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We propose a hybrid approach which employs the dynamical mean-field theory (DMFT) self-energy for the correlated, typically rather localized orbitals and a conventional density functional theory (DFT) exchange-correlation potential for the…

强关联电子 · 物理学 2021-06-16 Sumanta Bhandary , Karsten Held

Ensemble Density Functional Theory (EDFT) is a generalization of ground-state Density Functional Theory (GS DFT), which is based on an exact formal theory of finite collections of a system's ground and excited states. EDFT in various forms…

材料科学 · 物理学 2024-08-27 Remi J. Leano , Aurora Pribram-Jones , David A. Strubbe

We study spectra of Schr\"odinger operators on $\RR^d$. First we consider a pair of operators which differ by a compactly supported potential, as well as the corresponding semigroups. We prove almost exponential decay of the singular values…

数学物理 · 物理学 2016-01-07 Dirk Hundertmark , Rowan Killip , Shu Nakamura , Peter Stollmann , Ivan Veselic'

A uniform derivation is presented of the self-consistent field equations in a finite basis set. Both restricted and unrestricted Hartree-Fock (HF) theory as well as various density functional (DF) approximations are considered. The unitary…

计算物理 · 物理学 2020-03-10 Susi Lehtola , Frank Blockhuys , Christian Van Alsenoy

Expansion of a wave function in a basis of eigenfunctions of a differential eigenvalue problem lies at the heart of the R-matrix methods for both the Schr\"odinger and Dirac particles. A central issue that should be carefully analyzed when…

原子物理 · 物理学 2012-04-23 Julia Stasińska

In this chapter, we describe three related studies of the universal physics of two-component unitary Fermi gases with resonant short-ranged interactions. First we discuss an ab initio auxiliary field quantum Monte Carlo technique for…

量子气体 · 物理学 2012-03-21 Aurel Bulgac , Michael McNeil Forbes , Piotr Magierski

We consider one-dimensional random Schr\"odinger operators with a background potential, arising in the inverse problem of scattering. We study the influence of the background potential on the essential spectrum of the random Schr\"odinger…

数学物理 · 物理学 2017-12-22 Hayk Asatryan , Werner Kirsch

Over the last few decades, classical density-functional theory (DFT) and its dynamic extensions (DDFTs) have become powerful tools in the study of colloidal fluids. Recently, previous DDFTs for spherically-symmetric particles have been…

统计力学 · 物理学 2016-08-02 Miguel A. Durán-Olivencia , Benjamin D. Goddard , Serafim Kalliadasis

The scattering matrix of the Schrodinger operator with smooth short-range electric and magnetic potentials is considered. The asymptotic density of the eigenvalues of this scattering matrix in the high energy regime is determined. An…

谱理论 · 数学 2012-08-22 Daniel Bulger , Alexander Pushnitski

The Hohenberg-Kohn theorem and Kohn-Sham procedure are extended to functionals of the localized intrinsic density of a self-bound system such as a nucleus. After defining the intrinsic-density functional, we modify the usual Kohn-Sham…

核理论 · 物理学 2008-11-26 J. Engel

Electrons in zero external magnetic field can be studied with density functional theory (DFT) or with spin-DFT (SDFT). The latter is normally used for open shell systems because its approximations appear to model better the exchange and…

化学物理 · 物理学 2022-04-06 Timothy Callow , Benjamin Pearce , Nikitas Gidopoulos

Density functional theory (DFT), one of the most widely utilized methods available to computational chemistry, fails to describe systems with statically correlated electrons. To address this shortcoming, in previous work we transformed DFT…

化学物理 · 物理学 2023-01-02 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

Schr\"odinger operators often display singularities at the origin, the Coulomb problem in atomic physics or the various matter coupling terms in the Friedmann-Robertson-Walker problem being prominent examples. For various applications it…

量子物理 · 物理学 2023-05-12 Thomas Thiemann

This paper is concerned with the connection between density matrix method, supersymmetric quantum mechanics and Lewis-Riesenfeld invariant theory. It is shown that these three formulations share the common mathematical structure:…

量子物理 · 物理学 2007-05-23 Jian Qi Shen

In this work we explore the performance of approximations to electron correlation in reduced density-matrix functional theory (RDMFT) and of approximations to the observables calculated within this theory. Our analysis focuses on the…

强关联电子 · 物理学 2015-02-26 Stefano Di Sabatino , Jan A. Berger , Lucia Reining , Pina Romaniello

We study generalizations of the Schr\"odinger problem in statistical mechanics in two directions: when the density is constrained at more than two times, and when the joint law of the initial and final positions for the particles is…

概率论 · 数学 2020-01-30 Aymeric Baradat , Christian Léonard

The implementation of an efficient self-consistent field (SCF) method including both scalar relativistic effects and spin-orbit interaction in density functional theory (DFT) is presented. We make use of Gaussian-type orbitals (GTOs) and…

化学物理 · 物理学 2024-05-03 Yannick J. Franzke , Werner M. Schosser , Fabian Pauly

The object of the present study is the integrated density of states of a quantum particle in multi-dimensional Euclidean space which is characterized by a Schr{\"o}dinger operator with magnetic field and a random potential which may be…

数学物理 · 物理学 2009-11-07 Thomas Hupfer , Hajo Leschke , Peter Müller , Simone Warzel

We consider a natural class of extensions of the Anderson model on $\mathbb Z^d$, called random block Schr\"odinger operators (RBSOs), defined on the $d$-dimensional torus $(\mathbb Z/L\mathbb Z)^d$. These operators take the form…

概率论 · 数学 2025-04-15 Fan Yang , Jun Yin

We consider a product of an arbitrary number of independent rectangular Gaussian random matrices. We derive the mean densities of its eigenvalues and singular values in the thermodynamic limit, eventually verified numerically. These…

统计力学 · 物理学 2011-06-28 Z. Burda , A. Jarosz , G. Livan , M. A. Nowak , A. Swiech