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The dynamics of flexible polymer molecules are often assumed to be governed by hydrodynamics of the solvent. However there is considerable evidence that internal dissipation of a polymer contributes as well. Here we investigate the dynamics…

软凝聚态物质 · 物理学 2013-05-29 J. M. Deutsch

We revisit the classical problem of a polymer confined in a slit in both of its static and dynamic aspects. We confirm a number of well known scaling predictions and analyse their range of validity by means of comprehensive Molecular…

Langevin dynamics is used to study equilibrium properties of the suspension of magnetic filaments (chains of nanoparticles permanently crosslinked with polymers). It is shown that the filament suspension generally has a larger magnetic…

软凝聚态物质 · 物理学 2018-11-20 Andrey A. Kuznetsov

Recent developments of microscopic mechanical experiments allow the manipulation of individual polymer molecules in two main ways: \textit{uniform} stretching by external forces and \textit{non-uniform} stretching by external fields. Many…

生物物理 · 物理学 2015-06-11 Fabio Manca , Stefano Giordano , Pier Luca Palla , Fabrizio Cleri , Luciano Colombo

Entangled networks of stiff biopolymers exhibit complex dynamic response, emerging from the topological constraints that neighboring filaments impose upon each other. We propose a class of reference models for entanglement dynamics of stiff…

软凝聚态物质 · 物理学 2008-06-23 Felix Höfling , Tobias Munk , Erwin Frey , Thomas Franosch

We present an extensive analysis of the relaxation dynamics of entangled linear polymer melts via long-time molecular dynamics simulations of a generic bead-spring model. We study the mean-squared displacements, the autocorrelation function…

软凝聚态物质 · 物理学 2025-01-17 Alireza F. Behbahani , Friederike Schmid

We use Monte Carlo simulations to study polymer melts consisting of fully flexible and moderately stiff chains in the bond fluctuation model at a volume fraction $0.5$. In order to reduce the local density fluctuations, we test a…

软凝聚态物质 · 物理学 2015-06-24 Hsiao-Ping Hsu

We study the relaxation dynamics of a coarse-grained polymer chain at different degrees of stretching by both analytical means and numerical simulations. The macromolecule is modelled as a string of beads, connected by anharmonic springs,…

软凝聚态物质 · 物理学 2009-11-13 M. Febbo , A. Milchev , V. Rostiashvili , T. A. Vilgis , D. Dimitrov

We study the rotational dynamics of a flexible polymer initially wrapped around a rigid rod and unwinding from it. This dynamics is of interest in several problems in biology and constitutes a fundamental instance of polymer relaxation from…

软凝聚态物质 · 物理学 2014-07-29 Jean-Charles Walter , Marco Baiesi , Enrico Carlon , Helmut Schiessel

We study a model of "elastic" lattice polymer in which a fixed number of monomers $m$ is hosted by a self-avoiding walk with fluctuating length $l$. We show that the stored length density $\rho_m = 1 - <l>/m$ scales asymptotically for large…

统计力学 · 物理学 2010-06-16 Marco Baiesi , Gerard T. Barkema , Enrico Carlon

Active polymers possess numerous unique properties that are quite different from those observed in the system of small active molecule due to the intricate interplay between their activity and topological constraints. This study focuses on…

软凝聚态物质 · 物理学 2024-07-09 Jing Li , Bokai Zhang , Zhi-Yong Wang

The statistical mechanics of a linear non-interacting polymer chain with a large number of monomers is considered with fixed angular momentum. The radius of gyration for a linear polymer is derived exactly by functional integration. This…

软凝聚态物质 · 物理学 2013-05-29 Matthew Brunner , J. M. Deutsch

We study the translocation of a semiflexible polymer through extended pores with patterned stickiness, using Langevin dynamics simulations. We find that the consequence of pore patterning on the translocation time dynamics is dramatic and…

软凝聚态物质 · 物理学 2018-05-02 Rajneesh Kumar , Abhishek Chaudhuri , Rajeev Kapri

The Langevin Equation for cooperative dynamics represents the dynamics of polymer melts with chains of increasing degree of polymerization, covering the full range of behavior from the unentangled to the entangled regime. This equation…

软凝聚态物质 · 物理学 2015-09-30 M. G. Guenza

We consider the probability of knotting in equilateral random polygons in Euclidean 3-dimensional space, which model, for instance, random polymers. Results from an extensive Monte Carlo dataset of random polygons indicate a universal…

统计力学 · 物理学 2022-04-15 A. Xiong , A. J. Taylor , M. R. Dennis , S. G. Whittington

The interplay of topological constraints and Coulomb interactions in static and dynamic properties of charged polymers is investigated by numerical simulations and scaling arguments. In the absence of screening, the long-range interaction…

统计力学 · 物理学 2009-11-07 Paul G. Dommersnes , Yacov Kantor , Mehran Kardar

We use numerical simulations of a bead-spring model chain to investigate the evolution of the conformation of long and flexible elastic fibers in a steady shear flow. In particular, for rather open initial configurations, and by varying a…

软凝聚态物质 · 物理学 2015-06-11 Steve Kuei , Agnieszka M. Slowicka , Maria L. Ekiel-Jezewska , Eligiusz Wajnryb , Howard A. Stone

We simulate the nonlocal Stokesian hydrodynamics of an elastic filament which is active due a permanent distribution of stresslets along its contour. A bending instability of an initially straight filament spontaneously breaks flow symmetry…

We develop a theoretical description of the topological disentanglement occurring when torus knots reach the ends of a semi-flexible polymer under tension. These include decays into simpler knots and total unknotting. The minimal number of…

统计力学 · 物理学 2020-11-04 Michele Caraglio , Boris Marcone , Fulvio Baldovin , Enzo Orlandini , Attilio L. Stella

We study the influence of some quenched disorder in the sequence of monomers on the entropic elasticity of long polymeric chains. Starting from the Kratky-Porod model, we show numerically that some randomness in the favoured angles between…

统计力学 · 物理学 2009-10-30 D. Bensimon , D. Dohmi , M. Mezard