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We studied the ferroelectric and ferromagnetic properties of compressive strained and unstrained BiMnO3 thin films grown by rf-magnetron sputtering. BiMnO3 samples exhibit a 2D cube-on-cube growth mode and a pseudo-cubic struc-ture up to a…

材料科学 · 物理学 2013-06-06 G. M. De Luca , D. Preziosi , F. Chiarella , R. Di Capua , S. Gariglio , S. Lettieri , M. Salluzzo

The presence of domains in ferroic materials can negatively affect their macroscopic properties and hence their usefulness in device applications. From an experimental perspective, measuring materials comprising multiple domains can…

Here, we report the existence of large remnant polarization and dielectric constant in PbTiO3 buffered polycrystalline (BiFeO_3)_{1-x} (PbTiO_3)_x thin films of composition x = 0.25, 0.30 and 0.35 around the morphotropic phase boundary. The…

The presence of 2D electron gases at surfaces or interfaces in oxide thin films remains a hot topic in condensed matter physics. In particular, BaBiO3 appears as a very interesting system as it was theoretically proposed that its (001)…

In this work we elaborated and characterized nanocomposite thin films using a preselected multiferroic matrix Bi$_{0.9}$Gd$_{0.1}$Fe$_{0.9}$Mn$_{0.1}$O$_3$ (BGFMO) in the aim to enhance their basic ferroelectric and magnetic properties. The…

While nature provides a plethora of perovskite materials, only a few exhibits large ferroelectricity and possibly multiferroicity. The majority of perovskite materials have the non-polar CaTiO$_3$(CTO)structure, limiting the scope of their…

材料科学 · 物理学 2022-05-25 Hongwei Wang , Fujie Tang , Massimiliano Stengel , Hongjun Xiang , Qi An , Tony Low , Xifan Wu

Epitaxial bilayered thin films consisting of La0.6Sr0.4MnO3 (LSMO) and 0.7 Pb(Mg1/3Nb2/3)O3 0.3 PbTiO3 (PMN-PT) layers of relatively different thicknesses were fabricated on LaNiO3 coated LaAlO3 (100) single crystal substrates by pulsed…

材料科学 · 物理学 2011-06-29 Ayan Roy Chaudhuri , S. B. Krupanidhi , P. Mandal , A. Sundaresan

Recently, the perovskite BiCoO$_3$ has been shown experimentally to be isostructural with PbTiO$_3$, while simultaneously the $d^6$ Co$^{3+}$ ion has a high spin ground state with $C$-type antiferromagnetic ordering. Using hybrid density…

材料科学 · 物理学 2016-05-04 Leigh Weston , Xiangyuan Cui , Simon P. Ringer , Catherine Stampfl

Understanding the polarization switching mechanisms at play in ferroelectric materials is crucial for their exploitation in electronic devices. The conventional centrosymmetric reference structure-based mechanism which accounts for…

In the quest for novel magnetoelectric materials, we have grown, stabilized and explored the properties of La3BAlMnO9 (B = Co or Mn) thin films. In this paper, we report the influence of the growth parameters that promote B/Al/Mn ordering…

材料科学 · 物理学 2015-05-18 M. P. Singh , K. D. Truong , S. Jandl , P. Fournier

Under normal conditions, bulk crystals of BiScO$_3$ , BiCrO$_3$, BiMnO$_3$, BiFeO$_3$, and BiCoO$_3$ present three very different variations of the perovskite structure: an antipolar phase, a rhombohedral phase with a large polarization…

材料科学 · 物理学 2018-11-07 Akansha Singh , Viveka N. Singh , Enric Canadell , Jorge Íñiguez , Oswaldo Diéguez

The recent study of oxides led to the discovery of several new fascinating physical phenomena. High-temperature superconductivity, colossal magnetoresistance, dilute magnetic doping, or multiferroicity were discovered and investigated in…

材料科学 · 物理学 2012-01-11 Matthias Opel

While pyrochlore iridate thin films are theoretically predicted to possess a variety of emergent topological properties, experimental verification of these predictions can be obstructed by the challenge in thin film growth. Here we report…

Our first-principles results show that geometric frustration can be induced in thin films of multiferroic BiFeO3. We find that competing magnetic interactions occur in the so-called super-tetragonal phase of this material, which can be…

材料科学 · 物理学 2015-06-05 Carlos Escorihuela-Sayalero , Oswaldo Diéguez , Jorge Íñiguez

Octahedral distortion plays a key role in engineering the physical properties of heterostructures composed of perovskite oxides. We observe a strong in-plane uniaxial magnetic anisotropy in a strain-enabled multiferroic EuTiO3 thin film…

材料科学 · 物理学 2015-06-17 X. Ke , T. Birol , R. Misra , J. -H. Lee , B. J. Kirby , D. G. Schlom , C. J. Fennie , J. W. Freeland

This review covers the important advances in recent years in the physics of thin film ferroelectric oxides, the strongest emphasis being on those aspects particular to ferroelectrics in thin film form. We introduce the current state of…

材料科学 · 物理学 2009-11-11 M. Dawber , K. M. Rabe , J. F. Scott

We report first-principles calculations for one of the few materials that is believed to be a ferroelectric ferromagnet, Bi$_2$NiMnO$_6$. Our calculations show that, contrary to what it has been reported so far, bulk Bi$_2$NiMnO$_6$ does…

材料科学 · 物理学 2017-03-01 Oswaldo Diéguez , Jorge Íñiguez

Perovskite ferroelectric oxides are usually considered to be brittle materials, however, recent work [Dong et al., Science 366, 475 (2019)] demonstrated the super-elasticity in the freestanding BaTiO3 thin films. This property may originate…

材料科学 · 物理学 2020-04-15 Changqing Guo , Guohua Dong , Ziyao Zhou , Ming Liu , Houbing Huang , Jiawang Hong , Xueyun Wang

Multiferroics - materials which are simultaneously (ferro)magnetic and ferroelectric, and often also ferroelastic, attract now considerable attention, both because of the interesting physics involved and as they promise important practical…

强关联电子 · 物理学 2009-11-11 D. I. Khomskii

Strain engineering of perovskite oxide thin films has proven to be an extremely powerful method for enhancing and inducing ferroelectric behavior. In ferroelectric thin films and superlattices, the polarization is intricately linked to…