相关论文: Topological transitions in evaporating thin films

We study fully three-dimensional droplets that slide down an incline by employing a thin-film equation that accounts for capillarity, wettability, and a lateral driving force in small-gradient (or long-wave) approximation. In particular, we…

We have demonstrated that it is possible to evaporate diradicals in a controlled environment obtaining thin films in which the diradical character is preserved. However, evaporation represents a challenge. The presence of two radical sites…

We study the effects of confinement between two parallel walls on a two dimensional fluid with competing interactions which lead to the formation of particle micro-domains at the thermodynamic equilibrium (microphases or microseparation).…

We investigate the liquid-glass phase transition in a system of point-like particles interacting via a finite-range attractive potential in D-dimensional space. The phase transition is driven by an `entropy crisis' where the available phase…

We present here a simple model describing coexistence of solid and vapour phases. The two phases are separated by an interface. We show that when the concentration of supersaturated vapour reaches the dew-point, the droplet of solid is…

When a suspension dries, the suspending fluid evaporates, leaving behind a dry film composed of the suspended particles. During the final stages of drying, the height of the fluid film on the substrate drops below the particle size,…

The use of ultra-thin, i.e., monolayer films plays an important role for the emerging field of nano-fluidics. Since the dynamics of such films is governed by the interplay between substrate-fluid and fluid-fluid interactions, the transport…

We use transition path sampling to study evaporation in the SPC/E model of liquid water. Based on thousands of evaporation trajectories, we characterize the members of the transition state ensemble (TSE), which exhibit a liquid-vapor…

We study theoretically the evaporation-driven phase separation of a binary fluid mixture in a thin film deposited on a moving substrate, as occurs in meniscus-guided deposition for solution-processed materials. Our focus is on rapid…

The contributions of heat and work in generating a new surface area are considered. Unlike the classical theory of vapor/droplet equilibrium, which associates changing surface areas with work done against the surface tension, an alternative…

A tiny drop of one liquid, suspended within another, may be set into motion aligned with an imposed thermal gradient, as influenced by thermocapillary action stemming from the gradients in interfacial tension due to the local variations in…

A lubrication model can be used to describe the dynamics of a weakly volatile viscous fluid layer on a hydrophobic substrate. Thin layers of the fluid are unstable to perturbations and break up into slowly evolving interacting droplets. A…

We examine transient axial creeping flow in the annular gap between a rigid cylinder and a concentric elastic tube. The gap is initially filled with a thin fluid layer. The study focuses on viscous-elastic time-scales for which the rate of…

We study a system of diffusing-aggregating particles with deposition and evaporation of monomers. By combining theoretical and numerical methods, we establish a clearer understanding of the non-equilibrium phase transition known to occur in…

When placed on rough hydrophobic surfaces, water droplets of diameter larger than a few millimeters can easily form pearls, as they are in the Cassie-Baxter state with air pockets trapped underneath the droplet. Intriguingly, a natural…

Evaporation and condensation at a liquid/vapor interface are ubiquitous interphase mass and energy transfer phenomena that are still not well understood. We have carried out large scale molecular dynamics simulations of Lennard-Jones (LJ)…

Drops on a free-flow/porous-medium-flow interface have a strong influence on the exchange of mass, momentum and energy between the two macroscopic flow regimes. Modeling droplet-related pore-scale processes in a macro-scale context is…

We formulate a well posed interface formulation for canonical one-dimensional evaporation two-phase model problems (the Stefan and Sucking problems) commonly used to validate production codes. We focus on the interface between the vapor and…

Electrohydrodynamic instabilities of fluid-fluid interfaces can be exploited in various microfluidic applications in order to enhance mixing, replicate well-controlled patterns or generate drops of a particular size. In this work, we study…

We present a comprehensive experimental and theoretical investigation of the evaporation dynamics of freely levitated water droplets in an upward airstream under varying temperature and relative humidity conditions, using a custom-designed…