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The electric double layer is an important structure that appears at charged liquid interfaces, and it determines the performance of various electrochemical devices such as supercapacitors and electrokinetic energy converters. Here the…

软凝聚态物质 · 物理学 2023-08-15 Haruto Iwasaki , Yasuyuki Kimura , Yuki Uematsu

The Bragg-Williams free energy is used to incorporate nearest-neighbor interactions into the lattice gas model of a solvent-free ionic liquid near a planar electrode. We calculate the differential capacitance from solutions of the…

化学物理 · 物理学 2018-12-04 Rachel Downing , Bjorn K. Berntson , Guilherme V. Bossa , Sylvio May

We present a study of the structure and differential capacitance of electric double layers of aqueous electrolytes. We consider Electric Double Layer Capacitors (EDLC) composed of spherical cations and anions in a dielectric continuum…

软凝聚态物质 · 物理学 2021-07-21 Peter Cats , Ranisha S. Sitlapersad , Wouter K. den Otter , Anthony R. Thornton , René van Roij

Understanding the interfacial electrical properties between metallic electrodes and low dimensional semiconductors is essential for both fundamental science and practical applications. Here we report the observation of thickness reduction…

介观与纳米尺度物理 · 物理学 2015-02-17 Song-Lin Li , K. Komatsu , Shu Nakaharai , Yen-Fu Lin , M. Yamamoto , X. F. Duan , K. Tsukagoshi

We study the ground-state properties of a double layer graphene system with the Coulomb interlayer electron-electron interaction modeled within the random phase approximation. We first obtain an expression of the quantum capacitance of a…

材料科学 · 物理学 2017-09-06 Fariborz Parhizgar , Alireza Qaiumzadeh , Reza Asgari

Surfaces of metal oxides at working conditions are usually electrified due to the acid-base chemistry. The charged interface compensated with counterions forms the so-called electric double layer. The coupling of surface chemistry and…

软凝聚态物质 · 物理学 2019-07-02 Chao Zhang , Jürg Hutter , Michiel Sprik

Metal-oxide surfaces act as both Br{\o}nsted acids and bases, which allows the exchange of protons with the electrolyte solution and generates either positive or negative proton charges depending on the environmental pH. These interfacial…

化学物理 · 物理学 2024-08-13 Lisanne Knijff , Mei Jia , Chao Zhang

This article is present the effected oxide capacitor in CMOS structure of integrated circuit level 5 micrometer technology. It has designed and basic structure of MOS diode. It establish with aluminum metallization layer by sputtering…

其他计算机科学 · 计算机科学 2009-12-22 S. Rodthong , B. Burapattanasiri

One prominent structural feature of ionic liquids near surfaces is formation of alternating layers of anions and cations. However, how this layering responds to applied potential is poorly understood. We focus on the structure of…

Triggered by the revival of multiferroic materials, a lot of effort is presently undergoing as to find a coupling between a capacitance and a magnetic field. We show in this report that interfaces are the right way of increasing such a…

材料科学 · 物理学 2009-11-13 Mario Maglione

Progress in electrochemical applications of ionic liquids builds on an understanding of electrical double-layer. This computational study focuses on structure-determined quantities -- maximum packing density, potentials and capacitances --…

A new type of a capacitor with a very high volumetric capacitance is proposed. It is based upon the known phenomenon of a sharp increase of the dielectric constant of the metal-insulator composite in the vicinity of the percolation…

介观与纳米尺度物理 · 物理学 2015-05-27 A. L. Efros

We study the electrode polarization behaviour of different Na-Ca-phosphosilicate glasses by measuring the differential capacitance between blocking Pt electrodes. At low applied dc bias voltages, we detect a linear capacitance regime with…

无序系统与神经网络 · 物理学 2009-11-11 C. R. Mariappan , T. P. Heins , B. Roling

The results for the electrical double layer capacitance and the charge density of ``free ions'' obtained from the mesoscopic theory are compared with the corresponding results of the associative mean spherical approximation. While the first…

统计力学 · 物理学 2026-02-27 O. Patsahan

In electronic devices where a two-dimensional electron gas (2DEG) comprises one or both sides of a plane capacitor, the resulting capacitance $C$ can be larger than the "geometric capacitance" $C_g$ determined by the physical separation $d$…

介观与纳米尺度物理 · 物理学 2012-07-06 Brian Skinner , B. I. Shklovskii

Ionic liquids (ILs) are appealing electrolytes for their favorable physicochemical properties. However, despite their longstanding use, understanding the capacitive behavior of ILs remains challenging. This is largely due to the formation…

软凝聚态物质 · 物理学 2024-01-02 YeongKyu Lee , JunBeom Cho , Yongkyu Lee , Won Bo Lee , YongSeok Jho

If a clean two-dimensional electron gas (2DEG) with small concentration $n$ comprises one (or both) electrodes of a plane capacitor, the resulting capacitance $C$ can be larger than the "geometric capacitance" $C_g$ determined by the…

介观与纳米尺度物理 · 物理学 2013-01-15 Brian Skinner , B. I. Shklovskii

In this review, we shortly summarize the basic theoretical milestones achieved in the mean-field theory of room temperature ionic liquids (RTILs) on charged electrodes since the publication of Kornyshev's seminal paper in 2007. We pay…

软凝聚态物质 · 物理学 2021-12-28 Yury A. Budkov , Andrei L. Kolesnikov

Electrolyte gating using ionic liquid electrolytes has recently generated considerable interest as a method to achieve large carrier density modulations in a variety of materials. In noble metal thin films, electrolyte gating results in…

材料科学 · 物理学 2016-03-29 Trevor A Petach , Menyoung Lee , Ryan Davis , Apurva Mehta , David Goldhaber-Gordon

Electrochemistry experiments have established that the capacitance of electrode-electrolyte interfaces is much larger for good metals such as gold and platinum than for carbon-based materials. Despite the development of elaborate electrode…

材料科学 · 物理学 2021-09-03 Alessandra Serva , Laura Scalfi , Benjamin Rotenberg , Mathieu Salanne