相关论文: Configurational Prigogine-Defay ratio
We propose a statistical mechanical framework to unify the observed relationship between the superconducting energy gap $\Delta$, the pseudogap $\Delta^\ast$, and the critical temperature $T_\mathrm{c}$. In this model, fermions couple as a…
We use large-scale molecular dynamics simulations to study the kinetics of the liquid-gas phase separation if the temperature is lowered across the glass transition of the dense phase. We observe a gradual change from phase separated…
The high-frequency shear modulus of five Zr-, Pd-, Cu-based conventional and two high-entropy bulk metallic glasses was measured in a wide temperature range up to the beginning of crystallization. Using these data and general thermodynamic…
We determine the nature of the QCD transition using lattice calculations for physical quark masses. Susceptibilities are extrapolated to vanishing lattice spacing for three physical volumes, the smallest and largest of which differ by a…
In the holographic AdS/QCD approach, the confinement/deconfinement transition is associated with the Hawking-Page transition of a thermal anti-de Sitter (AdS) space to an AdS black hole. In the case of the hard wall model, the thermal…
Due to nonuniform aggregation in liquid state, from the thermodynamic point of view any glass-forming liquid in the vicinity of the liquid-to-solid phase transition temperature, irrespective of its actual chemical composition, shall be…
Building on the recently derived inhomogeneous mode-coupling theory, we extend the generalised mode-coupling theory of supercooled liquids to inhomogeneous environments. This provides a first-principles-based, systematic and rigorous way of…
Generation of equilibrium configurations is the major obstacle for numerical investigation of the slow dynamics in supercooled liquid states. The parallel tempering (PT) technique, originally proposed for the numerical equilibration of…
This perspective article reviews arguments that glass-forming liquids are different from those of standard liquid-state theory, which typically have a viscosity in the mPa$\cdot$s range and relaxation times of order picoseconds. These…
We employ an Einstein-Maxwell-Dilaton (EMD) holographic model, which is known to be in good agreement with lattice results for the QCD equation of state with $(2+1)$ flavors and physical quark masses, to investigate the temperature and…
Glasses are out-of-equilibrium systems aging under the crystallization threat. During ordinary glass formation, the atomic diffusion slows down rendering its experimental investigation impractically long, to the extent that a timescale…
The problem of measuring nontrivial static correlations in deeply supercooled liquids made recently some progress thanks to the introduction of amorphous boundary conditions, in which a set of free particles is subject to the effect of a…
The specific heat Cp and other properties of glasses (ranging from amorphous solids to disordered crystals) at low temperatures, are well known to be markedly different from those in fully-ordered crystals. For decades, this qualitative,…
The ways of portrayal of the pressure evolution of the glass temperature (Tg) beyond the dominated Simon-Glatzel-like pattern are discussed. This includes the possible common description of Tg(P) dependences in systems described by dtg/dP>0…
A constraint-modulated rate law for viscosity in glass-forming liquids is reported. The key assumption is that each configurational state is resolved independently under its current structural constraints, rather than as a point on a…
In this report we present the first ever results of strong pretransitional effect observed for the maximum of absorption peak $${\epsilon}_{max}^{''}(T)$$ in supercooled liquid-crystalline systems near the glass transition temperature. This…
We study the equilibrium thermodynamics of quantum hard spheres in the infinite-dimensional limit, determining the boundary between liquid and glass phases in the temperature-density plane by means of the Franz-Parisi potential. We find…
By the adoption of a quaternion orientational order parameter to describe solidification, the topological origins of the thermal transport properties of crystalline and non-crystalline solid states are considered herein. Global…
Dynamical quantities such as the diffusion coefficient and relaxation times for some glass-formers may depend on density and temperature through a specific combination, rather than independently, allowing the representation of data over…
The most puzzling aspect of the glass transition observed in laboratory is an apparent decoupling of dynamics from structure. In this paper we recount the implication of various theories of glass transition for the static correlation length…