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Small angle X-ray scattering (SAXS) in poly[2-methoxy-5-(2-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV) solution has shown the important role of pi-electron conjugation in controlling the chain conformation and assembly. By increasing…

软凝聚态物质 · 物理学 2015-05-13 Paramita Kar Choudhury , Debjani Bagchi , Reghu Menon

The conformation of polyelectrolytes in the solution state has long been of interest in polymer science. Herein we utilize all atom molecular dynamics simulations (MD) and small-angle x-ray scattering experiments (SAXS) to elucidate the…

We demonstrate in this paper the influence of solvent quality on the structure of the semi-dilute solution of a hydrophobic polyelectrolyte, partially sulfonated Poly-Styrene Sulfonate. Two solvents are used: (i) one mixture of water and an…

软凝聚态物质 · 物理学 2016-11-27 Wafa Essafi , Marie Noelle Spiteri , Claudine Williams , François Boué

The correlation between the transport properties and structural degrees of freedom of conducting polymers is a central concern in both practical applications and scientific research. In this study, we demonstrated the existence of…

A wide variation in the charge transport properties of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS) films is attributed to the degree of phase-segregation of the excess insulating polyanion. The results indicate that…

材料科学 · 物理学 2010-10-06 C. S. Suchand Sangeeth , Manu Jaiswal , Reghu Menon

We study the differences in electrical charge transport dynamics of the conductivity enhancement of poly(3,4-ethylenedioxythiophene) (PEDOT) derivatives under geometrical confinement. The results of polymer blend poly(3,4-ethylene…

材料科学 · 物理学 2022-03-04 Sukanya Das , Anil Kumar , K. S. Narayan

Polysaccharides are semi-flexible polymers composed of sugar residues with a myriad of important functions including structural support, energy storage and immunogenicity. The local conformation of such chains is a crucial factor governing…

软凝聚态物质 · 物理学 2020-01-29 Bradley W. Mansel , Timothy M. Ryan , Hsin-Lung Chen , Leif Lundin , Martin A. K. Williams

"Secondary doping" in poly(3,4-ethylenedioxy-thiophene):poly(styrenesulfonate) (PEDOT:PSS) is quite effective and a frequently used method for the conductivity enhancement. This simple approach, the addition of co-solvents to the PEDOT:PSS…

材料科学 · 物理学 2019-09-23 K. Itoh , Y. Kato , Y. Honma , H. Masunaga , A. Fujiwara , S. Iguchi , T. Sasaki

SAXS studies of four 60 base-pair DNA duplexes with sequences closely related to part of the GAGE6 (G-antigen 6) promoter have been performed to study the role of DNA conformations in solution and their potential relationship to DNA-protein…

We investigated the reversible resistive switching of poly(3,4-ethylenedioxythiophene):polystyrenesulfonate (PEDOT:PSS) thin films sandwiched between Al electrodes. The J-V sweep curve showed a hysteretic behavior which depends on the…

材料科学 · 物理学 2015-05-14 Hu Young Jeong , Jong Yun Kim , Tae Hyun Yoon , Sung-Yool Choi

Poly(3,4-ethylenedioxythiophene) : poly(styrene sulfonic acid (PEDOT:PSS), an optically transparent organic semi-conductor, constitutes a suspension of conducting PEDOT:PSS grains, shelled by an insulating layer of PSS. While a percolation…

材料科学 · 物理学 2013-09-19 A. N. Papathanassiou , I. Sakellis , J. Grammatikakis , E. Vitoratos , S. Sakkopoulos

Lithium--sulfur (Li/S) batteries are regarded as one of the most promising energy storage devices beyond lithium-ion batteries because of their high energy density of 2600 Wh/kg and an affordable cost of sulfur. Meanwhile, some challenges…

We study the dynamics of polymer chains in a bath of self-propelled particles (SPP) by extensive Langevin dynamics simulations in a two dimensional system. Specifically, we analyse the polymer looping properties versus the SPP activity and…

软凝聚态物质 · 物理学 2016-09-26 J. Shin , A. G. Cherstvy , W. K. Kim , R. Metzler

Composite materials based on Poly(3,4-ethylenedioxythiophene) (PEDOT) and CoFe$_2$O$_4$ magnetic nanoparticles (NP) were synthesized by chemical oxidative polymerization with varying monomer and surfactant (DBSA) concentrations, and were…

材料科学 · 物理学 2025-07-11 Gabriel Paciaroni , María Ana Castro , Carlos Acha , Paula Soledad Antonel

We report observations of a remarkable scaling behavior with respect to concentration in the passive microbead rheology of two highly entangled polymeric solutions, polyethylene oxide (PEO) and hyaluronic acid (HA). This behavior was…

软凝聚态物质 · 物理学 2018-10-17 Ian Seim , Jeremy A. Cribb , Jay M. Newby , Paula Vasquez , Martin Lysy , M. Gregory Forest , David B. Hill

The structure and dynamics of a range of polystyrene sulphonate comb polyelectrolytes with well defined chain architectures were examined with static light scattering, dynamic light scattering, small angle neutron/X-ray scattering, particle…

软凝聚态物质 · 物理学 2007-05-23 A. Papagiannopoulos , T. A. Waigh , C. Fernyhough , T. Hardingham , M. Heinrich

Synthetic polymers have a distribution of chain lengths which can be characterized by dispersity, D. Macroscopic properties of polymers are influenced by chain mobility in the melt and manipulating D can significantly impact these…

化学物理 · 物理学 2024-09-30 Taofeek Tejuosho , Sohil Kollipara , Sumant Patankar , Janani Sampath

The nanoscale fluctuation dynamics of semi dilute high molecular weight polymer solutions of Polyethylenoxide (PEO) in D2O under non-equilibrium flow conditions were studied by the neutron spin-echo technique. The sample cell was in…

流体动力学 · 物理学 2011-06-16 Maikel C. Rheinstadter , Rainer Sattler , Wolfgang Haeussler , Christian Wagner

Binding and phase behavior of oppositely charged polyelectrolytes and surfactants were studied in aqueous bulk solutions and at air-water interfaces. In particular, we have investigated the polyanion poly(sodium 4-styrenesulfonate) (NaPSS)…

软凝聚态物质 · 物理学 2020-07-16 Felix Schulze-Zachau , Björn Braunschweig

We discuss phase coexistence of polydisperse colloidal suspensions in the presence of adhesion forces. The combined effect of polydispersity and Baxter's sticky-hard-sphere (SHS) potential, describing hard spheres interacting via strong and…

统计力学 · 物理学 2009-11-11 Domenico Gazzillo , Achille Giacometti , Riccardo Fantoni
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