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Composites comprising Poly(Methyl Methacrylate) (PMMA) and CaCu3Ti4O12 (CCTO) via melt mixing followed by hot pressing were fabricated. These were characterized using X-ray diffraction (XRD), thermo gravimetric (TGA), scanning electron…

材料科学 · 物理学 2013-01-18 P. Thomas , R. S. Ernest Ravindran , K. B. R. Varma

The possibility of obtaining relatively high dielectric constant polymer-ceramic composite by incorporating the giant dielectric constant material, CaCu3Ti4O12 (CCTO) in a Poly(vinylidene fluoride) (PVDF) polymer matrix by melt mixing and…

材料科学 · 物理学 2013-01-18 P. Thomasa , K. T. Varughese , K. Dwarakanath , K. B. R. Varma

Poly(Methyl Methacrylate) (PMMA) and CaCu3Ti4O12 (CCTO) composites were fabricated via melt mixing followed by hot pressing technique. These were characterized using X-ray diffraction (XRD), thermo gravimetric (TGA), Thermo Mechanical…

材料科学 · 物理学 2013-01-21 P. Thomas , R. S. Ernest Ravindran , K. B. R. Varma

We have measured dielectric properties of Ca$_{1+x}$Cu$_{3-x}$Ti$_4$O$_{12}$ ($x$ = 0, 0.1, 0.5, 1, 1.5, 2, 2.9 and 3), and have found that Ca$_2$Cu$_2$Ti$_4$O$_{12}$ (a composite of CaCu$_3$Ti$_4$O$_{12}$ and CaTiO$_3$) exhibits a high…

材料科学 · 物理学 2009-11-11 W. Kobayashi , I. Terasaki

The Poly(vinylidene fluoride)/CaCu3Ti4O12 (CCTO) nanocrystal composite films (85nm) with relatively high dielectric permittivity (90 at 100Hz) were prepared by the solution casting followed by spin coating technique. The structural, the…

材料科学 · 物理学 2013-01-18 P. Thomas , S. Satapathy , K. Dwarakanath , K. B. R. Varma

The origins of an ultrahigh dielectric constant in polycrystalline CaCu3Ti4O12 (CCTO) was studied using the combination of impedance spectroscopy, electron microscopy, and scanning probe microscopy (SPM). Impedance spectra indicate that the…

材料科学 · 物理学 2009-11-10 S. V. Kalinin , J. Shin , G. M. Veith , A. P. Baddorf , M. V. Lobanov , H. Runge , M. Greenblatt

The cubic perovskite-related ceramic CaCu3Ti4O12 has a very high static dielectric constant ~10000 at room temperature (RT), which drops to about 100 below about 100 K. Substituting Cd for Ca reduces the RT value of the dielectric constant…

强关联电子 · 物理学 2007-05-23 C. C. Homes , T. Vogt , S. M. Shapiro , W. Si , S. Wakimoto , M. A. Subramanian

A thorough investigation of the dielectric properties of Cu2Ta4O12, a material crystallizing in a pseudo-cubic, perovskite-derived structure is presented. We measured the dielectric constant and conductivity of single crystals in an…

材料科学 · 物理学 2009-11-10 B. Renner , P. Lunkenheimer , M. Schetter , A. Loidl , A. Reller , S. G. Ebbinghaus

The dielectric constant of CaCu3Ti4O12 is measured with a different electrode geometry than previous measurements. Similar colossal values are obtained showing that they are "intrinsic" to the material. We show that in braced structures…

凝聚态物理 · 物理学 2007-05-23 A. P. Ramirez , G. Lawes , V. Butko , M. A. Subramanian , C. M. Varma

We observe the large enhancement in the dielectric response near the percolation threshold in a composite nanoparticle system consisting of metallic RuO$_2$ grains embedded into dielectric CaCu$_3$Ti$_4$O$_1$$_2$ (CCTO) matrix and annealed…

材料科学 · 物理学 2015-06-19 Rupam Mukherjee , Gavin Lawes , Boris Nadgorny

The glasses in the system (100-x)TeO2-xCaCu3Ti4O12, (x=0.25 to 3 mol %) were fabricated. The color varied from olive green to brown as the CaCu3Ti4O12 (CCTO) content increased in TeO2 matrix. The X-ray powder diffraction and differential…

材料科学 · 物理学 2013-01-22 P. Thomas , K. B. R. Varma

High dielectric constant nano composite of Polyaniline (PANI) CaCu3Ti4O12 (CCTO) was synthesized using a simple procedure involving in-situ polymerization of aniline in dil. HCl. The PANI and the composite were subjected to X-ray…

材料科学 · 物理学 2013-01-18 P. Thomas , K. Dwarakanath , K. B. R. Varma

In the present work we demonstrate that in addition to the well-known colossal-dielectric-constant material CaCu3Ti4O12 also various members of the series Ln2/3Cu3Ti4O12 with Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er and Tm, exhibit…

材料科学 · 物理学 2010-03-25 J. Sebald , S. Krohns , P. Lunkenheimer , S. G. Ebbinghaus , S. Riegg , A. Reller , A. Loidl

High-kappa dielectrics for insulating layers are a current key ingredient of microelectronics. X2O3 sesquioxide compounds are among the candidates. Here we show for a typical material of this class, ScO3, that the relatively modest…

材料科学 · 物理学 2009-11-13 Pietro Delugas , Vincenzo Fiorentini , Alessio Filippetti

The dielectric properties of CaCu3Ti4O12, a material showing colossal values of the dielectric constant, were investigated in a broad temperature and frequency range extending up to 1.3 GHz. A detailed equivalent circuit analysis of the…

材料科学 · 物理学 2009-11-10 P. Lunkenheimer , R. Fichtl , S. G. Ebbinghaus , A. Loidl

The dispersal of high dielectric constant ferroelectric ceramic material Ba(0.7)Sr(0.3)TiO(3) (Tc~30 C) and Ba(0.88)Sr(0.12)TiO(3) (Tc~90 C) in an ion conducting polymer electrolyte (PEO:NH4I) is reported to result in an increase in the…

化学物理 · 物理学 2009-11-10 Pramod Kumar Singh , Amreesh Chandra

Recently, materials exhibiting colossal dielectric constant ($CDC$) have attracted significant attention because of their high dielectric constant and potential applications in electronic devices, such as high dielectric capacitors,…

材料科学 · 物理学 2013-09-19 K. Liu , X. Y. Zhang

We present dielectric measurements of the colossal dielectric constant material CaCu3Ti4O12 extending up to 1.3 GHz also covering so far only rarely investigated single crystalline samples. Special emphasis is put on the second relaxation…

材料科学 · 物理学 2007-07-19 S. Krohns , P. Lunkenheimer , S. G. Ebbinghaus , A. Loidl

Dielectric capacitors are critical components in electronics and energy storage devices. The polymer based dielectric capacitors have advantages of flexibility, fast charge and discharge, low loss, and graceful failure. Elevating the use of…

Many transition-metal oxides show very large ("colossal") magnitudes of the dielectric constant and thus have immense potential for applications in modern microelectronics and for the development of new capacitance-based energy-storage…

强关联电子 · 物理学 2015-03-13 P. Lunkenheimer , S. Krohns , S. Riegg , S. G. Ebbinghaus , A. Reller , A. Loidl
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