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Within the framework of nonequilibrium Green's functions, we investigate the thermoelectric transport in a single molecular junction with electron-phonon and electron-electron interactions. By transforming into a displaced phonon basis, we…

介观与纳米尺度物理 · 物理学 2012-04-26 Jie Ren , Jian-Xin Zhu , James E. Gubernatis , Chen Wang , Baowen Li

Motivated by recent experiments, we present here an ab initio study of the impact of the phonon transport on the thermal conductance and thermoelectric figure of merit of C$_{60}$-based single-molecule junctions. To be precise, we combine…

介观与纳米尺度物理 · 物理学 2017-08-22 Jan Christopher Klöckner , Robert Siebler , Juan Carlos Cuevas , Fabian Pauly

We overview nonequilibrium Green function combined with density functional theory (NEGF-DFT) modeling of independent electron and phonon transport in nanojunctions with applications focused on a new class of thermoelectric devices where a…

介观与纳米尺度物理 · 物理学 2012-04-19 Branislav K. Nikolic , Kamal K. Saha , Troels Markussen , Kristian S. Thygesen

We show that a molecular junction can give large values of the thermoelectric figure of merit $ZT$, and so could be used as a solid state energy conversion device that operates close to the Carnot efficiency. The mechanism is similar to the…

介观与纳米尺度物理 · 物理学 2009-11-13 Padraig Murphy , Subroto Mukerjee , Joel Moore

We present an \emph{ab initio} study of the role of interference effects in the thermal conductance of single-molecule junctions. To be precise, using a first-principles transport method based on density functional theory, we analyze the…

介观与纳米尺度物理 · 物理学 2017-12-27 J. C. Klöckner , J. C. Cuevas , F. Pauly

Thermopower measurements of molecular junctions have recently gained interest as a characterization technique that supplements the more traditional conductance measurements. Here we investigate the electronic conductance and thermopower of…

介观与纳米尺度物理 · 物理学 2015-06-15 Troels Markussen , Chengjun Jin , Kristian S. Thygesen

We study the electronic contribution to the main thermoelectric properties of a molecular junction consisting of a single quantum dot coupled to graphene external leads. The system electrical conductivity (G), Seebeck coefficient ($S$), and…

介观与纳米尺度物理 · 物理学 2017-10-25 S. T. Rodriguez , I. Grosu , M. Crisan , I. Tifrea

We demonstrate how redox control of intra-molecular quantum interference in phase-coherent molecular wires can be used to enhance the thermopower (Seebeck coefficient) S and thermoelectric figure of merit ZT of single molecules attached to…

介观与纳米尺度物理 · 物理学 2015-09-10 Víctor M. García-Suarez , Colin J. Lambert , David Zs. Manrique , Thomas Wandlowski

Thermoelectric phenomena are traditionally associated with the interconversion of thermal and electrical energy in many-body systems. In the context of high-temperature quantum chromodynamics (QCD) matter produced in relativistic heavy-ion…

高能物理 - 唯象学 · 物理学 2025-12-09 Kamaljeet Singh , Raghunath Sahoo

Utilizing the non-coherent quantum transport formalism, we investigate thermoelectric performance across dissipative superlattice configurations in the linear regime of operation. Using the {\it{dissipative}} non-equilibrium Green's…

介观与纳米尺度物理 · 物理学 2020-12-30 Pankaj Priyadarshi , Bhaskaran Muralidharan

Motivated by recent experiments, we present here a systematic ab-initio study of the length dependence of the thermal conductance of single-molecule junctions. We make use of a combination of density functional theory with non-equilibrium…

介观与纳米尺度物理 · 物理学 2016-11-30 J. C. Klöckner , M. Bürkle , J. C. Cuevas , F. Pauly

Low-dimensional electronic and glassy phononic transport are two important ingredients of highly-efficient thermoelectric material, from which two branches of the thermoelectric research emerge. One focuses on controlling electronic…

材料科学 · 物理学 2015-07-14 Xue-Ya Mi , Xiaoxiang Yu , Kai-Lun Yao , Xiaoming Huang , Nuo Yang , Jing-Tao Lü

In this paper, we propose a computational framework, based on the VASP and phono3py computer codes, to obtain the thermoelectric figure of merit from the electron-phonon and phonon-phonon interactions using finite displacements in…

We study thermoelectric devices where a single 18-annulene molecule is connected to metallic zigzag graphene nanoribbons (ZGNR) via highly transparent contacts that allow for injection of evanescent wave functions from ZGNRs into the…

介观与纳米尺度物理 · 物理学 2011-08-03 Kamal K. Saha , Troels Markussen , Kristian S. Thygesen , Branislav K. Nikolic

We present a study of the thermopower $S$ and the dimensionless figure of merit $ZT$ in molecules sandwiched between gold electrodes. We show that for molecules with side groups, the shape of the transmission coefficient can be dramatically…

材料科学 · 物理学 2009-11-13 C. M. Finch , V. M. García-Suárez , C. J. Lambert

In this work, we investigate thermoelectric properties of junctions consisting of two partially overlapped graphene sheets coupled to each other in the cross-plane direction. It is shown that because of the weak van-der Waals interactions…

介观与纳米尺度物理 · 物理学 2014-10-07 V. Hung Nguyen , M. Chung Nguyen , Huy-Viet Nguyen , J. Saint-Martin , P. Dollfus

We report a combined experimental (C-AFM and SThM) and theoretical (DFT) study of the thermoelectric properties of molecular junctions made of self-assembled monolayers on Au of thiolated benzothieno-benzothiophene (BTBT) and alkylated BTBT…

介观与纳米尺度物理 · 物理学 2024-11-13 Sergio Gonzalez-Casal , Rémy Jouclas , Imane Arbouch , Yves Geerts , Colin van Dyck , Jérôme Cornil , Dominique Vuillaume

Thermoelectrics are a promising class of materials for renewable energy owing to their capability to generate electricity from waste heat, with their performance being governed by a competition between charge and thermal transport. A…

Thermoelectrics as a way to use waste heat, is essential in electronic industries, but its low performance at operational temperatures makes it inappropriate in practical applications. Tailoring graphene can change its properties. In this…

介观与纳米尺度物理 · 物理学 2022-10-25 M. Amir Bazrafshan , Farhad Khoeini

We present the first in a series of microscopic studies of electrical transport through individual molecules with metallic contacts. We view the molecules as ``heterostructures'' composed of chemically well-defined atomic groups, and…

介观与纳米尺度物理 · 物理学 2009-11-10 Yongqiang Xue , Mark A. Ratner
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