相关论文: Heterogeneous Nucleation in the Low Barrier Regime
We introduce a general formalism to analyze nucleation phenomena in inhomogeneous media which considers the influence of the metastable phase, which is treated as a heat bath in which clusters are embedded, in the dynamics of the nucleation…
We investigate metastability in the two dimensional Ising model in a square with free boundary conditions at low temperatures. Starting with all spins down in a small positive magnetic field, we show that the exit from this metastable phase…
Advanced phase-field techniques have been applied to address various aspects of polycrystalline solidification including different modes of crystal nucleation. The height of the nucleation barrier has been determined by solving the…
The liquid-vapor transition is a classic example of a discontinuous (first-order) phase transition. Such transitions underlie many phenomena in cosmology, nuclear and particle physics, and condensed-matter physics. They give rise to…
A ``persistence'' exponent theta has been extensively used to describe the nonequilibrium dynamics of spin systems following a deep quench: for zero-temperature homogeneous Ising models on the d-dimensional cubic lattice, the fraction p(t)…
The homogeneous and heterogeneous nucleation of a Lennard-Jones liquid is investigated using the umbrella sampling method. The free energy cost of forming a nucleating droplet is determined as a function of the quench depth, and the saddle…
We study the stability, the clustering and the phase-diagram of free cooling granular gases. The systems consist of mono-disperse particles with additional non-contact (long-range) interactions, and are simulated here by the event-driven…
We investigate the thermodynamical stability of low-density isospin-symmetric nuclear matter at finite temperature, explicitly including light clusters as degrees of freedom. Within a generalized mean-field framework, we compute the…
Systems with long-range interactions when quenced into a metastable state near the pseudo-spinodal exhibit nucleation processes that are quite different from the classical nucleation seen near the coexistence curve. In systems with…
We investigate the approach to stable and metastable equilibrium in Ising models using a cluster representation. The distribution of nucleation times is determined using the Metropolis algorithm and the corresponding $\phi^{4}$ model using…
An analytical model for the evolution of the boundary of the new phase in transformations ruled by nucleation and growth is presented. Both homogeneous and heterogeneous nucleation have been considered: The former includes transformations…
Transient homogeneous nucleation is studied in the limit of large critical sizes. Starting from pure monomers, three eras of transient nucleation are characterized in the classic Becker-D\"oring kinetic equations with two different models…
We investigate the Ising model on finite subgraphs of the hyperbolic lattice under minus boundary conditions and in the presence of a positive external field $h$. Interpreting the boundary as frozen or cold wall conditions, we show that,…
We present in this paper an exact study concerning a first order transition induced by an inhomogeneous boundary magnetic field in the 2D Ising model. From a previous analysis of the interfacial free energy in the discrete case (J. Phys. A,…
In a solid-state diffusional phase transformation involving nucleation and growth, the size of the critical nucleus for a homogeneous process (r*homo=r* ) has been assumed to be a time invariant constant of the transformation. The strain…
Flat walls facilitate the condensation of a supersaturated vapor: Classical theory of heterogeneous nucleation predicts that the free energy barrier $\Delta F_{\rm het}^*$ which needs to be overcome for the formation of sphere-cap shaped…
Phase diagrams of some globular proteins have a fluid-fluid transition as well as a fluid-crystal transition. Homogeneous nucleation of the crystal from the fluid phase near the critical point of the fluid-fluid transition is examined. As…
We consider an isolated point defect embedded in a homogeneous crystalline solid. We show that, in the harmonic approximation, a periodic supercell approximation of the formation free energy as well as of the transition rate between two…
The crystallisation of entangled polymers from their melt is investigated using computer simulation with a coarse-grained model. Using hybrid Monte Carlo simulations enables us to probe the behaviour of long polymer chains. We identify…
We develop a model in the framework of nuclear fragmentation at thermodynamic equilibrium which can be mapped onto an Ising model with constant magnetization. We work out the thermodynamic properties of the model as well as the properties…