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While graphene is a semi-metal, recently synthesized hydrogenated graphene called graphane, turns out to be an insulator. We have probed the metal insulator Transition in graphene-graphane system within the framework of density functional…

介观与纳米尺度物理 · 物理学 2009-11-10 Prachi Chandrachud , Bhalchandra S. Pujari , D. G. Kanhere

Graphene oxide (GO) is reduced by Joule heating using in-situ transmission electron microscopy (TEM). The approach allows the simultaneous study of GO conductivity by electrical measurements and of its composition and structural properties…

介观与纳米尺度物理 · 物理学 2021-04-16 Simon Hettler , David Sebastian , Mario Pelaez-Fernandez , Ana M. Benito , Wolfgang K. Maser , Raul Arenal

Graphene oxide (GO) exhibits rich chemical heterogeneity that strongly influences its structural, thermal, and mechanical properties, yet quantitatively linking reduction chemistry to heat transport remains challenging. In this work, we…

Graphene oxide (GO), the functionalized graphene with oxygenated groups (mainly epoxy and hydroxyl), has attracted resurgent interests in the past decade owing to its large surface area, superior physical and chemical properties, and easy…

材料科学 · 物理学 2020-01-14 Xiaoming Huang , Lizhao Liu , Si Zhou , Jijun Zhao

The magnetotransport in single layer graphene has been experimentally investigated in magnetic fields up to 18 T as a function of temperature. A pronounced T-dependence is observed for T < 50 K, which is either metallic, or insulating,…

介观与纳米尺度物理 · 物理学 2010-07-28 L. Zhang , Y. Zhang , M. Khodas , T. Valla , I. A. Zaliznyak

Graphene on a substrate has been shown to exhibit a transition, depending on the substrate material, from a zero-gap semiconductor state to a semimetallic state. The ground-state energy of the electron (hole) gas has been calculated within…

其他凝聚态物理 · 物理学 2008-05-30 P. V. Ratnikov

The allure of all carbon electronics stems from the spread in physical properties, across all its allotropes. The scheme also harbours unique challenges, like tunability of band-gap, variability of doping and defect control. Here, we…

介观与纳米尺度物理 · 物理学 2021-12-30 Arijit Kayal , Harikrishnan Gopalakrishnan , Kingshuk Bandopadhyay , Amit Kumar , S. Ravi P. Silva , J. Mitra

By using the real-space Green-Kubo formalism we study numerically the electron transport properties of low-fluorinated graphene. At low temperatures the diffuse transport regime is expected to be prevalent, and we found a pronounced…

介观与纳米尺度物理 · 物理学 2020-04-22 D. V. Kolesnikov , V. A. Osipov

Here we show, with simultaneous transport and photoemission measurements, that the graphene terminated SiC(0001) surface undergoes a metal-insulator transition (MIT) upon dosingwith small amounts of atomic hydrogen. We find the room…

介观与纳米尺度物理 · 物理学 2009-04-16 Aaron Bostwick , Jessica L. McChesney , Konstantin Emtsev , Thomas Seyller , Karsten Horn , Stephan D. Kevan , Eli Rotenberg

Graphene oxide (GO) flakes have been deposited to bridge the gap between two epitaxial graphene electrodes to produce all-graphene devices. Electrical measurements indicate the presence of Schottky barriers (SB) at the graphene/graphene…

介观与纳米尺度物理 · 物理学 2008-07-07 Xiaosong Wu , Mike Sprinkle , Xuebin Li , Fan Ming , Claire Berger , Walt A. de Heer

The author reports an experimental study of electrical and thermal transport in reduced graphene oxide (RGO)/polystyrene (PS) composites. The electrical conductivity ($\sigma$) of RGO/PS composites with different RGO concentrations at room…

材料科学 · 物理学 2017-02-28 Wonjun Park , Jiuning Hu , Luis A. Jauregui , Xiulin Ruan , Yong P. Chen

Graphene is of interest in the development of next-generation electronics due to its high electron mobility, flexibility and stability. However, graphene transistors have poor on/off current ratios because of the absence of a bandgap. One…

材料科学 · 物理学 2021-05-03 Shaorui Li , Jiaheng Li , Yongchao Wang , Chenglin Yu , Yaoxin Li , Wenhui Duan , Yayu Wang , Jinsong Zhang

A mild annealing procedure was recently proposed for the scalable enhancement of graphene oxide (GO) properties with the oxygen content preserved, which was demonstrated to be attributed to the thermally driven phase separation. In this…

化学物理 · 物理学 2015-02-10 Pengzhan Sun , Yanlei Wang , He Liu , Kunlin Wang , Dehai Wu , Zhiping Xu , Hongwei Zhu

Graphene oxide finds applications in different fields of science, including energy conversion. Electrochemical reduction of graphene oxide (GO) significantly improves its conductivity. However, the kinetics of this process depends on the…

We elucidate on the low mobility and charge traps of the chemically reduced graphene oxide (RGO) sheets by measuring and analyzing temperature dependent current-voltage characteristics. The RGO sheets were assembled between source and drain…

介观与纳米尺度物理 · 物理学 2015-05-19 Daeha Joung , A. Chunder , Lei Zhai , Saiful I. Khondaker

Broadband Dielectric Spectroscopy (BDS) measurements of P{\omicron}lyaniline/Graphene oxide composites were conducted for an as-prepared and a thermally annealed specimen, respectively, from 15K to room temperature. Electrical conductivity…

As a derivative of graphene, graphene oxide (GO) was initially developed by chemists to emulate some of the key properties of graphene, but it was soon recognized as a unique material in its own right, addressing an application space that…

光学 · 物理学 2023-03-08 David Moss

We report an in-depth study of the reduction of graphene oxide (GO) by in-situ thermal transmission electron microscopy (TEM) analysis. In-situ heating high-resolution TEM (HRTEM) imaging and electron energy-loss spectroscopy (EELS)…

材料科学 · 物理学 2021-04-15 M. Pelaez-Fernandez , A. Bermejo , A. M. Benito , W. K. Maser , R. Arenal

Zero dimensional graphene quantum dots (GQDs) exhibit interesting physical and chemical properties due to the edge effect and quantum confinement. As the number of carbon atoms in edge is more than on basal plane, GQDs are more reactive.…

Increasing energy demands of modern society requires deep understanding of the properties of energy storage materials as well as their performance tuning. We show that the capacitance of graphene oxide (GO) can be precisely tuned using a…

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