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Can liquid-like and gas-like states be distinguished beyond the critical point, where the liquid-gas phase transition no longer exists and conventionally only a single supercritical fluid phase is defined? Recent experiments and simulations…

统计力学 · 物理学 2024-04-30 Xinyang Li , Yuliang Jin

The location of the Frenkel line (FL) of a Lennard-Jones fluid which demarcates two distinct physical states, liquidlike and gaslike within the supercritical regime, has been established through molecular dynamics (MD) simulations of the…

统计力学 · 物理学 2018-01-29 Kanka Ghosh , C. V. Krishnamurthy

The supercritical state of matter is usually described as a continuous phase without sharp boundaries between liquid and gas regions. However, under non-equilibrium conditions, this view breaks down. Here we report an experimental…

化学物理 · 物理学 2025-11-25 Paul Fruton , Emma Lisoir , Happiness Imuetinyan , Cédric Giraudet , Fabrizio Croccolo

We predict that self-bound clusters of particles exist in the supercritical phase of simple fluids. These clusters, whose internal temperature is lower than the global temperature of the system, define a percolation line that starts at the…

统计力学 · 物理学 2009-10-31 X. Campi , H. Krivine , N. Sator

A revised phase diagram for water shows three distinct fluid phases. There is no continuity of liquid and gas and no critical point on Gibbs density surface. A liquid state, water, spans all temperatures. A thermodynamic rigidity function,…

统计力学 · 物理学 2013-08-22 Leslie V. Woodcock

Liquid water has anomalous liquid properties, such as its density maximum at 4\degree C. An attempt at theoretical explanation proposes a liquid-liquid phase transition line in the supercooled liquid state, with coexisting low-density (LDL)…

软凝聚态物质 · 物理学 2019-09-04 Peter Mausbach , Helge-Otmar May , George Ruppeiner

The moving-contact line between a fluid, liquid and a solid is a ubiquitous phenomenon, and determining the maximum speed at which a liquid can wet/dewet a solid is a practically important problem. Using continuum models, previous studies…

流体动力学 · 物理学 2022-08-17 J. S. Keeler , D. A. Lockerby , S. Kumar , J. E. Sprittles

The interplay between the structure and dynamics of partially confined Lennard Jones (LJ) fluids, deep into the supercritical phase, is studied over a wide range of densities in the context of the Frenkel line (FL), which separates rigid…

统计力学 · 物理学 2019-03-20 Kanka Ghosh , C. V. Krishnamurthy

When a 2D superconductor is subjected to a strong in-plane magnetic field, Zeeman polarization of the Fermi surface can give rise to inhomogeneous FFLO order with a spatially modulated gap. Further increase of the magnetic field eventually…

强关联电子 · 物理学 2018-07-17 Dimitri Pimenov , Ipsita Mandal , Francesco Piazza , Matthias Punk

A cell fluid model with a modified Morse potential is studied. The supercritical states are considered with respect to a possibility to build a separation boundary between liquid-like and gas-like bahaviors. Three different lines are…

统计力学 · 物理学 2025-04-08 O. A. Dobush , M. P. Kozlovskii , R. V. Romanik

A hallmark of a thermodynamic phase transition is the qualitative change of system thermodynamic properties such as energy and heat capacity. On the other hand, no phase transition is thought to operate in the supercritical state of matter…

统计力学 · 物理学 2020-04-13 L. Wang , C. Yang , M. T. Dove , V. V. Brazhkin , K. Trachenko

Strongly interacting, dynamically disordered and with no small parameter, liquids took a theoretical status between gases and solids. We review different approaches to liquids and propose that liquids do not need classifying in terms of…

软凝聚态物质 · 物理学 2016-01-13 K. Trachenko , V. V. Brazhkin

We have developed a scaled parametric equation of state to describe and predict thermodynamic properties of supercooled water. The equation of state, built on the growing evidence that the critical point of supercooled liquid-liquid water…

软凝聚态物质 · 物理学 2007-05-23 M. A. Anisimov , D. A. Fuentevilla

We theoretically explore a promising route to achieve the Fulde-Ferrell-Larkin-Ovchinnikov (FFLO) state in a spin-imbalanced ultracold Fermi gas. In the current stage of cold atom physics, search for this exotic Fermi superfluid is facing…

量子气体 · 物理学 2022-09-30 Taira Kawamura , Yoji Ohashi

On the phase diagram of a system undergoing a continuous phase transition of the second order, three lines, hyper-surfaces, convergent into the critical point feature prominently: the ordered and disordered phases in the thermodynamic…

统计力学 · 物理学 2013-07-16 A. Kashuba

We develop an approach to liquid thermodynamics based on collective modes. We perform extensive molecular dynamics simulations of noble, molecular and metallic liquids and provide the direct evidence that liquid energy and specific heat are…

软凝聚态物质 · 物理学 2017-03-08 L. Wang , C. Yang , M. T. Dove , Yu. D. Fomin , V. V. Brazhkin , K. Trachenko

At a temperature of roughly 1\,K, \ce{Sr2RuO4} undergoes a transition from a normal Fermi liquid to a superconducting phase. Even while the former is relatively simple and well understood, the superconducting state is not even after 25…

强关联电子 · 物理学 2021-01-21 Swagata Acharya , Dimitar Pashov , Elena Chachkarova , Mark Van Schilfgaarde , Cédric Weber

We investigate, for two water models displaying a liquid-liquid critical point, the relation between changes in dynamic and thermodynamic anomalies arising from the presence of the liquid-liquid critical point. We find a correlation between…

统计力学 · 物理学 2016-08-31 L. Xu , P. Kumar , S. V. Buldyrev , S. -H. Chen , P. H. Poole , F. Sciortino , H. E. Stanley

Achieving a coherent understanding of the many thermodynamic and dynamic anomalies of water is among the most important unsolved puzzles in physics, chemistry, and biology. One hypothesized explanation imagines the existence of a line of…

Fluidity, the ability of liquids to flow, is the key property distinguishing liquids from solids. This fluidity is set by the mobile transit atoms moving from one quasi-equilibrium point to the next. The nature of this transit motion is…

统计力学 · 物理学 2023-10-06 Cillian Cockrell , Oliver Dicks , Ilian T. Todorov , Alin M. Elena , Kostya Trachenko