相关论文: Recent Progress in the Definition of Thermodynamic…
From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…
From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…
The physical foundations of a variety of emerging technologies --- ranging from the applications of quantum entanglement in quantum information to the applications of nonequilibrium bulk and interface phenomena in microfluidics, biology,…
Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…
The entropy of classical thermodynamics is uniquely determined by the relation of adiabatical accessibilty between equilibrium states of thermodynamical systems. This review outlines the logical path leading to this results and the…
This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…
Entropy concept was introduced by Clausius 160 years ago, and has been continually enriched, developed and interpreted by the researchers in many different scientific disciplines ever since. Thermodynamics and other scientific disciplines…
To the student of thermodynamics the most difficult subject is entropy. In this paper we examine the actual, practical application of entropy to two simple systems, the homogeneous slab with fixed boundary values of the temperature, and an…
The available enthalpy is an early form of the modern thermodynamic concept of exergy, which is the generic name for the amount of work obtainable when some matter is brought to a state of equilibrium with its surroundings by means of…
The science of thermodynamics was put together in the Nineteenth Century to describe large systems in equilibrium. One part of thermodynamics defines entropy for equilibrium systems and demands an ever-increasing entropy for non-equilibrium…
Entropy is the distinguishing and most important concept of our efforts to understand and regularize our observations of a very large class of natural phenomena, and yet, it is one of the most contentious concepts of physics. In this…
A realistic and objective axiomatic formulation of Thermostatics for composite systems is presented. The main feature of our axiomatics is that it is free of empirical definitions. In particular, the basic concepts of the theory, such as…
A generally relativistic theory of thermodynamics is developed, based on four main physical principles: heat is a local form of energy, therefore described by a thermal energy tensor; conservation of mass, equivalent to conservation of…
Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A…
We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…
In recent papers, several authors have claimed that a definition of the thermodynamic entropy in terms of the logarithm of a volume in phase space, originally suggested by Gibbs, is the only valid definition. Arguing from the Gibbs entropy,…
It is argued that a typical many body energy eigenstate has a well defined thermodynamic entropy and that individual eigenstates possess thermodynamic characteristics analogous to those of generic isolated systems. We examine large systems…
It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…
Thermodynamic entropy is determined by a heat measurement through the Clausius equality. The entropy then formalizes a fundamental limitation of operations by the second law of thermodynamics. The entropy is also expressed as the Shannon…
In order to undestand how the complex concept of entropy emerged,we propose a trip towards the past reviewing the works of Clausius, Boltzmann, Gibbs and Planck. In particular, since the Gibbs's work is not very well known, we present a…