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相关论文: A Computational Investigation of the Catalytic Pro…

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Density functional theory (DFT) can be quite advantageous in advancing the field of catalysis because of the microscopic insights it provides, and thus can guide experimental searches of novel catalysts. Several recent works have…

材料科学 · 物理学 2022-03-24 Vaishali Sharma , Basant Roondhe , Sumit Saxena , Alok Shukla

Based on first principles density functional theory calculations we explore the energetics of the conversion of carbon mono and dioxide to methane over graphene oxide surfaces. Similar to the recently discovered hydration of various organic…

材料科学 · 物理学 2013-07-23 Danil W. Boukhvalov

We study the behavior of hydrated graphite oxide (GO) at high temperatures using thermally accelerated molecular dynamics simulations based on ab initio density functional theory. Our results suggest that GO, a viable candidate for water…

材料科学 · 物理学 2022-03-31 Andrii Kyrylchuk , Pranav Surabhi , David Tománek

The production of multiple types of graphene, such as free standing, epitaxial graphene on silicon carbide and metals, graphene in solution, chemically grown graphene-like molecules, various graphene nanoribbons, and graphene oxide with…

材料科学 · 物理学 2013-01-14 D. W. Boukhvalov

Graphene oxide (GO), the functionalized graphene with oxygenated groups (mainly epoxy and hydroxyl), has attracted resurgent interests in the past decade owing to its large surface area, superior physical and chemical properties, and easy…

材料科学 · 物理学 2020-01-14 Xiaoming Huang , Lizhao Liu , Si Zhou , Jijun Zhao

Graphene oxide is a rising star among 2D materials, yet its interaction with liquid water remains a fundamentally open question: experimental characterization at the atomic scale is difficult, and modelling by classical approaches cannot…

材料科学 · 物理学 2020-03-27 Félix Mouhat , François-Xavier Coudert , Marie-Laure Bocquet

Graphene, a two-dimensional (2D) promising emergent photocatalyst consisting of earth-abundant elements. This study evaluated the potential of graphene oxide (GO) towards photocatalytic degradation of a novel organic dye, Methylene Blue…

Hydrazine stands out as the most generally used chemical-reducing agent for reducing graphene oxide. Despite numerous experimental and theoretical investigations into the reduction reaction, the reduction mechanism remains unclear. In this…

无序系统与神经网络 · 物理学 2023-11-23 Shu Chen , Jianqiang Guo

Previous studies indicate that the properties of graphene oxide (GO) can be significantly improved by enhancing its graphitic domain size through thermal diffusion and clustering of functional groups. Remarkably, this transition takes place…

Hydration properties of graphene oxide (GO) are essential for most of its potential applications. In this work, we employ atomistic molecular dynamics simulations to investigate seven GO compositions with different levels of oxygenation.…

材料科学 · 物理学 2018-02-14 Antenor Neto , Vitaly V. Chaban , Eudes E. Fileti

When it is oxidized, graphite can be easily exfoliated forming graphene oxide (GO). GO is a critical intermediate for massive production of graphene, and it is also an important material with various application potentials. With many…

材料科学 · 物理学 2009-12-31 Wenhua Zhang , Vincenzo Carravetta , Zhenyu Li , Yi Luo , Jinlong Yang

The dynamic covalent properties of graphene oxide (GO) are of fundamental interest to a broad range of scientific areas and technological applications. It remains a challenge to access the feasible dynamic reactions for reversibly…

材料科学 · 物理学 2022-08-24 Zihan Yan , Wenjie Yang , Hao Yang , Chengao Ji , Shuming Zeng , Xiuyun Zhang , Liang Zhao , Yusong Tu

Interfacial adhesion between graphene and a SiO2 substrate is studied by density functional theory (DFT) with dispersion corrections. The results demonstrate the van der Waals (vdW) interaction as the predominate mechanism for the…

材料科学 · 物理学 2015-06-19 Wei Gao , Penghao Xiao , Graeme Henkelman , Kenneth M. Liechti , Rui Huang

Graphene oxide (GO) is one of chemically modified graphenes and has been extensively investigated worldwide. A monolayer sheet of GO can be chemically produced in solution and it has been expected to be adaptable to a wide variety of…

材料科学 · 物理学 2011-02-11 Yoshio Kanamori , Seiji Obata , Koichiro Saiki

The type and distribution of oxygen functional groups in graphene oxide (GO) and reduced graphene oxide (RGO) remain still a subject of great debate. Local analytic techniques are required to access the chemistry of these materials at a…

材料科学 · 物理学 2016-12-13 Anna Tararan , Alberto Zobelli , Ana M. Benito , Wolfgang K. Maser , Odile Stéphan

Oxidation of graphite and subsequent exfoliation leads to single layer graphene oxide (GO). GO has found many applications across diverse fields including medicinal chemistry, catalysis as well as a precursor for graphene. One of the key…

材料科学 · 物理学 2024-09-04 Sownyak Mondal , Soumya Ghosh

Graphene is thought to be a promising materials for many applications. However, pristine graphene is not suitable for most electrochemical devices, where defect engineering is crucial for its performance. We demonstrate how boron doping of…

材料科学 · 物理学 2023-07-07 Milica S. Ritopečki , Natalia V. Skorodumova , Ana S. Dobrota , Igor A. Pašti

We employ molecular dynamic simulations to study the reduction process of graphene-oxide (GO) in a chemically active environment enriched with hydrogen. We examine the concentration and pressure of hydrogen gas as a function of temperature…

材料科学 · 物理学 2016-09-28 Ramin M. Abolfath , Kyeongjae Cho

To explore the potential of molecular gas treatment of freshly cut lithium foils in non-electrolyte based passivation of high energy-density Li anodes, density functional theory (DFT) has been used to study the decomposition of molecular…

材料科学 · 物理学 2015-06-01 Stephan L. Koch , Benjamin J. Morgan , Stefano Passerini , Gilberto Teobaldi

Graphene oxide finds applications in different fields of science, including energy conversion. Electrochemical reduction of graphene oxide (GO) significantly improves its conductivity. However, the kinetics of this process depends on the…

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