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Ignition delay times of cyclopentene-oxygen-argon mixtures were measured behind reflected shock waves. Mixtures contained 0.5 or 1 % of hydrocarbons for equivalence ratios ranging from 0.5 to 1.5. Reflected shock waves conditions were:…

The autoignition delays of mixtures of methyl-cyclohexane (MCH), oxygen, nitrogen, and argon have been studied in a heated rapid compression machine under the conditions $P_C$ = 50 bar, $T_C$ = 690 - 910K. Three different mixture…

Autoignition delay times have been measured in a rapid compression machine at Lille at temperatures after compression from 630 to 840 K, pressures from 8 to 14 bar, \Phi = 1 and for a iso octane/1 hexene mixture containing 82% iso-octane…

Ignition delay times of cyclohexane-oxygen-argon and cyclopentane-oxygen-argon mixtures have been measured in a shock tube, the onset of ignition being detected by OH radical emission. Mixtures contained 0.5 or 1 % of hydrocarbon for…

Autoignition delay times, ?, of methyl crotonate, methyl acrylate, ethyl butanoate, ethyl crotonate, and ethyl acrylate were studied in shock tube experiments. A series of mixtures diluted with argon, of varying fuel/oxygen equivalence…

This paper describes an experimental and modeling study of the oxidation of the three isomers of xylene (ortho-, meta- and para-xylenes). For each compound, ignition delay times of hydrocarbon-oxygen-argon mixtures with fuel equivalence…

Autoignition delay experiments for the isomers of butanol, including n-, sec-, tert-, and iso-butanol, have been performed using a heated rapid compression machine. For a compressed pressure of 15 bar, the compressed temperatures have been…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Kamal Kumar , Chih-Jen Sung

New experimental data are collected for methyl-cyclohexane (MCH) autoignition in a heated rapid compression machine (RCM). Three mixtures of MCH/O2/N2/Ar at equivalence ratios of $\phi$=0.5, 1.0, and 1.5 are studied and the ignition delays…

化学物理 · 物理学 2017-06-12 Bryan W. Weber , WIlliam J. Pitz , Marco Mehl , Emma Silke , Alexander C. Davis , Chih-Jen Sung

In this work, oblique detonation of n-heptane/air mixture in high-speed wedge flows is simulated by solving the reactive Euler equations with a two-dimensional (2D) configuration. This is a first attempt to model complicated hydrocarbon…

流体动力学 · 物理学 2022-02-11 Hongbo Guo , Yong Xu , Hongtao Zheng , Huangwei Zhang

The details of ignition of Type Ia supernovae remain fuzzy, despite the importance of this input for any large-scale model of the final explosion. Here, we begin a process of understanding the ignition of these hotspots by examining the…

天体物理学 · 物理学 2009-11-13 L. Jonathan Dursi , F. X. Timmes

Autoignition delay experiments were performed for n-butanol in a heated rapid compression machine. Experiments were performed at pressures of 15 and 30 bar, in the temperature range 650-900 K, and for equivalence ratios of 0.5, 1.0, and…

化学物理 · 物理学 2017-06-12 Bryan W. Weber

In order to better understand the chemistry involved during the combustion of components of diesel fuel, the structure of a laminar lean premixed methane flame doped with indane has been investigated. The gases of this flame contains 7.1%…

Investigation of the autoignition delay of the butanol isomers has been performed at elevated pressure of 15 bar and low to intermediate temperatures of 725-870 K. Stoichiometric mixtures made in nitrogen/oxygen air were studied. For the…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Chih-Jen Sung

In the context of the search for gasoline surrogates for kinetic modeling purpose, this paper describes a new model for the low-temperature auto-ignition of n-heptane/iso-octane/hexene/toluene blends for the different linear isomers of…

Autoignition experiments for n-butanol have been performed using a heated rapid compression machine at compressed pressures of 15 and 30 bar, in the compressed temperature range of 675-925 K, and for equivalence ratios of 0.5, 1.0, and 2.0.…

化学物理 · 物理学 2017-06-06 Bryan W. Weber , Kamal Kumar , Yu Zhang , Chih-Jen Sung

Methyl valerate (C$_6$H$_{12}$O$_2$, methyl pentanoate) is a methyl ester and a relevant surrogate component for biodiesel. In this work, we present ignition delays of methyl valerate measured using a rapid compression machine at a range of…

化学物理 · 物理学 2017-06-07 Bryan W. Weber , Justin Bunnell , Kamal Kumar , Chih-Jen Sung

Autoignition of n-heptane droplet/vapor/air mixtures behind an oblique shock wave are studied, through Eulerian-Lagrangian method and a skeletal chemical mechanism. The effects of gas/liquid equivalence ratio (ER), droplet diameter, flight…

流体动力学 · 物理学 2022-12-16 Hongbo Guo , Yong Xu , Ningbo Zhao , Huangwei Zhang

Dynamics of ethylene autoignition and Deflagration-to-Detonation Transition (DDT) in a one-dimensional shock tube are numerically investigated using a skeletal chemistry including 10 species and 10 reactions. Different combustion modes are…

流体动力学 · 物理学 2022-08-24 Zhiwei Huang , Huangwei Zhang

Butanol, an alcohol which can be produced from biomass sources, has received recent interest as an alternative to gasoline for use in spark ignition engines and as a possible blending compound with fossil diesel or biodiesel. Therefore, the…

We report consistent ignition of high-pressure (p > 20-30 bar) hydrogen-oxygen mixtures diluted with helium, using an unfocused Nd:YAG laser. This corresponds to laser irradiances several orders of magnitude below the minimum ignition…

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