相关论文: On The Theory of Time dilation in Chemical Kinetic…
The magnitude of the rate of chemical reactions also depends on the position in the gravitational field, where a chemical reaction is being carried out. At weaker gravitational field rate of reaction is greater than the rate of reaction at…
Classical theories of chemical kinetics assume independent reactions in dilute solutions, whose rates are determined by mean concentrations. In condensed matter, strong interactions alter chemical activities and create inhomogeneities that…
The kinetics of chemical reactions are determined by the law of mass action, which has been successfully applied to homogeneous, dilute mixtures. At non-dilute conditions, interactions among the components can give rise to coexisting…
One of the concepts of Relativity theory that challenges conventional intuition the most is time dilation and length contraction. Usual approaches for describing relativistic effects in quantum systems merely postulate the consequences of…
We study the orbits of two interacting particles described by a fully relativistic classical mechanical Hamiltonian. We use two sets of initial conditions. In the first set (dynamics 1) the system's center of mass is at rest. In the second…
Reaction rate theory in solids is modified taking into account intrinsic localized modes or discrete breathers (DBs) that can appear in crystals with sufficient anharmonicity resulting in violation of Arrhenius law. Large amplitude…
As contrast to the Maxwellian distribution, equilibrium distribution of the second kind or turbulent equilibrium is shown to exist under tertiary molecular chaos hypothesis to replace the classical binary chaos by Boltzmann. It is expressed…
The shortening of bodies in the direction of motion, Lorentz contraction, follows from the solution of Maxwell's equations. Moving light clocks will tick slower than those at rest because the speed of light does not depend on a source of…
The classical theory of chemical reactions can be understood in terms of diffusive barrier crossing, where the rate of a reaction is determined by the inverse of the mean first passage time (FPT) to cross a free energy barrier. Whenever a…
The interplay between electronic interactions and disorder is neglected in the conventional Boltzmann theory of transport, yet can play an essential role in determining the resistivity of unconventional metals. When quasiparticles are…
Although first-order rate constants are basic ingredients of physical chemistry, biochemistry and systems modeling, their innermost nature is derived from complex physical chemistry mechanisms. The present study suggests that equivalent…
The classical approaches to the derivation of the (generalized) Mass Action Law (MAL) assume that the intermediate transition state (i) has short life time and (ii) is in partial equilibrium with the initial reagents of the elementary…
The study of chemical reactions in environments under nonequilibrium conditions has been of interest recently in a variety of contexts, including current-induced reactions in molecular junctions and scanning tunneling microscopy…
In this paper, it is shown why Lorentz Transformation implies the general case where observed events are not necessarily in the inertia frame of any observer but assumes a special scenario when determining the length contraction and time…
The balance equations for thermodynamic quantities are derived from the nonlocal quantum kinetic equation. The nonlocal collisions lead to molecular contributions to the observables and currents. The corresponding correlated part of the…
The classical mass action law in chemical kinetics is put into the context of multiscale thermodynamics.Despite the purely dissipative character of the classical mass action law, inertial effects also play a role in chemical kinetics.…
The dynamics of a radiating charge is one of the oldest unsettled problems in classical physics. The standard Lorentz-Abraham-Dirac (LAD) equation of motion is known to suffer from several pathologies and ambiguities. This paper briefly…
The Lorentz-Dirac radiation reaction formula predicts that the position shift of a charged particle due to the radiation reaction is of first order in acceleration if it undergoes a small acceleration. A semi-classical calculation shows…
The Lorentz-Abraham-Dirac (LAD) equation has proved valuable in describing the motion of radiating electric charges but suffers from runaway, pre-acceleration and other ambiguities. The usual scheme is problematic because of locality, which…
This paper investigates optimal fluctuations for chemical reaction systems with N species, M reactions, and general rate law. In the limit of large volume, large fluctuations for such models occur with overwhelming probability in the…