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Using computer simulations, we identify the mechanisms causing aggregation and structural arrest of colloidal suspensions interacting with a short-ranged attraction at moderate and high densities. Two different non-ergodicity transitions…

凝聚态物理 · 物理学 2009-11-07 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

The stress-induced yielding scenario of colloidal gels is investigated under rough boundary conditions by means of rheometry coupled to local velocity measurements. Under an applied shear stress, the fluidization of gels made of attractive…

软凝聚态物质 · 物理学 2015-02-11 Vincent Grenard , Thibaut Divoux , Nicolas Taberlet , Sébastien Manneville

We use dynamic light scattering and computer simulations to study equilibrium dynamics and dynamic heterogeneity in concentrated suspensions of colloidal hard spheres. Our study covers an unprecedented density range and spans seven decades…

A homogeneous thin polymer film with a stepped height profile levels due to the presence of Laplace pressure gradients. Here we report on studies of polymeric samples with precisely controlled, spatially inhomogeneous molecular weight…

软凝聚态物质 · 物理学 2014-01-07 Joshua D. McGraw , Thomas Salez , Oliver Bäumchen , Elie Raphaël , Kari Dalnoki-Veress

Physically assembled gels have promising applications in many fields because of their tunable mechanical properties. Here, we report the mechanical properties as a function of polymer volume fraction ($\phi$) for a physical gel system…

软凝聚态物质 · 物理学 2020-03-31 Satish Mishra , Rosa Maria Badani Prado , Santanu Kundu

Metastable gels formed by weakly attractive colloidal particles display a distinctive two-stage time-dependent settling behavior under their own weight. Initially a space-spanning network is formed that for a characteristic time, which we…

软凝聚态物质 · 物理学 2015-05-30 Paul Bartlett , Lisa J. Teece , Malcolm A. Faers

The relaxation dynamics of a model fluid of platelike colloidal particles is investigated by means of a phenomenological dynamic density functional theory. The model fluid approximates the particles within the Zwanzig model of restricted…

软凝聚态物质 · 物理学 2011-09-14 Markus Bier , Rene van Roij

We study theoretically the effect of a gravitational field on the equilibrium behaviour of a colloidal suspension of rods with different length-to-width aspect ratios. The bulk phases of the system are described with analytical equations of…

软凝聚态物质 · 物理学 2023-03-10 Tobias Eckert , Matthias Schmidt , Daniel de las Heras

We model the behaviour of a single colloid embedded in a cross-linked polymer gel, immersed in a viscous background fluid. External fields actuate the particle into a periodic motion, which deforms the embedding matrix and creates a local…

软凝聚态物质 · 物理学 2022-11-09 Guido L. A. Kusters , Cornelis Storm , Paul van der Schoot

We present molecular dynamics simulations of aggregation kinetics in a colloidal suspension modeled as a highly asymmetric binary mixture. Starting from a configuration with largely uncorrelated colloidal particles the system relaxes by…

统计力学 · 物理学 2007-05-23 Sorin Bastea

The addition of enough non-adsorbing polymer to an otherwise stable colloidal suspension gives rise to a variety of phase behavior and kinetic arrest due to the depletion attraction induced between the colloids by the polymers. We report a…

软凝聚态物质 · 物理学 2024-06-19 Sam E Griffiths , Nick Koumakis , Aidan T Brown , Teun Vissers , Patrick B Warren , Wilson C K Poon

To study the coexistence of two liquid states of water within one simulation box, we implement an equilibrium sedimentation method--which involves applying a gravitational field to the system and measuring/calculating the resulting density…

软凝聚态物质 · 物理学 2009-11-07 M. Yamada , H. E. Stanley , F. Sciortino

Colloidal gels are widely applied in industry due to their rheological character -- no flow takes place below the yield stress. Such property enables gels to maintain uniform distribution in practical formulations; otherwise, solid…

软凝聚态物质 · 物理学 2023-05-17 Yujie Jiang , Ryohei Seto

Gels are low-packing arrested states of matter which are able to support stress. On cooling, limited valence colloidal particles form open networks stabilized by the progressive increase of the interparticle bond lifetime. These gels, named…

软凝聚态物质 · 物理学 2017-09-11 Francesco Sciortino , Emanuela Zaccarelli

We study crystal nucleation under the influence of sedimentation in a model of colloidal hard spheres via Brownian Dynamics simulations. We introduce two external fields acting on the colloidal fluid: a uniform gravitational field (body…

软凝聚态物质 · 物理学 2013-07-03 John Russo , Anthony C. Maggs , Daniel Bonn , Hajime Tanaka

Recent theories predict that when a supercooled liquid approaches the glass transition, particle clusters with a special "amorphous order" nucleate within the liquid, which lead to static correlations dictating the dramatic slowdown of…

软凝聚态物质 · 物理学 2016-03-04 Bo Zhang , Xiang Cheng

The normal modes and relaxation rates of weak colloidal gels are investigated in computations employing different models of the hydrodynamic interactions between colloids. The eigenspectrum is computed for freely draining,…

流体动力学 · 物理学 2018-01-17 Zsigmond Varga , James W. Swan

Surface tension-driven flow techniques have recently emerged as an efficient means of shedding light into the rheology of thin polymer films. Motivated by experimental and theoretical approaches in films bearing a varying surface…

软凝聚态物质 · 物理学 2017-04-26 Ioannis Tanis , Hendrik Meyer , Thomas Salez , Elie Raphaël , Anthony C. Maggs , Jörg Baschnagel

Attractive colloidal particles can form a disordered elastic solid or gel when quenched into a two-phase region, if the volume fraction is sufficiently large. When the interactions are comparable to thermal energies the stress-bearing…

软凝聚态物质 · 物理学 2014-03-13 Lisa J. Teece , James M. Hart , Kerry Yen Ni Hsu , Stephen Gilligan , Malcolm A. Faers , Paul Bartlett

We consider the dynamic wetting and dewetting processes of films and droplets of complex liquids on planar surfaces, focusing on the case of colloidal suspensions, where the particle interactions can be sufficiently attractive to cause…

流体动力学 · 物理学 2024-11-20 J. Zhang , D. N. Sibley , D. Tseluiko , A. J. Archer