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Using the example of a cobalt dicarbonyl complex it is shown that two perpendicularly polarized IR laser pulses can be used to trigger an excitation of the delocalized CO stretching modes, which corresponds to an alternating localization of…

化学物理 · 物理学 2014-12-05 Mateusz Lisaj , Oliver Kühn

Vibrational-excitation cross sections of ground electronic state of carbon dioxide molecule by electron-impact through the CO2-(2\Pi) shape resonance is considered in the separation of the normal modes approximation. Resonance curves and…

化学物理 · 物理学 2016-11-01 V. Laporta , J. Tennyson , R. Celiberto

Resonant vibrational and rotation-vibration excitation cross sections for electron-CO scattering are calculated in the 0-10 eV energy range for all 81 vibrational states of CO, assuming that the excitation occur via the 2{\Pi} shape…

化学物理 · 物理学 2012-08-14 V. Laporta , C. M. Cassidy , J. Tennyson , R. Celiberto

A moderately intense $450$ fs laser pulse is used to create rotational wave packets in gas phase $\rm{I_2}$ molecules. The ensuing time-dependent alignment, measured by Coulomb explosion imaging with a delayed probe pulse, exhibits the…

Moir\'e patterns are additional, long-range periodicities in twisted crystalline bilayers. They are known to fundamentally change the electronic states of the layers, but similar effects on their mechanical and vibrational properties have…

介观与纳米尺度物理 · 物理学 2021-10-26 Georgy Gordeev , Sören Wasserroth , Han Li , Benjamin Flavel , Stephanie Reich

We separate a Bose-Einstein condensate into an array of 2D sheets using a 1D optical lattice, and then excite quantized vibrational motion in the direction normal to the sheets. Collisions between atoms induce vibrational de-excitation,…

其他凝聚态物理 · 物理学 2012-12-24 I. B. Spielman , P. R. Johnson , J. H. Huckans , C. D. Fertig , S. L. Rolston , W. D. Phillips , J. V. Porto

We investigate the collective excitation spectrum of a quasi-2D Bose-Einstein condensate trapped in a harmonic confinement with nonlinear rotation induced by a density-dependent gauge field. Using a Bogoliubov-de Gennes(BdG) analysis, we…

Non Born-Oppenheimer quantum dynamics of H$_{2}^{+}$ excited by shaped one-cycle laser pulses linearly polarized along the molecular axis have been studied by the numerical solution of the time-dependent Schr\"odinger equation within a…

原子与分子团簇 · 物理学 2017-08-02 Guennaddi K. Paramonov , Oliver Kühn , Andre D. Bandrauk

Electrostatic potentials strongly affect molecular energy levels and charge states, providing the fascinating opportunity of molecular gating. Their influence on molecular vibrations remains less explored. Here, we investigate…

We study the propagation of three-dimensional bipolar ultrashort electromagnetic pulses in an array of semiconductor carbon nanotubes at times much longer than the pulse duration, yet still shorter than the relaxation time in the system.…

Vibrational polaritons are formed by strong coupling of molecular vibrations and photon modes in an optical cavity. Experiments have demonstrated that vibrational strong coupling can change molecular properties and even affect chemical…

量子物理 · 物理学 2025-01-14 Thomas Schnappinger , Cyril Falvo , Markus Kowalewski

We have generated and detected the radial-breathing mode of coherent lattice vibrations in single-walled carbon nanotubes using ultrashort laser pulses. Because the band gap is a function of diameter, these diameter oscillations cause…

介观与纳米尺度物理 · 物理学 2015-06-25 Y. S. Lim , K. J. Yee , J. H. Kim , J. Shaver , E. H. Haroz , J. Kono , S. K. Doorn , R. H. Hauge , R. E. Smalley

Using a focused laser beam we stir a Bose-Einstein condensate confined in a magnetic trap. When the stirring frequency lies near the transverse quadrupolar mode resonance we observe the nucleation of vortices. When several vortices are…

统计力学 · 物理学 2007-05-23 F. Chevy , K. Madison , V. Bretin , J. Dalibard

We develop a fully quantum mechanical methodology to describe the static properties and the dynamics of a single anharmonic vibrational mode interacting with a quantized infrared cavity field in the strong and ultrastrong coupling regimes.…

化学物理 · 物理学 2020-06-22 Johan F. Triana , Federico J. Hernández , Felipe Herrera

We investigate the prospects of creating broad rotational wave packets by means of molecular interaction with long sequences of intense femtosecond pulses. Using state-resolved rotational Raman spectroscopy of oxygen, subject to a sequence…

量子物理 · 物理学 2016-01-27 M. Bitter , V. Milner

The time evolution of anharmonic molecular wave packets is investigated under the influence of the environment consisting of harmonic oscillators. These oscillators represent photon or phonon modes and assumed to be in thermal equilibrium.…

量子物理 · 物理学 2015-06-26 Peter Foldi , Mihaly G. Benedict , Attila Czirjak , Balazs Molnar

We present a theory of vibrational modulation of two-dimensional coherent Fourier transformed electronic spectra. Based on an expansion of the system's energy gap correlation function in terms of Huang-Rhys factors, we explain the…

Numerical simulations of magnetosonic wave formation driven by an expanding cylindrical piston are performed to get better physical insight into the initiation and evolution of large-scale coronal waves. Several very basic initial…

太阳与恒星天体物理 · 物理学 2015-06-15 S. Lulić , B. Vršnak , T. Žic , I. W. Kienreich , N. Muhr , M. Temmer , A. M. Veronig

This is the first in a series of two papers investigating the effect of electron-phonon coupling in two-dimensional Fourier transformed electronic spectroscopy. We present a series of one- and two-dimensional nonlinear spectroscopic…

Motivated by recent observations with Herschel/PACS, and the availability of new rate coefficients for the collisional excitation of CO (Yang et al. 2010), the excitation of warm astrophysical CO is revisited with the use of numerical and…

星系天体物理 · 物理学 2015-06-04 David A. Neufeld
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