相关论文: A fundamental requirement for crystal-field parame…
A simple method for constructing effective Hamiltonians for the 4fN and 4fN-15d energy levels of lanthanide ions in crystals from quantum-chemical calculations is presented. The method is demonstrated by deriving crystal-field and…
Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two $C_1$ point-group sites in Er$^{3+}$:Y$_2$SiO$_5$ may be transferred to other ions. The two crystallographic six- and…
For Klein-Gordon fields, it is well known that there exist an infinite number of nonequivalent Fock representations of the canonical commutation relations and, therefore, of inequivalent quantum theories. A context in which this kind of…
The crystal field theory as explained by Abragam and Bleaney in their landmark 1970 book on transition-ion electron paramagnetic resonance remains a cornerstone in the development of luminescence applications and molecular magnets based on…
The specific heat and thermodynamics of ${\rm Fe}_2{\rm P}$ single-crystals around the first order paramagnetic (PM) to ferromagnetic (FM) phase transition at $T_{\rm C} = 217 \,{\rm K}$ are empirically investigated. The magnitude and…
Parametrized crystal-field analyses are presented for both the six and seven fold coordinated, C$_{1}$ symmetry Sm$^{3+}$ centers in Y$_{2}$SiO$_{5}$, based on extensive spectroscopic data spanning the infrared to optical regions. Laser…
Symmetry provides important insight in understanding the nature of phase transitions. In the presence of crystalline symmetries, new phenomena in phase transition can emerge, such as intertwined orders and emergent symmetries. In this work,…
We describe a general method to model multicomponent ordered crystals using the phase-field crystal (PFC) formalism. As a test case, a generic B2 compound is investigated. We are able to produce a line of either first-order or second-order…
The order parameters for the phenomenological description of the smectic-{\it A} to smectic-{\it C} phase transition are formulated on the basis of molecular symmetry and structure. It is shown that, unless the long molecular axis is an…
The photoionization cross section $\sigma$, spin-polarization parameters $P$ and $Q$, and the angular-distribution asymmetry parameter $\beta$ are calculated for the $7s$ state of francium for photon energies below 10 eV. Two distinct…
Analytic expressions for the energy eigenvalues and eigenfunctions of a one-dimensional harmonic crystal are obtained. The average energy and density profiles are obtained numerically as a function of temperature. A surprisingly large…
We review the theory of second--order (ferro--)elastic phase transitions, where the order parameter consists of a certain linear combination of strain tensor components, and the accompanying soft mode is an acoustic phonon. In…
In this paper we give a complete analysis of the phase transitions in the mean-field Blume-Emery-Griffiths lattice-spin model with respect to the canonical ensemble, showing both a second-order, continuous phase transition and a…
In this paper we give a complete analysis of the phase transitions in the mean-field Blume-Emery-Griffiths lattice-spin model with respect to the canonical ensemble, showing both a second-order, continuous phase transition and a…
Computational crystal-field models have provided consistent models of both electronic and Zeeman-hyperfine structure for several rare earth ions. These techniques have not yet been applied to the Zeeman-hyperfine structure of Eu$^{3+}$…
Since a rigorous microscopic treatment of a nematic fluid system based on a pairwise interaction potential is immensely complex we had introduced a simple mean field potential which was a modification of the Maier-Saupe potential in a…
Finite symmetry adaptation techniques are applied to the determination of the intensity strength of two-photon transitions for ions with one partly-filled shell nl in crystalline environments of symmetry G. We treat the case of intra-…
The self-consistent equations for MI phase transition are formulated. We assume two order parameters which describe the phase transition. The first one is the density distribution at MI boundary $\rho (\vec r)$. The second one is a two…
The lattice distortion parameter (the deviation of the c/a ratio from the ideal value 1.633), orientational order parameter, and crystal-field parameter in hexagonal close-packed (hcp) lattice of p-H2, o-D2 and n-H2 are calculated using the…
In this paper, we study phase transitions in asymmetrical fermion superfluids. In this scenario, the candidates to form pair are particles with mismatched masses and chemical potentials. We derive an expression for the critical temperature…