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In this review we highlight recent theoretical and experimental work on sublattice asymmetric doping of impurities in graphene, with a focus on substitutional Nitrogen dopants. It is well known that one current limitation of graphene in…

介观与纳米尺度物理 · 物理学 2014-11-13 James A. Lawlor , Mauro S. Ferreira

Graphene has vast promising applications on the nanoelectronics and spintronics because of its unique magnetic and electronic properties. Making use of an ab initio spin-polarized density functional theory, implemented by the method of…

材料科学 · 物理学 2016-11-26 Zongguo Wang , Shaojing Qin , Chuilin Wang

Recent experimental findings and theoretical predictions suggest that nitrogen-doped CVD-grown graphene may give rise to electronic band gaps due to impurity distributions which favour segregation on a single sublattice. Here we demonstrate…

介观与纳米尺度物理 · 物理学 2016-02-09 Thomas Aktor , Antti-Pekka Jauho , Stephen R. Power

Among the different strategies used to induce the opening of a band gap in graphene, one common practice is through chemical doping. While a gap may me opened in this way, disorder-induced scattering is an unwanted side-effect that impacts…

介观与纳米尺度物理 · 物理学 2016-06-22 James A Lawlor , Claudia G Rocha , Vanessa Torres , Andrea Latgé , Mauro Ferreira

We propose a class of graphene nanoribbons showing strong intrinsic ferromagnetic behavior due to their asymmetry. Such ribbons are based on a zig-zag edged backbone surmounted by a periodic, triangular notched region of variable size. The…

Penta-graphene is a quasi-two-dimensional carbon allotrope consisting of a pentagonal lattice in which both sp2 and sp3-like carbons are present. Unlike graphene, penta-graphene exhibits a non-zero bandgap, which opens the possibility of…

The electronic and magnetic properties of zigzag graphene nanoribbons with asymmetric notches along their edges are investigated by first principle density functional theory calculations. It is found that the electronic and magnetic…

介观与纳米尺度物理 · 物理学 2015-08-14 Guang-Yao Song , Qing-Hong Yuan , Wen-Xin Hu , De-Yan Sun

Magnetic impurities adsorbed on graphene are coupled magnetically via the itinerant electrons. This interaction opens a gap in the band structure of graphene. The result strongly depends on how the magnetic impurities are distributed. While…

强关联电子 · 物理学 2010-10-05 Maria Daghofer , Nan Zheng , Adriana Moreo

Graphene nanoribbons are the counterpart of carbon nanotubes in graphene-based nanoelectronics. We investigate the electronic properties of chemically modified ribbons by means of density functional theory. We observe that chemical…

材料科学 · 物理学 2009-09-29 F. Cervantes-Sodi , G. Csányi , S. Piscanec , A. C. Ferrari

In contrast to the well recognized transverse-electric-field-induced half-metallicity in zigzag graphene nanoribbons, here we demonstrate by first-principles calculations that zigzag graphene nanoribbons sandwiched between hexagonal boron…

介观与纳米尺度物理 · 物理学 2013-04-15 Jin Yu , Wanlin Guo

It is known that there is a wide class of quasi-two-dimensional graphenelike nanomaterials which in many respects can outperform graphene. So, here in addition to graphene, the attention is directed to stanene (buckled honeycomb structure)…

介观与纳米尺度物理 · 物理学 2019-10-02 S. Krompiewski

The Dirac electrons of graphene, an intrinsic zero gap semiconductor, uniquely carry spin and pseudospin that give rise to many fascinating electronic and transport properties. While isolated zigzag graphene nanoribbons are…

材料科学 · 物理学 2016-07-22 M. X. Chen , M. Weinert

We investigate spin transport in diffusive graphene nanoribbons with both clean and rough zigzag edges, and long-range potential fluctuations. The long-range fields along the ribbon edges cause the local doping to come close to the charge…

介观与纳米尺度物理 · 物理学 2014-03-31 Jan Bundesmann , Ming-Hao Liu , Inanc Adagideli , Klaus Richter

We report on the possibility for a spin valve effect driven by edge defect engineering of zigzag graphene nanoribbons. Based on a mean-field spin unrestricted Hubbard model, electronic band structures and conductance profiles are derived,…

介观与纳米尺度物理 · 物理学 2015-05-14 Sankaran Lakshmi , Stephan Roche , Gianaurelio Cuniberti

We investigate the effect of edge defects (vacancies) and impurities (substitutional dopants) on the robustness of spin-polarization in graphene nanoribbons (GNRs) with zigzag edges, using density-functional-theory calculations. We found…

材料科学 · 物理学 2009-11-13 Bing Huang , Feng Liu , Jian Wu , Bing-Lin Gu , Wenhui Duan

Hydrogenated graphene, graphane, is studied on oxygen-terminated silicon dioxide substrate using ab initio calculations. A structure with hydrogenation only on one side of the graphene layer is found stable and its hydrogen configurations…

介观与纳米尺度物理 · 物理学 2011-07-13 M. Ijäs , P. Havu , A. Harju , P. Pasanen

Motivated by the recently observed sublattice asymmetry of substitutional nitrogen impurities in CVD grown graphene, we show, in a mathematically transparent manner, that oscillations in the local density of states driven by the presence of…

介观与纳米尺度物理 · 物理学 2014-11-13 James A. Lawlor , Paul D. Gorman , Stephen R. Power , Claudionor G. Bezerra , Mauro S. Ferreira

Two magnetic impurities on the edge of a zigzag graphene nanoribbon strongly interact with each other via indirect coupling, which can be mediated by conducting carriers. By means of Quantum Monte Carlo (QMC) simulations, we find that the…

强关联电子 · 物理学 2015-03-09 F. M. Hu , Liangzhi Kou , Thomas Frauenheim

Electrical current can be completely spin polarized in a class of materials known as half-metals, as a result of the coexistence of metallic nature for electrons with one spin orientation and insulating for electrons with the other. Such…

介观与纳米尺度物理 · 物理学 2009-11-11 Young-Woo Son , Marvin L. Cohen , Steven G. Louie

Realizing magnetism in graphene/carbon nanostructures is a decade-long challenge. The magnetic edge state and half metallicity in zigzag graphene nanoribbons are particularly promising [Y.-W. Son, et al., Nature 444, 347 (2006)]. However,…

介观与纳米尺度物理 · 物理学 2018-12-05 Shiyuan Gao , Li Yang
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