相关论文: Ambipolar transition voltage spectroscopy: analyti…
Transition voltage spectroscopy (TVS) has recently been introduced as a spectroscopic tool for molecular junctions where it offers the possibility to probe molecular level energies at relatively low bias voltages. In this work we perform…
The proposed protocol is an attempt to meet the experimentalists' legitimate desire of reliably and easily extracting microscopic parameters from current-voltage measurements on molecular junctions. It applies to junctions wherein charge…
A theoretical analysis of inelastic electron tunneling spectroscopy (IETS) experiments conducted on molecular junctions are presented, where the second derivative of the current with respect to voltage is usually plotted as a function of…
Transition Voltage Spectroscopy (TVS) has been proposed as a tool to analyze charge transport through molecular junctions. We extend TVS to Au-vacuum-Au junctions and study the distance dependence of the transition voltage V_t(d) for clean…
Molecules of bisthiolterthiophene have been adsorbed on the two facing gold electrodes of a mechanically controllable break junction in order to form metal-molecule(s)-metal junctions. Current-voltage (I-V) characteristics have been…
We assess the performances of the transition voltage spectroscopy (TVS) method to determine the energies of the molecular orbitals involved in the electronic transport though molecular junctions. A large number of various molecular…
Whether at phenomenological or microscopic levels, most theoretical approaches to charge transport through molecular junctions postulate or attempt to justify microscopically the existence of a dominant molecular orbital (MO). Within such…
For the first time a vertically polarized electron beam has been used for physics experiments at MAMI in the energy range between 180 and 855 MeV. The beam-normal single-spin asymmetry $A_{\mathrm{n}}$, which is a direct probe of…
A multi-detector array has been designed and constructed for the simultaneous measurement of energy- and angular correlations of electron-positron pairs. Experimental results are obtained over a wide angular range for high-energy…
In molecular charge transport, transition voltage spectroscopy (TVS) holds the promise that molecular energy levels can be explored at bias voltages lower than required for resonant tunneling. We investigate the theoretical basis of this…
Using non-equilibrium renormalized perturbation theory, we calculate the retarded and lesser self energies, the spectral density rho(omega) near the Fermi energy, and the conductance G through a quantum dot as a function of a small bias…
Asymmetric valences in a binary electrolyte can significantly affect the performance of systems such as reverse electrodialysis cells, batteries, and supercapacitors. To generate a theoretical understanding of this effect, we consider a…
The potential profile across a biased molecular junction is calculated within the framework of a simple Thomas-Fermi type screening model. In particular, the relationship between this profile and the lateral molecular cross section is…
Every now and then one can hear in the molecular electronics community that asymmetric couplings ($\Gamma_{s} \neq \Gamma_{t}$) of the dominant level (molecular orbital) to electrodes ($s$ and $t$) which typically have shapes different of…
Recently, Song et al [Nature 462, 1039 (2009)] employed transition-voltage spectroscopy to demonstrate that the energy $\varepsilon_H$ of the highest occupied molecular orbital (HOMO) of single-molecule transistors can be controlled by a…
Exactly solvable rererence potentials of several smoothly joined Morse-type components were constructed for the lowest two excimer states of Ar2 molecule. The parameters of the potentials have been ascertained by fitting to the experimental…
A complete survey is presented of all half-life and branching-ratio measurements related to the isospin T = 1/2 mirror beta transitions ranging from 3He to 83Mo. No measurements are ignored, although some are rejected for cause. Using the…
We propose the fast semi-analytical method of modelling the polarization curves in the voltammetric experiment. The method is based on usage of the special func- tions and shows a big calculation speed and a high accuracy and stability. Low…
Several studies on the transition voltage ($V_t$) are based on calculations of the tunneling current within the Simmons model. In this paper devoted to vacuum nano-junctions, we compare the Simmons results for $V_t$ with those obtained from…
The predictions for transition form factors $\gamma^*\to \gamma f_2(1270)$ and $\gamma^*\to \gamma a_2(1320)$ and corresponding $e^+e^-\to \gamma^*\to f_2\gamma$ and $e^+e^-\to \gamma^*\to a_2\gamma$ cross sections are obtained for the…