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Understanding and manipulating work fluctuations in microscale and nanoscale systems are of both fundamental and practical interest. For example, in considering the Jarzynski equality $\langle e^{-\beta W} \rangle=e^{-\beta \Delta F}$, a…

统计力学 · 物理学 2015-08-26 Gaoyang Xiao , Jiangbin Gong

A result of great theoretical and experimental interest, Jarzynski equality predicts a free energy change $\Delta F$ of a system at inverse temperature $\beta$ from an ensemble average of non-equilibrium exponential work, i.e., $\langle…

统计力学 · 物理学 2017-10-18 Juan D. Jaramillo , Jiawen Deng , Jiangbin Gong

The central quantity in the celebrated quantum Jarzynski equality is $e^{-\beta W}$, where $W$ is work and $\beta$ is the inverse temperature. The impact of quantum randomness on the fluctuations of $e^{-\beta W}$ and hence on the…

量子物理 · 物理学 2023-10-24 Wei Cheng , Wenquan Liu , Yang Wu , Zhibo Niu , Chang-Kui Duan , Jiangbin Gong , Xing Rong , Jiangfeng Du

Thermodynamics constrains changes to the energy of a system, both deliberate and random, via its first and second laws. When the system is not in equilibrium, fluctuation theorems such as the Jarzynski equality further restrict the…

Work is one of the most basic notion in statistical mechanics, with work fluctuation theorems being one central topic in nanoscale thermodynamics. With Hamiltonian chaos commonly thought to provide a foundation for classical statistical…

统计力学 · 物理学 2017-02-01 Jiawen Deng , Alvis Mazon Tan , Peter Hanggi , Jiangbin Gong

We present a generalization of Jarzynski's Equality, applicable to quantum systems, relating discretized mechanical work and free-energy changes. The theory is based on a step-wise pulling protocol. We find that work distribution functions…

量子物理 · 物理学 2012-09-21 Van A. Ngo , Stephan Haas

The well-known Jarzynski equality, often written in the form $e^{-\beta\Delta F}=\langle e^{-\beta W}\rangle$, provides a non-equilibrium means to measure the free energy difference $\Delta F$ of a system at the same inverse temperature…

统计力学 · 物理学 2017-08-22 Jiawen Deng , Juan D. Jaramillo , Peter Hanggi , Jiangbin Gong

The classical Jarzynski equality establishes an exact relation between the stochastic work performed on a system driven out of thermal equilibrium and the free energy difference in a corresponding quasi-static process. This fluctuation…

量子物理 · 物理学 2025-08-21 Konstantin Beyer , Walter T. Strunz

We derive exact fluctuation equalities for open systems that recover free energy differences between two equilibrium endpoints connected by nonequilibrium processes with arbitrary dynamics and coupling. The exponential of the free energy…

统计力学 · 物理学 2025-12-15 Mohammad Rahbar , Christopher J. Stein

The Jarzynski equality allows the calculation of free-energy differences using values of work measured from nonequilibrium trajectories. The number of trajectories required to accurately estimate free-energy differences in this way grows…

统计力学 · 物理学 2025-05-13 Stephen Whitelam

The work fluctuations of an oscillator in contact with a heat reservoir and driven out of equilibrium by an external force are studied experimentally. The oscillator dynamics is modeled by a Langevin equation. We find both experimentally…

统计力学 · 物理学 2009-11-11 Frederic Douarche , Sergio Ciliberto , Artem Petrosyan

In this paper, we study Jarzynski's equality and fluctuation theorems for diffusion processes. While some of the results considered in the current work are known in the (mainly physics) literature, we review and generalize these…

数学物理 · 物理学 2019-04-09 Carsten Hartmann , Christof Schuette , Wei Zhang

It has been shown recently that the Jarzynski equality is generalized under nonequilibrium feedback control [T. Sagawa and M. Ueda, Phys. Rev. Lett. {\bf 104}, 090602 (2010)]. The presence of feedback control in physical systems should…

统计力学 · 物理学 2013-05-29 M. Ponmurugan

The free-energy difference $\Delta F$ between two high-dimensional systems is notoriously difficult to compute, but very important for many applications, such as drug discovery. We demonstrate that an unconventional definition of work…

软凝聚态物质 · 物理学 2024-10-24 Adrianne Zhong , Benjamin Kuznets-Speck , Michael R. DeWeese

We consider the paradigm of an overdamped Brownian particle in a potential well, which is modulated through an external protocol, in the presence of stochastic resetting. Thus, in addition to the short range diffusive motion, the particle…

统计力学 · 物理学 2020-03-25 Deepak Gupta , Carlos A. Plata , Arnab Pal

Estimating free-energy differences using nonequilibrium work relations, such as the Jarzynski equality, is hindered by poor convergence when work fluctuations are large. For systems governed by overdamped Langevin dynamics, we propose the…

统计力学 · 物理学 2025-08-14 Stephen Whitelam

The optimal protocols for the irreversible work achieve their maximum usefulness if their work fluctuations are the smallest ones. In this work, for classical and isothermal processes subjected to finite-time and weak drivings, I show that…

统计力学 · 物理学 2023-11-14 Pierre Nazé

From the perspective of quantum thermodynamics, realisable measurements cost work and result in measurement devices that are not perfectly correlated with the measured systems. We investigate the consequences for the estimation of work in…

量子物理 · 物理学 2019-11-05 Tiago Debarba , Gonzalo Manzano , Yelena Guryanova , Marcus Huber , Nicolai Friis

The nonequilibrium work relation, or Jarzynski equality, establishes a statistical relationship between a series of nonequilibrium experiments on a system subjected to thermal fluctuations and a hypothetical experiment at thermodynamic…

统计力学 · 物理学 2024-11-19 Jean-Luc Garden

We consider in this paper, a few important issues in non-equilibrium work fluctuations and their relations to equilibrium free energies. First we show that Jarzynski identity can be viewed as a cumulant expansion of work. For a switching…

统计力学 · 物理学 2015-05-20 M Suman Kalyan , G Anjan Prasad , V S S Sastry , K P N Murthy
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