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The temperature-induced shift of the Raman G line in epitaxial graphene on SiC and Ni surfaces, as well as in graphene supported on SiO2, is investigated with Raman spectroscopy. The thermal shift rate of epitaxial graphene on 6H-SiC(0001)…

介观与纳米尺度物理 · 物理学 2011-02-18 Nicola Ferralis , Roya Maboudian , Carlo Carraro

We probe the local inhomogeneities of the electronic properties of graphene at the nanoscale using scanning probe microscopy techniques. First, we focus on the study of the electronic inhomogeneities caused by the graphene-substrate…

介观与纳米尺度物理 · 物理学 2012-10-16 A. Castellanos-Gomez , Arramel , M. Wojtaszek , R. H. M. Smit , N. Tombros , N. Agraït , B. J. van Wees , G. Rubio-Bollinger

Chemical functionalization of graphene modifies the local electron density of the carbon atoms and hence electron transport. Measuring these changes allows for a closer understanding of the chemical interaction and the influence of…

介观与纳米尺度物理 · 物理学 2010-12-17 A. Jacobsen , F. M. Koehler , W. J. Stark , K. Ensslin

We investigate the influence of SiO2, Au, Ag, Cu, and Pt substrates on the Raman spectrum of graphene. Experiments reveal particularly strong modifications to the intensity, position, width, and shape of the Raman signal of graphene on…

材料科学 · 物理学 2015-06-16 Qin Zhou , Sinisa Coh , Marvin L. Cohen , Steven G. Louie , A. Zettl

Conventional field effect transistor operation in graphene is limited by its zero gap and minimum quantum conductivity. In this work, we report on controlled electrochemical modification of graphene such that its conductance changes by more…

材料科学 · 物理学 2007-12-13 T. J. Echtermeyer , M. C. Lemme , M. Baus , B. N. Szafranek , A. K. Geim , H. Kurz

Chemical, mechanical, thermal and/or electronic properties of bulk or low-dimensional materials can be engineered by introducing structural defects to form novel functionalities. When using particles irradiation, these defects can be…

材料科学 · 物理学 2022-02-07 L. Basta , A. Moscardini , S. Veronesi , F. Bianco

We analyze the electrostatic interactions between a single graphene layer and a SiO$_2$ susbtrate, and other materials which may exist in its environment. We obtain that the leading effects arise from the polar modes at the SiO$_2$ surface,…

材料科学 · 物理学 2009-11-13 J. Sabio , C. Seoanez , S. Fratini , F. Guinea , A. H. Castro Neto , F. Sols

Few-layer graphene deposited on semiconductor nanorods separated by undoped spacers has been studied in perspective for the fabrication of stable nanoresonators. We show that an applied bias between the graphene layer and the nanorod…

Covalently functionalizing mechanical exfoliated monolayer and bilayer graphenides with {\lambda}-iodanes led to the discovery that the monolayers supported on a SiO2 substrate are considerably more reactive than bilayers as demonstrated by…

Monolayer graphene was deposited on a Si wafer substrate decorated with SiO2 nanoparticles (NPs) and then exposed to aryl radicals that were generated in situ from their diazonium precursors. Using micro-Raman mapping, the aryl radicals…

材料科学 · 物理学 2012-11-28 Q. Wu , Y. Wu , Y. Hao , J. Geng , M. Charlton , S. Chen , Y. Ren , H. Ji , H. Li , D. W. Boukhvalov , R. D. Piner , C. W. Bielawski , R. S. Ruoff

Intercalation reactions modify the charge density in van der Waals (vdW) materials through coupled electronic-ionic charge accumulation, and are susceptible to modulation by interlayer hybridization in vdW heterostructures. Here, we…

We study the effects of polarizable substrates such as SiO2 and SiC on the carrier dynamics in graphene. We find that the quasiparticle spectrum acquires a finite broadening due to the long-range interaction with the polar modes at the…

介观与纳米尺度物理 · 物理学 2009-11-13 S. Fratini , F. Guinea

In this paper we show how single layer graphene can be utilized to study swift heavy ion (SHI) modifications on various substrates. The samples were prepared by mechanical exfoliation of bulk graphite onto SrTiO$_3$, NaCl and Si(111),…

材料科学 · 物理学 2015-06-12 O. Ochedowski , S. Akcöltekin , B. Ban d`Etat , H. Lebius , M. Schleberger

Graphene modifications with oxygen or hydrogen are well known in contrast to carbon attachment to the graphene lattice. The chemical modification of graphene sheets with aromatic diazonium ions (carbon attachment) is analyzed by confocal…

We report mid-infrared photocurrent spectra of graphene nanoribbon arrays on SiO2 dielectrics showing dual signatures of the substrate interaction. First, hybrid polaritonic modes of graphene plasmons and dielectric surface polar phonons…

The structure and chemical composition are the key parameters influencing the properties of organic thin films deposited on inorganic substrates. Such films often display structures that substantially differ from the bulk, and the substrate…

The interaction between graphene and substrates provides a viable routes to enhance functionality of both materials. Depending on the nature of electronic interaction at the interface, the electron band structure of graphene is strongly…

The electron band structure of graphene on SrTiO3 substrate has been investigated as a function of temperature. The high-resolution angle-resolved photoemission study reveals that the spectral width at Fermi energy and the Fermi velocity of…

First-principles calculations of the effect of carbon coverage on the atomic, electronic and magnetic structure of nickel and iron substrates demonstrate insignificant changes in the interatomic distances and magnetic moments on the atoms…

材料科学 · 物理学 2014-12-24 D. W. Boukhvalov , Yu. N. Gornostyrev , M. A. Uimin , A. V. Korolev , A. Ye Yermakov

Graphene has many unique properties that make it an ideal material for fundamental studies as well as for potential applications. Here we review the recent results on the Raman spectroscopy and imaging of graphene. Raman spectroscopy and…

材料科学 · 物理学 2008-10-17 Zhen hua Ni , Ying ying Wang , Ting Yu , Ze xiang Shen
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