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We investigate the thermopower of single molecules weakly coupled to metallic leads. We model the molecule in terms of the relevant electronic orbitals coupled to phonons corresponding to both internal vibrations and to oscillations of the…

介观与纳米尺度物理 · 物理学 2009-09-29 Jens Koch , Felix von Oppen , Yuval Oreg , Eran Sela

We report a method using scanning tunnelling microscope single molecular break junction to simultaneously measure and correlate the single-molecule thermopower and electrical conductance. In contrast to previously reported approaches, it…

介观与纳米尺度物理 · 物理学 2021-09-24 Joseph M. Hamill , Christopher Weaver , Tim Albrecht

The resonant tunneling model is the simplest model for describing electronic transport through nanoscale objects like individual molecules. A complete understanding includes not only charge transport but also thermal transport and their…

介观与纳米尺度物理 · 物理学 2021-01-25 Matthias A. Popp , André Erpenbeck , Heiko B. Weber

Several models of thermionic energy nanoconverters have been proposed to study the transport phenomena that take place in electronic devices. For example, in resonant tunneling junctions those phenomena are manifested through the…

介观与纳米尺度物理 · 物理学 2020-06-02 G. Valencia-Ortega , L. A. Arias-Hernandez

In this paper we investigate the spin-resolved thermoelectric properties of strongly correlated molecular junctions in the linear response regime. The magnetic molecule is modeled by a single orbital level to which the molecular core spin…

介观与纳米尺度物理 · 物理学 2021-05-25 Anand Manaparambil , Ireneusz Weymann

We study the electrical conductance $G$ and the thermopower $S$ of single-molecule junctions, and reveal signatures of different transport mechanisms: off-resonant tunneling, on-resonant coherent (ballistic) motion, and multi-step hopping.…

介观与纳米尺度物理 · 物理学 2017-04-12 Roman Korol , Michael Kilgour , Dvira Segal

Charge and heat transport through a single molecule tunnel-coupled to external normal electrodes have been studied. The molecule with sufficiently strong interaction between lectrons and vibrational internal degrees of freedom can be…

介观与纳米尺度物理 · 物理学 2012-04-16 Karol Izydor Wysokinski

In this work we study thermoelectric properties of graphene nanoribbons with side-attached organic molecules. By adopting a single-band tight binding Hamiltonian and the Green's function formalism, we calculated the transmission and Seebeck…

介观与纳米尺度物理 · 物理学 2013-06-26 L. Rosales , C. D. Nunez , M. Pacheco , A. Latge , P. A. Orellana

We use the concept of resonant tunneling to calculate the thermopower of molecular nanosystems. It turns out that the sign of the thermovoltage under resonant tunneling conditions depends sensitively on the participating molecular orbital,…

介观与纳米尺度物理 · 物理学 2011-09-05 Vladimir N. Ermakov , Sergei P. Kruchinin , Hyun Taki Kim , Thomas Pruschke

We investigate basic properties of the thermopower (Seebeck coefficient) of phase-coherent conductors under the influence of dephasing and inelastic processes. Transport across the system is caused by a voltage bias or a thermal gradient…

介观与纳米尺度物理 · 物理学 2011-11-17 David Sanchez , Llorens Serra

We study charge and energy transfer in two-site molecular electronic junctions in which electron transport is assisted by a vibrational mode. To understand the role of mode harmonicity/anharmonicity on transport behavior, we consider two…

介观与纳米尺度物理 · 物理学 2015-09-01 Bijay Kumar Agarwalla , Jian-Hua Jiang , Dvira Segal

While thermoelectric transport theory is well established and widely applied, there remains some degree of confusion on the proper thermodynamic definition of the Seebeck coefficient (or thermoelectric power) which is a measure of the…

材料科学 · 物理学 2016-04-05 Y. Apertet , H. Ouerdane , C. Goupil , Ph. Lecoeur

We study the thermopower of a quantum dot weakly coupled to two reservoirs by tunnel junctions. At low temperatures the transport through the dot is suppressed by charging effects (Coulomb blockade). As a result the thermopower shows an…

介观与纳米尺度物理 · 物理学 2009-11-07 M. Turek , K. A. Matveev

We report on the first measurement of the Seebeck coefficient in a tunnel-contacted and gate-tunable individual single-quantum dot junction in the Kondo regime, fabricated using the electromigration technique. This fundamental…

介观与纳米尺度物理 · 物理学 2019-01-31 B. Dutta , D. Majidi , A. Garcia Corral , P. Erdman , S. Florens , T. Costi , H. Courtois , C. B. Winkelmann

We report the first concurrent determination of conductance (G) and thermopower (S) of single-molecule junctions via direct measurement of electrical and thermoelectric currents using a scanning tunneling microscope-based break-junction…

介观与纳米尺度物理 · 物理学 2012-01-10 J. R. Widawsky , P. Darancet , J. B. Neaton , L. Venkataraman

We theoretically study the nonequilibrium thermoelectric transport properties of a strongly-correlated molecule (or quantum dot) embedded in a tunnel junction. Assuming that the coupling of the molecule to the contacts is asymmetric, we…

介观与纳米尺度物理 · 物理学 2023-02-22 Anand Manaparambil , Ireneusz Weymann

The transport properties of a CNT capacitively coupled to a molecule vibrating along one of its librational modes are studied and its transport properties analyzed in the presence of an STM tip. We evaluate the linear charge and thermal…

介观与纳米尺度物理 · 物理学 2013-09-12 F. Remaggi , N. Traverso Ziani , G. Dolcetto , F. Cavaliere , M. Sassetti

Charge and heat transfer through a nanoscale conductor is not only determined by the transmission properties of the electrons, but can also be strongly impacted by coupling to other degrees of freedom in the environment of the conductor.…

介观与纳米尺度物理 · 物理学 2017-10-10 Michael Mecklenburg , Björn Kubala , Joachim Ankerhold

In this work we present a detailed study and derivation of the thermopower and thermoelectric coefficient of nano-granular metals at large tunneling conductance between the grains, g_T>> 1. An important criterion for the performance of a…

介观与纳米尺度物理 · 物理学 2015-05-13 Andreas Glatz , I. S. Beloborodov

We look for manifestations of quantum interference effects in the Seebeck coefficient of a molecular junction, when the electronic conductance exhibits pronounced destructive interference features due to the presence of quasi-degenerate…

介观与纳米尺度物理 · 物理学 2015-06-11 Lena Simine , Wei Jia Chen , Dvira Segal
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