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We investigate the normal state of the superconducting compound PuCoGa$_5$ using the combination of density functional theory (DFT) and dynamical mean field theory (DMFT), with the continuous time quantum Monte Carlo (CTQMC) and the…

强关联电子 · 物理学 2018-08-01 W. H. Brito , S. Choi , Y. X. Yao , G. Kotliar

Actinide materials play a special role in condensed matter physics, spanning behaviours of itinerant d-electron and localized 4f-electron materials. An intermediate state, found notably in Pu-based materials whose 5f electrons are neither…

Electronic correlations and spin-orbit interactions in plutonium create variations in the bonding behavior of each of its allotropes. In $\delta$-Pu, the 5f electrons lie at the tipping point between itinerant and localized behavior which…

材料科学 · 物理学 2024-05-16 Alexander R. Muñoz , Travis E. Jones

We present a theoretical model of the electronic structure of delta-Pu that is consistent with many of the electronic structure related properties of this complex metal. In particular we show that the theory is capable of reproducing the…

By LDA+U method with spin-orbit coupling (LDA+U+SO) the magnetic state and electronic structure have been investigated for plutonium in \delta and \alpha phases and for Pu compounds: PuN, PuCoGa5, PuRh2, PuSi2, PuTe, and PuSb. For metallic…

强关联电子 · 物理学 2007-05-23 A. O. Shorikov , A. V. Lukoyanov , M. A. Korotin , V. I. Anisimov

We report the results of inelastic neutron scattering experiments on NpCoGa$_{5}$, an isostructural analogue of the PuCoGa$_{5}$ superconductor. Two energy scales characterize the magnetic response in the antiferromagnetic phase. One is…

强关联电子 · 物理学 2007-09-15 N. Magnani , A. Hiess , R. Caciuffo , E. Colineau , F. Wastin , J. Rebizant , G. H. Lander

We report on results of the first realistic electronic structure calculations of the Pu-based PuCoGa5 superconductor based on the dynamical mean field theory. We find that dynamical correlations due to the local Coulomb interaction between…

强关联电子 · 物理学 2009-11-11 L. V. Pourovskii , M. I. Katsnelson , A. I. Lichtenstein

Recently, superconductivity in PuCoGa5 was discovered. It has the same crystal structure as CeMIn5(M=Ir, Co, Rh). The electron correlation in PuCoGa5 is estimated to be weak compared with CeMIn5, and the filling number of electrons is…

超导电性 · 物理学 2009-11-10 Kazunori Tanaka , Hiroaki Ikeda , Kosaku Yamada

The electronic structures of the actinide elements U, Np, Pu, Am, Cm and Bk are investigated within the self-interaction corrected local spin density approximation. This method allows to describe a dual character of the 5f electrons, some…

强关联电子 · 物理学 2009-11-11 A. Svane , L. Petit , Z. Szotek , W. M. Temmerman

The intricate interplay between itinerant-localized 5f states and strongly correlated electronic states have been systematically investigated in isostructural actinide compounds AnSn3 (An=U, Np, Pu) by using a combination of the density…

强关联电子 · 物理学 2024-01-10 Haiyan Lu , Li Huang

Since their discovery nearly a decade ago, plutonium-based superconductors have attracted considerable interest, which is now heightened by the latest discovery of superconductivity in PuCoIn5. In the framework of density functional theory…

强关联电子 · 物理学 2015-05-28 Jian-Xin Zhu , P. H. Tobash , E. D. Bauer , F. Ronning , B. L. Scott , K. Haule , G. Kotliar , R. C. Albers , J. M. Wills

Plutonium (Pu), in which the 5$f$ valence electrons always wander the boundary between localized and itinerant states, exhibits quite complex crystal structures and unprecedentedly anomalous properties with respect to temperature and…

强关联电子 · 物理学 2020-03-26 Li Huang , Haiyan Lu

Based on its condensed-matter properties, crystal structure, and metallurgy, which includes a phase diagram with six allotropic phases, plutonium is one of the most complicated pure elements in its solid state. Its anomalous properties,…

强关联电子 · 物理学 2015-05-20 Jian-Xin Zhu , R. C. Albers , K. Haule , J. M. Wills

Correlation effects are important for making predictions in the delta phase of Pu. Using a realistic treatment of the intra-atomic Coulomb correlations we address the long-standing problem of computing ground state properties. The…

强关联电子 · 物理学 2016-08-31 S. Savrasov , MPI Stuttgart , G. Kotliar , Rutgers New Jersey

We have measured X-ray magnetic circular dichroism (XMCD) spectra at the Pu $M_{4,5}$ absorption edges from a newly-prepared high-quality single crystal of the heavy fermion superconductor $^{242}$PuCoGa$_{5}$, exhibiting a critical…

强关联电子 · 物理学 2017-10-16 N. Magnani , R. Eloirdi , F. Wilhelm , E. Colineau , J. -C. Griveau , A. B. Shick , G. H. Lander , A. Rogalev , R. Caciuffo

A century on from its discovery, a complete fundamental understanding of superconductivity is still missing. Considerable research efforts are currently devoted to elucidating mechanisms by which pairs of electrons can bind together through…

The puzzling absence of Pu magnetic moments in a PuAm environment is explored using the self-consistent Dynamical Mean Field Theory (DMFT) calculations in combination with the Local Density Approximation. We argue that delta-Pu -Am alloys…

强关联电子 · 物理学 2008-09-26 J. H. Shim , K. Haule , S. Savrasov , G. Kotliar

The symmetry of the superconducting order parameter in single-crystalline PuCoGa$_5$ ($T_{\rm c} = 18.5$ K) is investigated via zero- and transverse- field muon spin relaxation ($\mu$SR) measurements, probing the possible existence of…

To elucidate the localized-itinerant dual nature and orbital dependent correlations of Pu-5f valence electrons in plutonium borides (PuBx, x=1, 2, 6, 12), the electronic structures are throughout investigated by using the combination of…

强关联电子 · 物理学 2023-09-21 Haiyan Lu , Li Huang

The {\em around-mean-field} LSDA+U correlated band theory is applied to investigate the electronic and magnetic structure of $fcc$-Pu-Am alloys. Despite a lattice expansion caused by the Am atoms, neither tendency to 5$f$ localization nor…

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