相关论文: Cation vacancy order in the K0.8+xFe1.6-ySe2 syste…
Ga2SeTe2 belongs to a family of materials with large intrinsic vacancy concentrations that are being actively studied due to their potential for diverse applications that include thermoelectrics and phase-change memory. In this article, the…
We measure the pressure dependence of the electrical resistivity and the crystal structure of iron superconductor Sr2VO3FeAs. Below ~10 GPa the structure compresses but remains undeformed, with regular FeAs4 tetrahedrons, and a constant Tc.…
The effects of iron deficiency in FexSe0.5Te0.5 thin films (0.8<x<1) on superconductivity and electronic properties have been studied. A significant enhancement of the superconducting transition temperature (TC) up to 21K was observed in…
Point defects in body-centred cubic Fe, Cr and concentrated random magnetic Fe-Cr are investigated using density functional theory and theory of elasticity. The volume of a substitutional Cr atom in ferromagnetic bcc Fe is approximately…
The study of the iron-based superconductor FeSe has blossomed with the availability of high quality single crystals, obtained through flux/vapor-transport growth techniques below the structural transformation temperature of its tetragonal…
The origin of transition metal vacancies and their effects on the properties of ThCr2Si2-type compounds have been less studied and poorly understood. Here we carefully investigate the structure, physical properties, and electronic structure…
We elucidate the existing controversies in the newly discovered K-doped iron selenide (KxFe2-ySe2-z) superconductors. The stoichiometric KFe2Se2 with \surd2\times\surd2 charge ordering was identified as the parent compound of KxFe2-ySe2-z…
The spinel FeV2O4 is known to exhibit peculiar physical properties, which is generally ascribed to the unusual presence of two cations showing a pronounced interplay between spin, orbital and lattice degrees of freedom (Fe2+ and V3+ on the…
We report the effects of heavy-ion irradiation on FeSe single crystals by irradiating Uranium up to a dose equivalent matching field of $B_\phi$ = 16 T. Almost continuous columnar defects along the $c$-axis with a diameter $\sim$10 nm are…
The search for new superconducting materials has been spurred on by the discovery of iron-based superconductors whose structure and composition is qualitatively different from the cuprates. The study of one such material,…
Boron and Silicon site occupancies of the T2 phase in the Cr-Si-B system were investigated experimentally and by first-principles electronic-structure calculations within the scope of the Density Functional Theory (DFT). A sample with…
Since the discovery of superconductivity at 26 K in oxy-pnictide LaFeAsO1-xFx, enormous interests have been stimulated in the field of condensed matter physics and material sciences. Among the many kind of structures in the iron pnictide…
We analyze magnetic order in iron-chalcogenide Fe$_{1+y}$Te -- the parent compound of high-temperature superconductor Fe$_{1+y}$Te$_{1-x}$Se$_x$. Neutron scattering experiments show that magnetic order in this material contains components…
Frustrated quasidoublets without time-reversal symmetry can host highly unconventional magnetic structures with continuously distributed order parameters even in a single-phase crystal. Here, we report the comprehensive thermodynamic and…
A layer of monodisperse circular steel disks in a nearly square horizontal cell forms, for shear amplitudes SA $\le$ 0.08, hexagonal close-packed crystallites that grow and merge until a single crystal fills the container. Increasing the…
We examine the effect of vacancies on the phase behavior and structure of systems consisting of hard cubes using event-driven molecular dynamics and Monte Carlo simulations. We find a first-order phase transition between a fluid and a…
This article reviews recent experimental investigations on two binary Fe-chalcogenides: FeSe and Fe$_{1+y}$Te. The main focus is on synthesis, single crystal growth, chemical composition, as well as on the effect of excess iron on…
We have carried out a detailed study to investigate the existence of an insulating parent phase for FeSe superconductor. The insulating Fe4Se5 with specific Fe-vacancy order shows a 3D-Mott variable range hopping behavior with a Verwey-like…
Using first-principles density functional theory (DFT), we studied the issue of water incorporation in iron bearing wadsleyite (Mg$_2$SiO$_4$)mineral at transition zone pressures and temperature under varying conditions of vacancy…
If the topological insulator Bi$_{2}$Se$_{3}$ is doped with electrons, superconductivity with $T_{{\rm c}}\approx3-4\:{\rm K}$ emerges for a low density of carriers ($n\approx10^{20}{\rm cm}^{-3}$) and with a small ratio of the…