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Chemical reactions inside cells are typically subject to the effects both of the cell's confining surfaces and of the viscoelastic behavior of its contents. In this paper, we show how the outcome of one particular reaction of relevance to…

软凝聚态物质 · 物理学 2015-06-04 Pinaki Bhattacharyya , Rati Sharma , Binny J. Cherayil

A theory of diffusion-controlled intramolecular reactions of polymer chain in dilute solution is formulated. Our model is based on the widely used diffusion-reaction formalism of Wilemski and Fixman (J. Chem. Phys. 60, 866 (1974). Our model…

软凝聚态物质 · 物理学 2016-06-02 Aniruddha Chakraborty

We investigate theoretically the end-to-end looping time of a long chain polymer molecule immersed in a solvent. The dynamics of the end-to-end distance is governed by a Smoluchowski-like equation of a particle moving under the influence of…

软凝聚态物质 · 物理学 2018-03-20 Moumita Ganguly , Aniruddha Chakraborty

Hydrodynamic interactions between particles confined in a liquid-filled linear channel are known to be screened beyond a distance comparable to the channel width. Using a simple analytical theory and lattice-Boltzmann simulations, we show…

软凝聚态物质 · 物理学 2010-07-06 Derek Frydel , Haim Diamant

We study thermalization in a one-dimensional quantum system consisting of a noninteracting fermionic chain with each site of the chain coupled to an additional bath site. Using a density matrix renormalization group algorithm we investigate…

统计力学 · 物理学 2013-03-14 N. Sedlmayr , J. Ren , F. Gebhard , J. Sirker

We study the behaviour of a hydrophobic chain near a hydrophobic boundary in two dimensions, using the decorated lattice model of Berkema and Widom [G.T. Barkema and B. Widom, J. Chem. Phys. 113, 2349 (2000)] to obtain effective,…

统计力学 · 物理学 2015-06-24 Pinar Onder , Ayse Erzan

We theoretically investigate the looping dynamics of a linear polymer immersed in a viscoelastic fluid. The dynamics of the chain is governed by a Rouse model with a fractional memory kernel recently proposed by Weber et al. (S. C. Weber,…

软凝聚态物质 · 物理学 2012-07-09 Rajarshi Chakrabarti

The development of a coherent conceptual basis for the treatment of non-linear microscopic phenomena, such as, hydrodynamic interaction, finite extensibility, excluded volume and internal viscosity, in molecular theories of dilute polymer…

统计力学 · 物理学 2021-07-16 J. Ravi Prakash

Connecting short time microscopic dynamics with long time hydrodynamics in strongly correlated quantum systems is one of the outstanding questions. In particular, it is very difficult to determine various hydrodynamic coefficients like the…

统计力学 · 物理学 2020-05-20 Jonathan Wurtz , Anatoli Polkovnikov

The linear viscoelastic response of single semiflexible polymer chains in the infinite-dilution limit is studied using Brownian dynamics simulations of coarse-grained bead-spring chains. The springs obey the FENE-Fraenkel force law, a…

软凝聚态物质 · 物理学 2026-03-03 Amit Varakhedkar , P. Sunthar , J. Ravi Prakash

The dynamics of a heteropolymer chain in solution is studied in the limit of long chain length. Using functional integral representation we derive an effective equation of motion, in which the heterogeneity of the chain manifests itself as…

凝聚态物理 · 物理学 2009-10-28 Jiunn-Ren Roan , E. I. Shakhnovich

The dynamics of loop formation by linear polymer chains has been a topic of several theoretical/experimental studies. Formation of loops and their opening are key processes in many important biological processes. Loop formation in flexible…

软凝聚态物质 · 物理学 2015-05-14 K. P. Santo , K. L. Sebastian

The correlations in the motion of reptating polymers in their melt are investigated by means of kinetic Monte Carlo simulations of the three dimensional slithering snake version of the bond-fluctuation model. Surprisingly, the slithering…

统计力学 · 物理学 2009-11-07 L. Mattioni , J. P. Wittmer , J. Baschnagel , J. -L. Barrat , E. Luijten

Using nonequilibrium computer simulations, we study the response of ferromagnetic nanofilaments, consisting of stabilized onedimensional chains of ferromagnetic nanoparticles, under external rotating magnetic fields. In difference with…

软凝聚态物质 · 物理学 2024-10-07 Pedro A. Sánchez , Antonio Cerrato , Joan J. Cerdà , Carles Bona-Cases , Tomás Sintes , Joan Massó

We present numerical and analytical results describing the effect of hydrodynamic interactions on the dynamics of a short polymer chain in solution. A molecular dynamics algorithm for the polymer is coupled to a direct simulation Monte…

软凝聚态物质 · 物理学 2009-10-31 A. Malevanets , J. M. Yeomans

An approximation to the added mass matrix of an assembly of spheres is constructed on the basis of potential flow theory for situations where one sphere is much larger than the others. In the approximation the flow potential near a small…

流体动力学 · 物理学 2017-03-08 B. U. Felderhof

Using the language of the Flory chi parameter, we develop a theory that unifies the treatment of the single-chain structure and the solution thermodynamics of polymers in poor solvents. The structure of a globule and its melting…

软凝聚态物质 · 物理学 2015-06-19 Rui Wang , Zhen-Gang Wang

Ring, or cyclic, polymers have unique properties compared to linear polymers, due to their topologically closed structure that has no beginning or end. Experimental measurements on molecular ring polymers are challenging due to their…

软凝聚态物质 · 物理学 2023-03-15 Ruben Verweij , Julio Melio , Indrani Chakraborty , Daniela J Kraft

We prove the hydrodynamic limit for a one dimensional harmonic chain with a random flip of the momentum sign. The system is open and subject to two thermostats at the boundaries and to an external tension at one of the endpoints. Under a…

概率论 · 数学 2024-06-10 Tomasz Komorowski , Stefano Olla , Marielle Simon

Generic short-range interacting quantum systems with a conserved quantity exhibit universal diffusive transport at late times. We employ non-equilibrium quantum field theory and semi-classical phase-space simulations to show how this…

量子气体 · 物理学 2020-12-15 Alexander Schuckert , Izabella Lovas , Michael Knap
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