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Methods for estimating the correlation energy of molecules and other electronic systems are discussed based on the assumption that the correlation energy can be partitioned between atomic regions. In one method, the electron density is…

化学物理 · 物理学 2022-05-16 Jerry L. Whitten

The electronic structures of element cerium under high pressure remain unclear all the time. We tried to calculate the electronic structures of $\alpha'$, $\alpha"$, and $\epsilon$-Ce which only exist in the presence of pressure, by using…

强关联电子 · 物理学 2018-11-02 Haiyan Lu , Li Huang

In electronic structure calculations, the correlation energy is defined as the difference between the mean field and the exact solution of the non relativistic Schr\"odinger equation. Such an error in the different calculations is not…

量子物理 · 物理学 2022-04-04 Kumar J. B. Ghosh , Sabre Kais , Dudley R. Herschbach

We study the properties of the lower bound on the exchange-correlation energy in two dimensions. First we review the derivation of the bound and show how it can be written in a simple density-functional form. This form allows an explicit…

强关联电子 · 物理学 2010-02-25 E. Rasanen , S. Pittalis , C. R. Proetto , K. Capelle

The analysis of correlation energy of the simplest first approximation of a variational method for the intrashell states of two-electron atoms is the purpose of the present work. This method allows to divide energy of atom on Coulomb and…

原子物理 · 物理学 2008-10-23 V. V. Kavera

We consider density functionals for exchange and correlation energies in two-dimensional systems. The functionals are constructed by making use of exact constraints for the angular averages of the corresponding exchange and correlation…

强关联电子 · 物理学 2010-02-25 E. Rasanen , S. Pittalis

The capability of density-functional theory to deal with the ground-state of strongly correlated low-dimensional systems, such as semiconductor quantum dots, depends on the accuracy of functionals developed for the exchange and correlation…

强关联电子 · 物理学 2009-02-25 S. Pittalis , E. Rasanen , C. Proetto , E. K. U. Gross

We discuss alternative homogeneous electron gas systems in which a finite number $n$ of electrons are confined to a $D$-dimensional sphere. We derive the first few terms of the high-density ($r_s\to0$, where $r_s$ is the Seitz radius)…

化学物理 · 物理学 2011-12-09 Pierre-François Loos , Peter M. W. Gill

In electronic devices where a two-dimensional electron gas (2DEG) comprises one or both sides of a plane capacitor, the resulting capacitance $C$ can be larger than the "geometric capacitance" $C_g$ determined by the physical separation $d$…

介观与纳米尺度物理 · 物理学 2012-07-06 Brian Skinner , B. I. Shklovskii

We present analytical solutions to a quantum-mechanical three-body problem in three dimensions, which describes a helium-like two-electron atom. Similarly to Hooke's atom, the Coulombic electron-nucleus interaction potentials are replaced…

量子物理 · 物理学 2017-02-15 C. A. Downing

We compute the ground state energy of atoms and quantum dots with a large number N of electrons. Both systems are described by a non-relativistic Hamiltonian of electrons in a d-dimensional space. The electrons interact via the Coulomb…

量子物理 · 物理学 2015-05-14 Hervé Kunz , Rico Rueedi

The non-relativistic interacting electron gas in an external field of positively charged massive cores is dealt with in the scheme of second quantization. Ladder operators that change between stationary states of contiguous energy…

量子物理 · 物理学 2025-02-27 Miguel Lagos

The variational and diffusion quantum Monte Carlo methods are used to calculate the correlation energy of the paramagnetic three-dimensional homogeneous electron gas at intermediate to high density. Ground state energies in finite cells are…

强关联电子 · 物理学 2023-03-29 Sam Azadi , N. D. Drummond , S. M. Vinko

We consider electrostatic interactions in two classes of nanostructures embedded in a three dimensional space: (1) helical nanotubes, and (2) thin films with uniform bending (i.e., constant mean curvature). Starting from the atomic scale…

介观与纳米尺度物理 · 物理学 2023-04-11 Prashant K. Jha , Timothy Breitzman , Kaushik Dayal

We investigate the effects of electron correlations on the ground state energy and the chemical potential of a droplet confined by a parabolic potential at high magnetic fields. We demonstrate the importance of correlations in estimating…

凝聚态物理 · 物理学 2009-10-28 Kang-Hun Ahn , J. H. Oh , K. J. Chang

Two electrons move in a quasi one--dimensional wire under the influence of a short--range interaction. We restrict Hilbert space to those states where the two electrons are close to each other. Using supersymmetry, we present a complete…

无序系统与神经网络 · 物理学 2009-11-07 Jean Richert , Hans A. Weidenmueller

Fully relativistic approach to evaluate the correlation effects in highly charged ions is presented. The interelectronic-interaction contributions of first and second orders in $1/Z$ are treated rigorously within the framework of…

原子物理 · 物理学 2019-12-18 Y. S. Kozhedub , A. V. Malyshev , D. A. Glazov , V. M. Shabaev , I. I. Tupitsyn

The ground state energy of the two--dimensional uniform electron gas has been calculated with fixed--node diffusion Monte Carlo, including backflow correlations, for a wide range of electron densities as a function of spin polarization. We…

强关联电子 · 物理学 2009-11-07 Claudio Attaccalite , Saverio Moroni , Paola Gori-Giorgi , Giovanni B. Bachelet

Electron density and electron momentum density, while independently tractable experimentally, bear no direct connection without going through the many-electron wave function. However, invoking a variant of the constrained-search formulation…

原子物理 · 物理学 2009-11-11 M. K. Harbola , Rajendra R. Zope , Anjali Kshirsagar , Rajeev K. Pathak

Three-dimensional (3D) simulations of electron beams propagating in high energy density (HED) plasmas using the quasi-static Particle-in-Cell (PIC) code QuickPIC demonstrate a significant increase in stopping power when beam electrons…

等离子体物理 · 物理学 2021-09-15 Ian N. Ellis , David J. Strozzi , Warren B. Mori , Fei Li , Frank R. Graziani