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The exciton transport in the prototypical organic semiconductor Di-Indeno-Perylene (DIP) has been investigated by means of photoluminescence (PL) quenching and interpreted by an advanced exciton diffusion model including interference…

材料科学 · 物理学 2012-07-05 A. K. Topczak , T. Roller , B. Engels , W. Brütting , J. Pfaum

Excitons are widely found in semiconductors. In contrast to inorganic-based semiconductors, where the presence of excitons may need special morphonology, like low-dimensional layer structure, the excitons prevailingly exist in molecular…

应用物理 · 物理学 2022-08-26 Dongcheng Chen , Yanfei Lu , Qiaobo Wang , Shi-Jian Su

Organic dopants are frequently used to surface-dope inorganic semiconductors. The resulted hybrid inorganic-organic materials have a crucial role in advanced functional materials and semiconductor devices. In this article, we study charge…

材料科学 · 物理学 2017-08-01 Xiaoming Wang , Keivan Esfarjani , Mona Zebarjadi

We studied the electron transfer from excitons in adsorbed indoline dye layers across the organic-inorganic interface. The hybrids consist of indoline derivatives on the one hand and different inorganic substrates (TiO$_2$, ZnO,…

We use a frequency-dependent electro-optic technique to measure the hole mobility in small molecule organic semiconductors, such as 6,13 bis(triisopropylsilylethynyl)-pentacene. Measurements are made on semiconductor films in bottom gate,…

材料科学 · 物理学 2012-12-20 Emily G. Bittle , Joseph W. Brill , Joseph P. Straley

We derive exciton-spin interactions from a microscopic correlated model that captures important aspects of the physics of charge-transfer (CT) insulators to address magnetism associated with exciton creation. We present a minimal model…

强关联电子 · 物理学 2023-11-16 Tatsuya Kaneko , Yuta Murakami , Denis Golež , Zhiyuan Sun , Andrew J. Millis

We study theoretically the excitonic nonlinearity in hybrid organic-inorganic Ruddlesden-Popper perovskite thin films. The composite layered structure of these materials allows for flexible modulation of their excitonic response between the…

介观与纳米尺度物理 · 物理学 2022-11-14 D. A. Baghdasaryan , E. S. Hakobyan , D. B. Hayrapetyan , I. V. Iorsh , I. A. Shelykh , V. Shahnazaryan

We develop a theory of the electronic structure and photophysics of interacting chains of \pi- conjugated polymers to understand the differences between solutions and films. While photoexcitation generates only the intrachain exciton in…

材料科学 · 物理学 2009-11-13 Zhendong Wang , Sumit Mazumdar , Alok Shukla

We present a simple but powerful method to determine the thicknesses of the accumulation and depletion layers and the distribution curve of injected carriers in organic field effect transistors. The conductivity of organic semiconductors in…

Understanding charge separation dynamics in organic semiconductor blends is crucial for optimizing the performance of organic photovoltaic solar cells. In this study, we explored the optoelectronic properties and charge separation dynamics…

Many linked processes occur concurrently in strongly excited semiconductors, such as interband and intraband absorption, scattering of electrons and holes by the heated lattice, Pauli blocking, bandgap renormalization and the formation of…

Excitons in organic crystalline semiconductors play a crucial role in the operation of optoelectronic devices such as organic solar cells, light-emitting diodes, and photodetectors. The excitonic properties of materials are dramatically…

材料科学 · 物理学 2023-10-25 M. V. Klymenko , L. Z. Tan , S. P. Russo , J. H. Cole

Long-range and fast transport of coherent excitons is important for development of high-speed excitonic circuits and quantum computing applications. However, most of these coherent excitons have only been observed in some low-dimensional…

We have used an electro-optic technique to measure the position-dependent infrared absorption of holes injected into a thin crystal of the organic semiconductor, 6,13-bis(triisopropylsilylethynyl)-pentacene incorporated in a field-effect…

材料科学 · 物理学 2015-05-18 E. G. Bittle , J. W. Brill , J. E. Anthony

The interplay between strong light-matter interactions and charge doping represents an important frontier in the pursuit of exotic many-body physics and optoelectronics. Here, we consider a simplified model of a two-dimensional…

介观与纳米尺度物理 · 物理学 2021-05-19 Guangyao Li , Olivier Bleu , Meera M. Parish , Jesper Levinsen

The pioneering experiments of Karl H. Drexhage explained the classical interaction of light with matter and the modification of the decay rates of an emitter.1 Here, we tried to mimic these experiments in a slightly different configuration…

材料科学 · 物理学 2023-01-26 Kuljeet Kaur , Pooja Bhatt , Ben Johns , Jino George

Harnessing the optoelectronic response of organic semiconductors requires a thorough understanding of the fundamental light-matter interaction that is dominated by the excitation of correlated electron-hole pairs, i.e. excitons. The nature…

Charge transfer states in organic semiconductors play crucial roles in processes such as singlet fission and exciton dissociation at donor/acceptor interfaces. Recently, a time-resolved spectroscopy study of…

化学物理 · 物理学 2016-02-19 Takatoshi Fujita , Sule Atahan-Evrenk , Nicolas P. D. Sawaya , Alan Aspuru-Guzik

A series of bowl-shaped dicyclopenta perylene (DCPP) derivatives have been theoretically constructed by indeno-substitution at the peri-positions of DCPP, and suitably functionalizing with aza-, fluoride and imide-groups to enhance the…

材料科学 · 物理学 2021-11-23 Suryakanti Debata , Nataliya N Karaush , Sridhar Sahu

We probe charge photogeneration and subsequent recombination dynamics in neat regioregular poly(3-hexylthiophene) films over six decades in time by means of time-resolved photoluminescence spectroscopy. Exciton dissociation at 10K occurs…

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