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Implicit electron-density solvation models based on joint density-functional theory offer a computationally efficient solution to the problem of calculating thermodynamic quantities of solvated systems from firstprinciples quantum…

化学物理 · 物理学 2015-02-12 Deniz Gunceler , T. A. Arias

Interfacial polar molecules feature a strongly anisotropic response to applied electric field, favoring dipole orientations parallel to the interface. In water, in particular, this effect combines with generic orientational preferences…

软凝聚态物质 · 物理学 2017-02-08 Dusan Bratko , Christopher D. Daub , Alenka Luzar

Nanoparticles are often covered in ligand monolayers, which can undergo a temperature-dependent order-disorder transition that switches the particle-particle interaction from repulsive to attractive in solution. In this work, we examine how…

软凝聚态物质 · 物理学 2018-07-05 Asaph Widmer-Cooper , Phillip L. Geissler

Selected theoretical developments in modeling of deposition of submicrometer size (submicron) particles on solid surfaces, with and without surface diffusion, of interest in colloid, polymer, and certain biological systems, are surveyed. We…

材料科学 · 物理学 2008-10-16 Vladimir Privman

We study the interaction of small hydrophobic particles on the surface of an ultra-soft elastic gel, in which a small amount of elasticity of the medium balances the weights of the particles. The excess energy of the surface of the deformed…

软凝聚态物质 · 物理学 2014-06-09 Aditi Chakrabarti , Manoj K. Chaudhury

Lipid nanoparticles own a remarkable potential in nanomedicine, only partially disclosed. While the clinical use of liposomes and cationic lipid-nucleic acid complexes is well-established, liquid lipid nanoparticles (nanoemulsions), solid…

We investigated the formation of cocontinuous structures in polymer blends. These polymeric bijels (bicontinuous interfacially jammed emulsion gels) were composed of polystyrene oligomer, polybutene and fluorescent hydrophobic silica…

软凝聚态物质 · 物理学 2015-02-03 Lian Bai , John Fruehwirth , Xiang Cheng , Christopher W. Macosko

We study the conformational properties of complex polymer macromolecules, consisting in general of $n$ subsequently connected chains (blocks) of different lengths and distinct chemical structure. Depending on the solvent conditions, the…

软凝聚态物质 · 物理学 2019-12-03 V. Blavatska , K. Haydukivska

Being able to predict and tune the colloidal stability of nanoparticles is essential for a wide range of applications, yet our ability to do so is currently poor due to a lack of understanding of how they interact with one another. Here, we…

软凝聚态物质 · 物理学 2018-08-30 Thomas Kister , Debora Monego , Paul Mulvaney , Asaph Widmer-Cooper , Tobias Kraus

Multilayer assemblies of metal nanoparticles can act as photonic structures, where collective plasmon resonances hybridize with cavity modes to create plasmon-polariton states. For sufficiently strong coupling, plasmon polaritons…

光学 · 物理学 2026-05-28 Tanay Paul , Allison M. Green , Delia J. Milliron , Thomas M. Truskett

Implementation of resonant colloidal nanoparticles for improving performance of organometal halide perovskites solar cells is highly prospective approach, because it is compatible with the solution processing techniques used for any organic…

We study electrostatic correlations in structured solvents confined to nanoscale systems. We derive variational equations of Netz-Orland type for a model liquid composed of finite size dipoles. These equations are solved for both dilute…

软凝聚态物质 · 物理学 2015-06-19 Sahin Buyukdagli , Ralf Blossey

Optical activity is a fundamental phenomenon originating from the chiral nature of crystals and molecules. While intrinsic chiroptical responses of ordinary chiral materials to circularly polarized light are relatively weak, they can be…

Cholesteric liquid crystals can exhibit spatial patterns in molecular alignment at interfaces that can be exploited for particle assembly. These patterns emerge from the competition between bulk and surface energies, tunable with the system…

软凝聚态物质 · 物理学 2023-11-30 Lisa Tran , Kyle J. M. Bishop

Bright, saturated structural colors in birds have inspired synthesis of self-assembled, disordered arrays of assembled nanoparticles with varied particle spacings and refractive indices. However, predicting colors of assembled…

We report a comprehensive study of aqueous halide adsorption on nanoparticles of gold and palladium that addresses several limitations hampering the use of atomistic modeling as a tool for understanding and improving wet-chemical synthesis…

材料科学 · 物理学 2021-08-17 Joakim Löfgren , J. Magnus Rahm , Joakim Brorsson , Paul Erhart

In recent years significant attention has been attracted to proposals which utilize DNA for nanotechnological applications. Potential applications of these ideas range from the programmable self-assembly of colloidal crystals, to biosensors…

软凝聚态物质 · 物理学 2008-05-02 Nicholas A. Licata

Bimetallic nanoparticles (often known as nanoalloys) with core-shell arrangement are of special interest in several applications, such as in optics, catalysis, magnetism and biomedicine. Despite wide interest in applications, the physical…

介观与纳米尺度物理 · 物理学 2015-06-15 Davide Bochicchio , Riccardo Ferrando

We propose a unifying, analytical theory accounting for the self-organization of colloidal systems in nano- or micro-cluster phases. We predict the distribution of cluter sizes with respect to interaction parameters and colloid…

软凝聚态物质 · 物理学 2009-11-13 Nicolas Destainville , Lionel Foret

Auxiliary nanostructures introduce additional flexibility into optomechanical manipulation schemes. Metamaterials and metasurfaces capable to control electromagnetic interactions at the near-field regions are especially beneficial for…