相关论文: Particle Number Fluctuations for van der Waals Equ…
The van der Waals (VDW) equation of state is a simple and popular model to describe the pressure function in equilibrium systems of particles with both repulsive and attractive interactions. This equation predicts an existence of a…
Particle number fluctuations are considered within the van der Waals (VDW) equation, which contains both attractive (mean-field) and repulsive (eigenvolume) interactions. The VDW equation is used to calculate the scaled variance of particle…
The non-Gaussian measures of the particle number fluctuations -- skewness $S\sigma$ and kurtosis $\kappa \sigma^2$ -- are calculated in a vicinity of the critical point. This point corresponds to the end point of the first-order liquid-gas…
In this paper, we modify the VDW equation of state by adding a temperature factor to it. As a result, we give out a good phase diagram and the correlation of the reduced pressure and the reduced temperature when a balanced liquid-gas…
Equation of state with quantum statistics corrections is derived for a multi-component gas of particles interacting through the repulsive and attractive van der Waals (vdW) forces up to first few orders over a small parameter $\delta…
The renowned van der Waals (VDW) state equation quantifies the equilibrium relationship between pressure $P$, volume $V$ and temperature $k_{B}T$ of a real gas. We assign new variable interpretations adapted to the economic context: $P…
The van der Waals (vdW) theory of fluids is the first and simplest theory that takes into account interactions between the particles of a system that result in a phase transition versus temperature. Combined with Maxwell's construction,…
The van der Waals (VDW) equation of state predicts the existence of a first-order liquid-gas phase transition and contains a critical point. The VDW equation with Fermi statistics is applied to a description of the nuclear matter. The…
The quantum theory of the fluctuations of the van der Waals (vdW) force between macroscopic bodies is developed. Unlike the mean vdW force that is determined by all quantum states that contribute to the optical absorption, the energies of…
The Van der Waal's equation of state for a (slightly) non-ideal classical gas is usually derived in the context of classical statistical mechanics by using the canonical ensemble. We use the hard sphere potential with no short range…
We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…
Taking into account the recently developed van der Waals (VDW) like equation of state (EoS) for grand canonical ensemble of fermions, the temperature dependent profiles of normalized entropy density ($s /T^3$) and the ratio of shear…
A generalization of the quantum van der Waals equation of state for a multi-component system in the grand canonical ensemble is proposed. The model includes quantum statistical effects and allows to specify the parameters characterizing…
The multiplicity fluctuations are studied in the van der Waals excluded volume hadron-resonance gas model. The calculations are done in the grand canonical ensemble within the Boltzmann statistics approximation. The scaled variances for…
The study of Mayer's cluster expansion (CE) for the partition function demonstrates a possible way to resolve the problem of the CE non-physical behavior at condensed states of fluids. In particular, a general equation of state is derived…
The retarded Van der Waals force between a polarizable particle and a perfectly conducting plate is re-examined. The expression for this force given by Casimir and Polder represents a mean force, but there are large fluctuations around this…
A thermodynamic phase transition denotes a drastic change of state of a physical system due to a continuous change of thermodynamic variables, as for instance pressure and temperature. The classical van der Waals equation of state is the…
We extend the Van der Waals equation of state to a universal form and find that the van der Waals equation of state is a special condition of this form. Then a good form of the equation of state for a balanced liquid-gas coexistence…
We present an approach to describing fluctuational electrodynamic (FED) interactions, particularly van der Waals (vdW) interactions as well as radiative heat transfer (RHT), between material bodies of vastly different length scales,…
The equation of state with quantum statistics corrections is used for particle number fluctuations $\omega$ of isotopically symmetric nuclear matter with interparticle van der Waals and Skyrme local density interactions. The fluctuations,…