution of a quantum system. Recently this principle has been dubbed the fourth law of thermodynamics (Beretta Gian Paolo. 2020 The fourth law…

量子物理 · 物理学 2022-08-17 Rohit Kishan Ray

The Replica Exchange Wang-Landau Method is used to estimate the energy landscape of a polymer composed of a simple hydrophobic and polar sequence using the HP protein model. Calculations of state transitions between the energy levels of the…

软凝聚态物质 · 物理学 2023-03-22 Jared McDonald , Michael R. von Spakovsky , William T. Reynolds

By suitable reformulations, we review the mathematical frameworks of six different approaches to the description of non-equilibrium dynamics with the purpose to set up a unified formulation of the Maximum Entropy Production (MEP) principle…

统计力学 · 物理学 2013-06-27 Gian Paolo Beretta

The 2D toric code is a prototypical example that exhibits non-trivial topological properties and a ground state possessing a non-trivial topological order. Until now, all the cases studied in the literature have been in the stable…

量子物理 · 物理学 2024-11-01 Cesar Damian , Adriana Saldana-Robles , Michael von Spakovsky

The steepest-entropy-ascent quantum thermodynamic (SEAQT) framework is utilized to study the effects of temperature on polymer brushes. The brushes are represented by a discrete energy spectrum and energy degeneracies obtained through the…

软凝聚态物质 · 物理学 2024-01-09 Jared McDonald , Michael R. von Spakovsky , William T. Reynolds

The thermodynamics of quantum systems driven out of equilibrium has attracted increasing attention in last the decade, in connection with quantum information and statistical physics, and with a focus on non-classical signatures. While a…

量子物理 · 物理学 2022-06-01 Gonzalo Manzano , Roberta Zambrini

The Steepest Entropy Ascent (SEA) ansatz, recently recognized as the fourth law of thermodynamics, governs the irreversible evolution of a system from a non-equilibrium state toward a unique maximum-entropy equilibrium. SEA builds upon the…

量子物理 · 物理学 2025-08-21 Rohit Kishan Ray

We first discuss the geometrical construction and the main mathematical features of the maximum-entropy-production/steepest-entropy-ascent nonlinear evolution equation proposed long ago by this author in the framework of a fully quantum…

量子物理 · 物理学 2015-05-13 Gian Paolo Beretta

This paper presents a nonequilibrium thermodynamic model for the relaxation of a local, isolated system in nonequilibrium using the principle of steepest entropy ascent (SEA), which can be expressed as a variational principle in…

统计力学 · 物理学 2016-09-21 Guanchen Li , Michael R. von Spakovsky

Stochastic thermodynamics is a framework for describing non-equilibrium processes at the level of fluctuating trajectories, where the state of a system evolves as a stochastic time series, allowing thermodynamic quantities such as work,…

This work presents a general unifying theoretical framework for quantum non-equilibrium systems. It is based on a re-statement of the dynamical problem as one of inferring the distribution of collision events that move a system toward…

量子物理 · 物理学 2015-03-30 David M. Rogers
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