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We synthesized lanthanum hydride (LaHx) by laser heating of lanthanum in hydrogen atmosphere at pressure P = 170 GPa. The sample shows a superconducting step at 209 K and 170 GPa and temperature dependence of resistance. By releasing the…

Electrical resistivity measurements under high pressures up to 29 GPa were performed for oxypnictide compound LaFeAsO. We found a pressure-induced superconductivity in LaFeAsO. The maximum value of Tc is 21 K at ~12 GPa. The pressure…

超导电性 · 物理学 2009-11-13 H. Okada , K. Igawa , H. Takahashi , Y. Kamihara , M. Hirano , H. Hosono , K. Matsubayashi , Y. Uwatoko

The ternary iron arsenide BaFe2As2 becomes superconducting by hole doping, which was achieved by partial substitution of the barium site with potassium. We have discovered bulk superconductivity up to Tc = 38 K in (Ba1-xKx)Fe2As2 with x =…

超导电性 · 物理学 2008-09-06 Marianne Rotter , Marcus Tegel , Dirk Johrendt

The effects of simultaneous Sb doping on the superconductivity of 112-type Ca1-xRExFeAs2 (RE = La, Ce, Pr, and Nd) were studied through measurements of the magnetization and electrical resistivity. In Sb-free materials, the superconducting…

The fluorine-doped rare-earth iron oxyarsenides, REFeAsO1-xFx (RE =rare earth) have recently emerged as a new family of high-temperature superconductors with transition temperatures (Tc) as high as 55 K (refs 1-4). Early work has provided…

Significant manifestation of interplay of superconductivity and charge density wave, spin density wave or magnetism is dome-like variation in superconducting critical temperature (Tc) for cuprate, iron-based and heavy Fermion…

La-substituted CaFeAsH,(Ca1-xLax)FeAsH, were synthesized by the solid state reaction at 1173 K under high pressure of 2.5 GPa. The r-T anomaly corresponding to tetragonal to orthorhombic structural transition was suppressed by…

超导电性 · 物理学 2014-02-19 Yoshinori Muraba , Satoru Matsuishi , Hideo Hosono

Recent theoretical and experimental studies of hydrogen-rich materials at megabar pressures (i.e., >100 GPa) have led to the discovery of very high-temperature superconductivity in these materials. Lanthanum superhydride LaH$_{10}$ has been…

超导电性 · 物理学 2022-01-05 Yanfeng Ge , Fan Zhang , Russell J. Hemley

We have synthesized 10 new iron oxyarsenides, K$Ln_2$Fe$_4$As$_4$O$_2$ ($Ln$ = Gd, Tb, Dy, and Ho) and Cs$Ln_2$Fe$_4$As$_4$O$_2$ ($Ln$ = Nd, Sm, Gd, Tb, Dy, and Ho), with the aid of lattice-match [between $A$Fe$_2$As$_2$ ($A$ = K and Cs)…

超导电性 · 物理学 2017-09-13 Si-Qi Wu , Zhi-Cheng Wang , Chao-Yang He , Zhang-Tu Tang , Yi Liu , Guang-Han Cao

In the iron-based high-Tc bulk superconductors, Tc above 50K was only observed in the electron-doped 1111-type compounds. Here we revisit the electron-doped SmFeAsO polycrystals to make a further investigation for the highest T-c in these…

超导电性 · 物理学 2017-11-16 Xiao-Chuan Wang , Jia Yu , Bin-Bin Ruan , Bo-Jin Pan , Qing-Ge Mu , Tong Liu , Kang Zhao , Gen-Fu Chen , Zhi-An Ren

Exploring new unconventional superconductors is of great value for both fundamental research and practical applications. It is a long-term challenge to develop and study more hole-doped superconductors in 1111 system of iron-based…

超导电性 · 物理学 2025-01-27 Yixin Liu , Teng Wang , Zulei Xu , Da Jiang , Yi Zhao , Yanpeng Qi , Xiaoni Wang , Ming Yang , Mao Ye , Wei Peng , Gang Mu

Lanthanum (La) is the first member of the rare-earth series of elements that has recently raised considerable interest because of its unique high-Tc superhydride LaH10. Although several studies have found superconductivity and phase…

Single crystals of the compounds LaFePO, PrFePO, and NdFePO have been prepared by means of a flux growth technique and studied by electrical resistivity, magnetic susceptibility and specific heat measurements. We have found that PrFePO and…

超导电性 · 物理学 2009-11-13 R. E. Baumbach , J. J. Hamlin , L. Shu , D. A. Zocco , N. M. Crisosto , M. B. Maple

Single crystals of Ca1-xLaxFe2As2 for x ranging from 0 to 0.25 have been grown and characterized by structural, transport and magnetic measurements. Coexistence of two superconducting phases is observed, in which the low superconducting…

超导电性 · 物理学 2013-10-21 Y. Sun , W. Zhou , L. J. Cui , J. C. Zhuang , Y. Ding , F. F. Yuan , J. Bai , Z. X. Shi

Here we report the superconductivity in the iron-based oxyarsenide Sm[O1-xFx]FeAs, with the onset resistivity transition temperature at 55.0 K and Meissner transition at 54.6 K. This compound has the same crystal structure as LaOFeAs with…

Establishing a complete electronic phase diagram for REFeAsO (RE = rare earth, RE1111) ironbased superconductors has remained experimentally challenging. Here, we report a systematic investigation of PrFeAsO1-xFx over the full nominal…

The synthesis, structural and physical properties of iron lanthanide oxypnictide superconductors, L4Fe2As2Te1-xO4 (L = Pr, Sm, Gd), with transition temperature at ~ 25 K are reported. Single crystals have been grown at high pressure using…

超导电性 · 物理学 2015-06-18 S. Katrych , A. Pisoni , S. Bosma , S. Weyeneth , N. D. Zhigadlo , R. Gaal , J. Karpinski , L. Forró

Chemical doping has recently become a very important strategy to induce superconductivity especially in complex compounds. Distinguished examples include Ba-doped La$_2$CuO$_4$ (the first high temperature superconductor), K-doped BaBiO$_3$,…

We report the synthesis and characterization of a new electron-doped La-oxypnictide superconductor by partial substitution of lanthanum by thorium. The superconducting transition temperature at about 30.3 K was observed in La0.8Th0.2OFeAs…

超导电性 · 物理学 2009-11-13 J. Prakash , S. J. Singh , S. Patnaik , A. K. Ganguli

Superconductivity at about 15.6 K was achieved in Tb_{1-x}Ca_xFeAsO by partially substituting Tb^{3+} with Ca^{2+} in the nominal doping region x = 0.40 \sim 0.50. A detailed investigation was carried out in a typical sample with doping…

超导电性 · 物理学 2010-02-28 Gang Mu , Bin Zeng , Peng Cheng , Xiyu Zhu , Fei Han , Bing Shen , Hai-Hu Wen