相关论文: Is photoisomerization of stilbene in solution dire…
A range of chemical reactions occurring on the surfaces of metal nanoparticles exhibit enhanced rates under plasmonic excitation. Recent analyses based on Arrhenius law fitting have argued in favor of a purely photothermal mechanism of…
The behavior of a particle in a solvent has been framed using stochastic dynamics since the early theory of Kramers. A particle in a chemical reaction reacts slower in a diluted solvent because of the lack of energy transfer via collisions.…
We consider a molecular junction immersed in a solvent where the electron transfer is dominated by Marcus-type steps. However, the successive nature of the charge transfer through the junction does not imply that the solvent reach thermal…
One considers the motion of a test particle in an homogeneous fluid in equilibrium at temperature $T$, undergoing dissipative collisions with the fluid particles. It is shown that the corresponding linear Boltzmann equation still posseses a…
Recently, we have shown that thermal effects play a crucial role in speeding up the rate of bond-dissociation reactions. This was done by applying a simple temperature-shifted Arrhenius Law to the experimental data, corroborated with…
It is shown that thermally excited plasmon-polariton modes can strongly mediate, enhance and \emph{tune} the near-field radiation transfer between two closely separated graphene sheets. The dependence of near-field heat exchange on doping…
Ionic conductivity in solid electrolytes is commonly expected to exhibit Arrhenius dependence on temperature, determined by a well-defined activation energy. Consequently, a standard approach involves calculating this energy using…
The emergent photoactive materials through photochemistry make it possible to directly convert photon energy to mechanical work. There is much recent work in developing appropriate materials and a promising new system is semi-crystalline…
[Abridged] Photoionization, whether by starlight or other sources, has difficulty in accounting for the observed spectra of the optical filaments that often surround central galaxies in large clusters. Our first paper examined whether…
We use large scale molecular dynamics simulations of the isomerizations of azobenzene molecules diluted inside a simple molecular material, to investigate the effect of a modification of the cis isomer shape on the induced diffusion…
Employing a previously derived formulation, and extending the treatment from purely transverse modes to wave vectors having a longitudinal component, we discuss the prospects for the occurrence of Weibel-type color-current filamentation in…
Interpretations of the very rich second solar spectrum of the MgH molecule face serious problems owing to the complete lack of any information about rates of collisions between the MgH and hydrogen atoms. This work seeks to begin the…
This work inspects the thermally activated transfer of solute particles across the interface between two interstitial solid solution phases that equilibrate internally by fast diffusion on conserved arrays of sites. When each phase is…
We study C70 fullerene matter waves in a Talbot-Lau interferometer as a function of their temperature. While the ideal fringe visibility is observed at moderate molecular temperatures, we find a gradual degradation of the interference…
We propose a theoretical approach to quantitatively determine the photothermally driven enhancement of molecular mobility of graphene-indomethacin mixtures under infrared laser irradiation. Graphene plasmons absorb incident electromagnetic…
For a detailed understanding of chemical processes in nature and industry, we need accurate models of chemical reactions in complex environments. While Eyring transition state theory is commonly used for modeling chemical reactions, it is…
The broadening of the hydrogen lines during flares is thought to result from increased charge (electron, proton) density in the flare chromosphere. However, disagreements between theory and modeling prescriptions have precluded an accurate…
Graphene supports strongly confined transverse-magnetic sheet plasmons whose spectral characteristics depend on the energetic distribution of Dirac particles. The question arises whether plasmons can become amplified when graphene is pumped…
Plasmas in an accretion flow are heated by MHD turbulence generated through the magneto-rotational instability. The viscous stress driving the accretion is intimately connected to the microscopic processes of turbulence dissipation. We show…
Context. In dffuse interstellar clouds the excitation temperature derived from the lowest levels of H$^+_3$ is systematically lower than that derived from H2. The differences may be attributed to the lack of state-specific formation and…