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The electronic structure of the first Pu based superconductor PuCoGa5 is explored using photoelectron spectroscopy and a novel theoretical scheme. Exceptional agreement between calculation and experiment defines a path forward for…

We present measurements of the thermoelectric power of the plutonium-based unconventional superconductor PuCoGa$_{5}$. The data is interpreted within a phenomenological model for the quasiparticle density of states of intermediate valence…

强关联电子 · 物理学 2016-11-10 K. Gofryk , J-C. Griveau , P. S. Riseborough , T. Durakiewicz

Recent experiments on CeCoIn5 -- a prototypical d-wave superconductor -- indicate that its normal state lies near an unconventional quantum critical point (QCP). One intriguing hypothesis is that quantum-critical fluctuations promote…

Antiferromagnetic (AFM) (or spin-density wave) quantum critical fluctuation enhanced just below H_c2(0) have been often observed in d-wave superconductors with a strong Pauli paramagnetic depairing (PD) including CeCoIn_5. It is shown here…

超导电性 · 物理学 2015-05-18 Ryusuke Ikeda , Yuhki Hatakeyama , Kazushi Aoyama

Applied pressure drives the heavy-fermion antiferromagnet CeRhIn$_{5}$ towards a quantum critical point that becomes hidden by a dome of unconventional superconductivity. Magnetic fields suppress this superconducting dome, unveiling the…

Some of the most remarkable phenomena---and greatest theoretical challenges---in condensed matter physics arise when $d$ or $f$ electrons are neither fully localized around their host nuclei, nor fully itinerant. This localized/itinerant…

We investigate the nature of the 5$f$ electrons in the unconventional odd-parity superconductor UTe$_2$, focusing on the degree of covalency, localization versus itinerancy, and dominant electronic configuration. This is achieved using…

Unconventional superconductivity in many materials is believed to be mediated by magnetic fluctuations. It is an open question how magnetic order can emerge from a superconducting condensate and how it competes with the magnetic spin…

强关联电子 · 物理学 2017-11-08 D. G. Mazzone , S. Raymond , J. L. Gavilano , P. Steffens , A. Schneidewind , G. Lapertot , M. Kenzelmann

The correlated band theory implemented as a combination of the local density approximation with the exact diagonalization of the Anderson impurity model is applied to PuO$_2$. We obtain an insulating electronic structure consistent with the…

材料科学 · 物理学 2014-12-10 A. B. Shick , J. Kolorenc , L. Havela , T. Gouder , R. Caciuffo

We outline key elements of a theory that accounts for anomalous properties of the PuCoGa$_5$ and PuRhGa$_5$ compounds as a consequence of a two-body interference between two Kondo screening channels. Virtual valence fluctuations of the…

强关联电子 · 物理学 2009-11-13 M. Dzero , P. Coleman

The Kondo effects of an Anderson impurity embedded into a d-wave superconductor is studied. Within the slave-boson mean-field approach, the derived Bogoliubov-de Gennes equations are solved via exact diagonalization. We show that a critical…

超导电性 · 物理学 2009-10-31 Jian-Xin Zhu , C. S. Ting

The heavy fermion superconductor CeCoIn_5 can be tuned between superconducting and antiferromagnetic ground states by hole doping with Cd. Nuclear magnetic resonance (NMR) data indicate that these two orders coexist microscopically with an…

强关联电子 · 物理学 2007-10-02 R. R. Urbano , B. -L. Young , N. J. Curro , J. D. Thompson , L. D. Pham , Z. Fisk

We present superfluid density calculations for the unconventional superconductor PuCoGa$_5$ by solving the real-space Bogoliubov-de Gennes equations on a square lattice within the Swiss Cheese model in the presence of strong on-site…

超导电性 · 物理学 2012-04-30 Tanmoy Das , Jian-Xin Zhu , Matthias J. Graf

A procedure for quantifying the U $5f$ electrons' covalence and degree of localization in U intermetallic compounds is presented. To this end, bulk sensitive hard and soft x-ray photoelectron spectroscopy were utilized in combination with…

An understanding of the phase diagram of elemental plutonium (Pu) must include both the effects of the strong directional bonding and the high density of states of the Pu 5f electrons, as well as how that bonding weakens under the influence…

强关联电子 · 物理学 2015-06-18 Jian-Xin Zhu , R. C. Albers , K. Haule , G. Kotliar , J. M. Wills

Plutonium-based compounds establish an ideal platform for exploring the interplay between long-standing itinerant-localized 5$f$ states and strongly correlated electronic states. In this paper, we exhaustively investigate the correlated…

强关联电子 · 物理学 2023-09-21 Haiyan Lu , Li Huang

We compare the trends on the strength of electronic correlations across the different phases of elemental Pu focusing on its site and orbital dependence, using a combination of density functional theory (DFT) and dynamical mean field theory…

强关联电子 · 物理学 2021-01-04 W. H. Brito , G. Kotliar

We investigate the electronic state and the superconductivity in the 5-orbital Hubbard model for iron pnictides by using the dynamical mean-field theory in conjunction with the Eliashberg equation. The renormalization factor exhibits…

超导电性 · 物理学 2013-11-26 Jun Ishizuka , Takemi Yamada , Yuki Yanagi , Yoshiaki Ono

The intermediate valence of Ce in CeCo$_5$ challenges standard density functional theory (DFT) and static DFT+$U$ approaches, which fail to capture its magnetic properties. By combining DFT+$U$ with exact diagonalization of the Anderson…

强关联电子 · 物理学 2026-04-21 Alexander B. Shick , Evgenia A. Tereshina-Chitrova

The spectra of Pu chalcogenides and pnictides are computed with LDA+DMFT and interpreted with the aid of valence histograms and slave-boson calculations. We find the chalcogenides are mixed-valent ($n_f = 5.2$) materials with a strongly…

强关联电子 · 物理学 2010-01-11 Chuck-Hou Yee , Gabriel Kotliar , Kristjan Haule